Skip to main content
Log in

Pore structure of CO2-cured seawater sea-sand concrete with sufficient carbonation and its mechanical behaviors under uniaxial compression

  • Original Article
  • Published:
Materials and Structures Aims and scope Submit manuscript

Abstract

Seawater sea-sand concrete (SSC) structures reinforced with fiber reinforced polymer (FRP) bars were proposed to capture CO2 by means of carbonation curing in this study. FRP-SSC structures allowed sufficient carbonation to occur since the steel corrosion in traditional reinforced concrete structures would not exist. Herein, the pore structure of CO2-cured SSC with sufficient carbonation was examined, and the mechanical behaviors under uniaxial compression were also investigated. MIP testing was employed, and surface fractal dimension in various pore-size regions was calculated. The results indicate that CO2 curing leads to a more significant variation in smaller mesopores of SSC than CC. Regarding middle capillary pores, the surface fractal dimension in almost all CO2-cured specimens ranges from 2.6617 to 2.8124, which means that these pores show distinct fractal characteristics, but this phenomenon does not be observed in water-cured specimens. This indicates that CO2 curing can greatly reduce ink-bottle pores in concrete. Furthermore, the compressive strength gain of CO2-cured SSC with sufficient carbonation is above 30% at the 180-days age. The compressive strength gain can be attributed to the improvement in the surface fractal dimension. Moreover, CO2-cured specimens exhibit higher peak stress, smaller peak strain, and greater elastic module, resulting in lower plasticity. Consequently, CO2 curing renders SSC and CC more brittle.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16

Similar content being viewed by others

References

  1. Monteiro PJM, Miller SA, Horvath A (2017) Towards sustainable concrete. Nat Mater 16(7):698–699

    Article  Google Scholar 

  2. Xiao JZ, Qiang CB, Nanni A, Zhang KJ (2017) Use of sea-sand and seawater in concrete construction: current status and future opportunities. Constr Build Mater 155:1101–1111. https://doi.org/10.1016/j.conbuildmat.2017.08.130

    Article  Google Scholar 

  3. Ahmed A, Guo SC, Zhang ZH, Shi CJ, Zhu DJ (2020) A review on durability of fiber reinforced polymer (FRP) bars reinforced seawater sea sand concrete. Constr Build Mater 256:119484. https://doi.org/10.1016/j.conbuildmat.2020.119484

    Article  Google Scholar 

  4. Li PR, Li WG, Yu T, Qu FL, Tam VWY (2020) Investigation on early-age hydration, mechanical properties and microstructure of seawater sea sand cement mortar. Constr Build Mater 249:118776. https://doi.org/10.1016/j.conbuildmat.2020.118776

    Article  Google Scholar 

  5. Guo MH, Hu B, Xing F, Zhou XQ, Sun M, Sui LL, Zhou YW (2020) Characterization of the mechanical properties of eco-friendly concrete made with untreated sea sand and seawater based on statistical analysis. Constr Build Mater 234:117339. https://doi.org/10.1016/j.conbuildmat.2019.117339

    Article  Google Scholar 

  6. Feng WH, Tang YC, Yang YM, Cheng Y, Qiu JH, Zhang HX, Isleem HF, Tayeh BA, Namdar A (2023) Mechanical behavior and constitutive model of sustainable concrete: Seawater and sea-sand recycled aggregate concrete. Constr Build Mater 364:130010. https://doi.org/10.1016/j.conbuildmat.2022.130010

    Article  Google Scholar 

  7. Younis A, Ebead U, Judd S (2018) Life cycle cost analysis of structural concrete using seawater, recycled concrete aggregate, and GFRP reinforcement. Constr Build Mater 175:152–160. https://doi.org/10.1016/j.conbuildmat.2018.04.183

    Article  Google Scholar 

  8. Page CL, Treadaway KWJ (1982) Aspects of the electrochemistry of steel in concrete. Nature 297(5862):109–115. https://doi.org/10.1038/297109a0

    Article  Google Scholar 

  9. Angst U, Elsener B, Larsen CK, Vennesland Ø (2009) Critical chloride content in reinforced concrete: a review. Cem Concr Res 39(12):1122–1138. https://doi.org/10.1016/j.cemconres.2009.08.006

