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Ion-Exchange Ability of Polyaniline-Polyvinyl Alcohol Colloids with Various Anions

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Abstract

Polyaniline-polyvinyl alcohol (PAPVA) colloids consisting of polyaniline (PA) and polyvinyl alcohol (PVA) were prepared. This colloid is electrochemically active and can adsorb various anions. The adsorption occurs electro-chemically or chemically. The selectivity sequence of the PAPVA colloid toward monovalent anions was SCN-> ClO4−>BF4−>Br− ≫ Cl−≈CF3COO−≫C6H5SO3−. Adsorption ability of the PAPVA colloid toward each anion was enhanced when large anions such as G6H5SO3−, were doped into the colloid.

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Yamaguchi University, Tokiwadai, Ube, 755, Japan

    Hidenobu Nakao, Tsutomu Nagaoka & Kotaro Ogura

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  1. Hidenobu Nakao
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  2. Tsutomu Nagaoka
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  3. Kotaro Ogura
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Nakao, H., Nagaoka, T. & Ogura, K. Ion-Exchange Ability of Polyaniline-Polyvinyl Alcohol Colloids with Various Anions. ANAL. SCI. 13, 327–331 (1997). https://doi.org/10.2116/analsci.13.327

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  • DOI: https://doi.org/10.2116/analsci.13.327

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