Skip to main content
Log in

Effect of temperature on the hydration process and strength development in blends of Portland cement and activated coal gangue or fly ash

  • Published:
Journal of Zhejiang University-SCIENCE A Aims and scope Submit manuscript

Abstract

This paper describes the results of an investigation into the effect of the variation of curing temperatures between 0 and 60 °C on the hydration process, pore structure variation, and compressive strength development of activated coal gangue-cement blend (ACGC). Hardened ACGC pastes cured for hydration periods from 1 to 360 d were examined using the non-evaporable water method, thermal analysis, mercury intrusion porosimetry, and mechanical testing. To evaluate the specific effect of activated coal gangue (ACG) as a supplementary cementing material (SCM), a fly ash-cement blend (FAC) was used as a control. Results show that raising the curing temperature accelerates pozzolanic reactions involving the SCMs, increasing the degree of hydration of the cement blends, and hence increasing the rate of improvement in strength. The effect of curing temperature on FAC is greater than that on ACGC. The pore structure of the hardened cement paste is improved by increasing the curing temperature up to 40 °C, but when the curing temperature reaches 60 °C, the changing nature of the pore structure leads to a decrease in strength. The correlation between compressive strength and the degree of hydration and porosity is linear in nature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Escalante-garcía, J.I., Sharp, J.H., 2001. The microstructure and mechanical properties of blended cements hydrated at various temperatures. Cement and Concrete Research, 31(5):695–702. [doi:10.1016/S0008-8846(01)00471-9]

    Article  Google Scholar 

  • Gómez-Zamorano, L.Y., Escalante-García, J.I., 2010. Effect of curing temperature on the nonevaporable water in Portland cement blended with geothermal silica waste. Cement and Concrete Composites, 32(8):603–610. [doi:10.1016/j. cemconcomp.2010.07.004]

    Article  Google Scholar 

  • Gong, C.C., Song, X.Y., Li, D.X., 2005a. Mechanism discussion on calcined activate coal gangue. Journal of Material Science and Engineering, 23(1):88–91, 108 (in Chinese).

    Google Scholar 

  • Gong, C.C., Tao, X., Li, D.X., 2005b. Study on activation and structure performance of calcined coal gangue. Material Review, 19(2):115–117, 120 (in Chinese).

    Google Scholar 

  • Haneharas, S., Tomosawa, F., Kobayakawa, M., Hwang, K.R., 2001. Effects of water/powder ratio, mixing ratio of fly ash, and curing temperature on pozzolanic reaction of fly ash in cement paste. Cement and Concrete Research, 31(1):31–39. [doi:10.1016/S0008-8846(00)00441-5]

    Article  Google Scholar 

  • Hu, S.G., Wang, X., Lü, L.N., Geng, J., Ding, Q.J., 2005. The influence of coal gangue to the hydration process of Portland coal gangue cement. Cement, (8):5–7 (in Chinese).

  • Leng, F.G., 2000. The comprehensive utilization of coal slack. Build Science Research of Sichuan, 26(2):44–46 (in Chinese).

    Google Scholar 

  • Li, D.X., Song, X.Y., Gong, C.C., Pan, Z.H., 2006. Research on cementitious behavior and mechanism of pozzolanic cement with coal gangue. Cement and Concrete Research, 36(9):1752–1759. [doi:10.1016/j.cemconres.2004.11.004]

    Article  Google Scholar 

  • Liu, X.P., Wang, P.M., 2008. Interface structure of Portland coal gangue blended cement. Journal of the Chinese Ceramic Society, 36(1):104–111 (in Chinese).

    Google Scholar 

  • Liu, X.P., Wang, P.M., Xia, C.H., 2006. Study on Morphologies of Hydrates of High C3S Content Cement Mixed with Coal Gangue at Various Temperatures. 6th International Symposium on Cement and Concrete/Canmet-ACI International Symposium on Concrete Technology for Sustainable, Xi’an, China. Foreign Language Press, Beijing, China, p.242–248.

    Google Scholar 

  • Lothenbach, B., Winnefeld, F., Alder, C., Wieland, E., Lunk, P., 2007. Effect of temperature on the pore solution, microstructure and hydration products of Portland cement pastes. Cement and Concrete Research, 37(4):483–491. [doi:10.1016/j.cemconcres.2006.11.016]

    Article  Google Scholar 

  • Lothenbach, B., Matschei, T., Möschner, G., Glasser, F.P., 2008. Thermodynamic modelling of the effect of temperature on the hydration and porosity of Portland cement. Cement and Concrete Research, 38(1):1–18. [doi:10.1016/j.cemconcres.2007.08.017]

    Article  Google Scholar 

  • Matschei, T., Glasser, F.P., 2010. Temperature dependence, 0 to 40 °C, of the mineralogy of Portland cement paste in the presence of calcium carbonate. Cement and Concrete Research, 40(5):763–777. [doi:10.1016/j.cemconcres. 2009.11.010]

    Article  Google Scholar 

  • Mehta, P.K., Monteiro, P.J.M., 1993. Concrete: Structure, Properties and Materials. Prentice Hall, New Jersey, USA, p.22–36.

    Google Scholar 

  • Rojas, M.F., Sánchez de Rojas, M.I., 2005. Influence of metastable hydrated phases on the pore size distribution and degree of hydration of MK-blended cements cured at 60 °C. Cement and Concrete Research, 35(7):1292–1298. [doi:10.1016/j. cemconcres.2004.10.038]

    Article  Google Scholar 

  • Taylor, H.F.W., 1997. Cement Chemistry. Thomas Telford Publishing, London, England, p.238–252.

    Book  Google Scholar 

  • Wang, P.M., Liu, X.P., Hu, S.G., Lü, L.N., Ma, B.G., 2007. Hydration models of Portland coal gangue cement and Portland fly ash cement. Journal of the Chinese Ceramic Society, 35(S1):180–186 (in Chinese).

    Google Scholar 

  • Zhang, J.X., Sun, H.H., Sun, Y.M., Zhang, N., 2010. Corrosion behavior of steel rebar in coal gangue-based mortars. Journal of Zhejiang University-SCIENCE A (Applied Physics and Engineering), 11(5):382–388. [doi:10.1631/jzus.A0900443]

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xian-ping Liu.

Additional information

Project supported by the National Basic Research Program of China (Nos. 2001CB610704 and 2009CB623104), and the Youth Foundation of Key Laboratory of Advanced Civil Engineering Materials (Tongji University), Ministry of Education, China

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, Pm., Liu, Xp. Effect of temperature on the hydration process and strength development in blends of Portland cement and activated coal gangue or fly ash. J. Zhejiang Univ. Sci. A 12, 162–170 (2011). https://doi.org/10.1631/jzus.A1000385

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1631/jzus.A1000385

Key words

k]CLC number

Navigation