    Article  Google Scholar 

  10. Qiao GF, Ou JP (2007) Corrosion monitoring of reinforcing steel in cement mortar by EIS and ENA. Electrochim Acta 52(28):8008–8019. https://doi.org/10.1016/j.electacta.2007.06.070

    Article  Google Scholar 

  11. Robert M, Cousin P, Benmokrane B (2009) Durability of GFRP reinforcing bars embedded in moist concrete. J Compos Constr 13(2):66–73. https://doi.org/10.1061/(ASCE)1090-0268(2009)13:2(66)

    Article  Google Scholar 

  12. Guo F, Al-Saadi S, Singh Raman RK, Zhao XL (2018) Durability of fiber reinforced polymer (FRP) in simulated seawater sea sand concrete (SWSSC) environment. Corros Sci 141:1–13. https://doi.org/10.1016/j.corsci.2018.06.022

    Article  Google Scholar 

  13. Zhang QT, Xiao JZ, Liao QX, Duan ZH (2019) Structural behavior of seawater sea-sand concrete shear wall reinforced with GFRP bars. Eng Struct 189:458–470. https://doi.org/10.1016/j.engstruct.2019.03.101

    Article  Google Scholar 

  14. Robert M, Benmokrane B (2010) Effect of aging on bond of GFRP bars embedded in concrete. Cem Conc Compos 32(6):461–467. https://doi.org/10.1016/j.cemconcomp.2010.02.010

    Article  Google Scholar 

  15. Liao JJ, Zeng JJ, Bai YL, Zhang LH (2022) Bond strength of GFRP bars to high strength and ultra-high strength fiber reinforced seawater sea-sand concrete (SSC). Compos Struct 281:115013. https://doi.org/10.1016/j.compstruct.2021.115013

    Article  Google Scholar 

  16. Zeng JJ, Liao JJ, Zhuge Y, Guo YC, Zhou JK, Huang ZH, Zhang LH (2022) Bond behavior between GFRP bars and seawater sea-sand fiber-reinforced ultra-high strength concrete. Eng Struct 254:113787. https://doi.org/10.1016/j.engstruct.2021.113787

    Article  Google Scholar 

  17. Chen Y, Davalos JF, Ray I, Kim HY (2007) Accelerated aging tests for evaluations of durability performance of FRP reinforcing bars for concrete structures. Compos Struct 78(1):101–111. https://doi.org/10.1016/j.compstruct.2005.08.015

    Article  Google Scholar 

  18. Kamal ASM, Boulfiza M (2011) Durability of GFRP Rebars in simulated concrete solutions under accelerated aging conditions. J Compos Constr 15(4):473–481. https://doi.org/10.1061/(ASCE)CC.1943-5614.0000168

    Article  Google Scholar 

  19. Kim HY, Park YH, You YJ, Moon CK (2008) Short-term durability test for GFRP rods under various environmental conditions. Compos Struct 83(1):37–47. https://doi.org/10.1016/j.compstruct.2007.03.005

    Article  Google Scholar 

  20. Wang ZK, Zhao XL, Xian GJ, Wu G, Singh Raman RK, Al-Saadi S, Haque A (2017) Long-term durability of basalt- and glass-fibre reinforced polymer (BFRP/GFRP) bars in seawater and sea sand concrete environment. Constr Build Mater 139:467–489. https://doi.org/10.1016/j.conbuildmat.2017.02.038

    Article  Google Scholar 

  21. Liu Z, Meng WN (2021) Fundamental understanding of carbonation curing and durability of carbonation-cured cement-based composites: a review. J CO2 Util 44:101428. https://doi.org/10.1016/j.jcou.2020.101428

    Article  Google Scholar 

  22. Li N, Mo LW, Unluer C (2022) Emerging CO2 utilization technologies for construction materials: a review. J CO2 Util 65:102237. https://doi.org/10.1016/j.jcou.2022.102237

    Article  Google Scholar 

  23. Zhang D, Ghouleh Z, Shao YX (2017) Review on carbonation curing of cement-based materials. J CO2 Util 21:119–131. https://doi.org/10.1016/j.jcou.2017.07.003

