Abstract
When an aqueous solution (W) containing flavin mononucleotide, pyruvic acid and O2 was put into contact with a nitrobenzene solution (NB) containing Na+, K+, valinomycin and a ferrocene derivative, CO2 was evolved in W and Na+ was transferred from NB to W, though K+ remained in NB. The above-mentioned respiration mimetic reaction process, accompanied by the selective ion transfer, was elucidated by referring to the ion and electron transfer voltammograms at the W/NB interface and by taking into account the energetics of the coupling between the ion and electron transfers.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. L. Lehninger, “Principles of Biochemistry”, Chap. 13 and 17, Worth Publishers, New York, 1982.
D. G. Nicholls, “Bioenergetics: An Introduction to the Chemiosmotic Theory”, Academic Press, New York, 1982.
B. Alberts, D. Bray, J. Lewis, D. Raff, K. Roberts and J. Watson, “Molecular Biology of the Cell”, 3rd ed., Chap. 14, Garland Publishing, New York, 1994.
S. Kihara, M. Suzuki, K. Maeda, K. Ogura, S. Umetani, M. Matsui and Z. Yoshida, Anal. Chem., 58, 2954 (1986).
S. Kihara, M. Suzuki, K. Maeda, K. Ogura, M. Matsui and Z. Yoshida, J. Electroanal. Chem., 271, 107 (1989).
K. Maeda, S. Kihara, M. Suzuki and M. Matsui, J. Electroanal. Chem., 303, 171 (1991).
S. Kihara, M. Suzuki, M. Sugiyama and M. Matsui, J. Electroanal. Chem., 249, 109 (1988).
H. Nishida, N. Takada, M. Yoshimura, T. Sonoda and H. Kobayashi, Bull. Chem. Soc. Jpn., 57, 2600 (1984).
R. S. Bahr and P. Boudjouk, J. Org. Chem., 57, 5545 (1992).
T. Fujinaga and S. Kihara, CRC Crit. Rev. Anal. Chem., 6, 223 (1977).
S. Kihara, Z. Yoshida, H. Muto, H. Aoyagi and Y. Baba, Anal. Chem., 52, 1601 (1980).
M. Suzuki, M. Matsui and S. Kihara, J. Electroanal. Chem., 438, 147 (1997).
Z. Samec, J. Electroanal. Chem., 99, 385 (1979).
Z. Samec, J. Electroanal. Chem., 103, 1 (1979).
J. March, “Advanced Organic Chemistry”, 4th ed., p. 1175, John Wiley & Sons, New York, 1992.
T. Kakutani, Y. Nishiwaki, T. Osakai and M. Senda, Bull. Chem. Soc. Jpn., 59, 781 (1986).
Z. Samec and P. Papoff, Anal. Chem., 62, 1010 (1990).
H. Matsuda, Y. Yamada, K. Kanamori, Y. Kudo and Y. Takeda, Bull. Chem. Soc. Jpn., 64, 1497 (1991).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Maeda, K., Nishihara, M., Ohde, H. et al. Selective Ion Transfer Accompanied by a Respiration Mimetic Reaction at an Aqueous/Organic Solutions Interface. ANAL. SCI. 14, 85–88 (1998). https://doi.org/10.2116/analsci.14.85
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.2116/analsci.14.85