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Co-precipitation of Calcium Carbonate and Barium Carbonate at High Temperature

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Abstract

Ammonium carbonate solution was added into a solution of calcium and barium maintained at 90°C, and a carbonate precipitate was produced. Co-precipitation of calcium carbonate and barium carbonate was investigated analytically. The calcium and barium carbonates produced at high temperature were both composed of rod-shaped particles and their crystals belonged to the orthorhombic system. The co-precipitated particles of calcium and barium carbonates were generally composed of two kinds of crystals: a spindle-shaped crystal and a cubic-like plate crystal. The spindle-shaped and cubic-like crystals were both solid solutions of calcium and barium carbonates. The precipitate produced in an equimolecular solution of calcium and barium was composed of only cubic-like plate crystals. These belonged to the orthorhombic system; their lattice constants were estimated to be a0=5.06, b0=8.80 and c0=6.24. The lattice constants of these spindle-shaped and cubic-like crystals were estimated on the assumption that all the crystals belonged to the orthorhombic system.

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References

  1. J. Johnston, H. E. Merwin and E. D. Williamson, Am. J. Sci., (IV), 41, 473 (1916).

    Article  CAS  Google Scholar 

  2. K. Kamiya and S. Sakka, Gypsum & Lime, 163, 23 (1979).

    Google Scholar 

  3. J. J. Lander, J. Chem. Phys. 17, 892 (1949).

    Article  CAS  Google Scholar 

  4. R. Kiriyama, “Kozo Mukikagaku”, III, Kyoritsu, Tokyo, p. 187 (1960).

    Google Scholar 

  5. M. Ishibashi, “Jikken Bunsekikagaku”, Kyoritsu, Tokyo, p. 81 (1977).

    Google Scholar 

  6. ASTM card, 5-0453; 5-0378.

  7. Chem. Soc. Japan, “Kagakubinran”, Maruzen, Tokyo p. 790, 800 (1975).

  8. E. R. Segnit, H. D. Holland and C. J. Biscardi, Geochim. Cosmochim. Acta, 26, 1301 (1962).

    Article  CAS  Google Scholar 

  9. K. Takiyama and E. Kozuki, J. Electr. Microsc., 18, 93 (1969).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Home Science, Mukogawa Women’s University, Ikebiraki-cho, Nishmomiya, Hyogo, 663, Japan

    Keiko Yokofujita, Yuko Ishii & Kazuyosbi Takiyama

Authors
  1. Keiko Yokofujita
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  2. Yuko Ishii
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  3. Kazuyosbi Takiyama
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Yokofujita, K., Ishii, Y. & Takiyama, K. Co-precipitation of Calcium Carbonate and Barium Carbonate at High Temperature. ANAL. SCI. 1, 37–39 (1985). https://doi.org/10.2116/analsci.1.37

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  • DOI: https://doi.org/10.2116/analsci.1.37

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