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Molecular-Recognition and Sensory System of γ-Cyclodextrin Capped by Sodium Anthranilate

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Abstract

γ-Cyclodextrin with a sodium anthranilate moiety (1) has been prepared as a sensing molecule for organic compounds including terpenoids and bile acids. The sensing and host-guest complexation properties are discussed here in comparison with those of β-cyclodextrin with a sodium anthranilate moiety (2) and γ-cyclodextrin with two sodium anthranilate moieties (3). Compound 1 shows a pure monomer fluorescence with an intensity which increases upon the addition of guest species. The extent of fluorescence variation with a guest is used to determine the sensing factor (ΔI/I0) of 1 for a guest. Compound 1 recognizes terpenoids better than 3 and bile acids better than 2.

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Authors and Affiliations

  1. Department of Materials Engineering and Applied Chemistry, Mining College, Akita University, Tegata, Akita, 010, Japan

    Fumio Hamada, Kyoko Ishikawa & Itsu Tamura

  2. Department of Bioengineering, Faculty of Bioscience and Biotechnology, Tokyo Institute of Technology, Nagatsuta, Yokohama, 227, Japan

    Akihiko Ueno

Authors
  1. Fumio Hamada
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  2. Kyoko Ishikawa
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  3. Itsu Tamura
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  4. Akihiko Ueno
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Hamada, F., Ishikawa, K., Tamura, I. et al. Molecular-Recognition and Sensory System of γ-Cyclodextrin Capped by Sodium Anthranilate. ANAL. SCI. 11, 935–939 (1995). https://doi.org/10.2116/analsci.11.935

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  • DOI: https://doi.org/10.2116/analsci.11.935

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