    Article  Google Scholar 

  24. Rostami V, Shao YX, Boyd AJ (2012) Carbonation curing versus steam curing for precast concrete production. J Mater Civ Eng 24(9):1221–1229. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000462

    Article  Google Scholar 

  25. Wei JX, Mo KH, Ling TC (2023) Roles of subsequent curing on the pH evolution and further hydration for CO2 cured cement pastes. J Build Eng 64:105701. https://doi.org/10.1016/j.jobe.2022.105701

    Article  Google Scholar 

  26. Xian XP, Zhang D, Lin H, Shao YX (2022) Ambient pressure carbonation curing of reinforced concrete for CO2 utilization and corrosion resistance. J CO2 Util 56:101861. https://doi.org/10.1016/j.jcou.2021.101861

    Article  Google Scholar 

  27. Xian XP, Logan C, Shao YX (2022) Dimensional stability of cement paste and concrete subject to early-age carbonation curing. Mater Struct. https://doi.org/10.1617/s11527-022-01926-8

    Article  Google Scholar 

  28. Xian XP, Zhang D, Shao YX, Zhang SP (2022) Evaluation of corrosion resistance of precast reinforced concrete subjected to early-age ambient pressure carbonation curing by accelerated impressed current method. J Sustain Cem-based Mater 12(5):592–608. https://doi.org/10.1080/21650373.2022.2098200

    Article  Google Scholar 

  29. Zhang D, Liu TL, Shao YX (2020) Weathering carbonation behavior of concrete subject to early-age carbonation curing. J Mater Civ Eng. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003087

    Article  Google Scholar 

  30. Zhang D, Shao YX (2019) Enhancing chloride corrosion resistance of precast reinforced concrete by carbonation curing. ACI Mater J 116(3):3–12. https://doi.org/10.14359/51714461

    Article  Google Scholar 

  31. Pan XY, Shi CJ, Hu X, Ou ZH (2017) Effects of CO2 surface treatment on strength and permeability of one-day-aged cement mortar. Constr Build Mater 154:1087–1095. https://doi.org/10.1016/j.conbuildmat.2017.07.216

    Article  Google Scholar 

  32. Guo BB, Yu RC, Wang J, Zhang ZD, Wang Y, Niu DT (2023) Three-fold benefits of using CO2 to cure seawater sea sand concrete. Constr Build Mater 401:132868. https://doi.org/10.1016/j.conbuildmat.2023.132868

    Article  Google Scholar 

  33. Zhan BJ, Xuan DX, Poon CS, Shi CJ (2019) Mechanism for rapid hardening of cement pastes under coupled CO2-water curing regime. Cem Concr Compos 97:78–88. https://doi.org/10.1016/j.cemconcomp.2018.12.021

    Article  Google Scholar 

  34. Chen TF, Gao XJ (2019) Effect of carbonation curing regime on strength and microstructure of Portland cement paste. J CO2 Util 34:74–86. https://doi.org/10.1016/j.jcou.2019.05.034

    Article  Google Scholar 

  35. Siddique S, Naqi A, Jang JG (2020) Influence of water to cement ratio on CO2 uptake capacity of belite-rich cement upon exposure to carbonation curing. Cem Concr Compos 111:103616. https://doi.org/10.1016/j.cemconcomp.2020.103616

    Article  Google Scholar 

  36. Ouyang X, Wu ZM, Shan B, Chen Q, Shi CJ (2022) A critical review on compressive behavior and empirical constitutive models of concrete. Constr Build Mater 323:126572. https://doi.org/10.1016/j.conbuildmat.2022.126572

    Article  Google Scholar 

  37. Li D, Niu DT, Fu Q, Luo DM (2020) Fractal characteristics of pore structure of hybrid Basalt–Polypropylene fibre-reinforced concrete. Cem Concr Compos 109:103555. https://doi.org/10.1016/j.cemconcomp.2020.103555

    Article  Google Scholar 

  38. Niu DT, Li D, Fu Q (2020) A 3D-IFU model for characterising the pore structure of hybrid fibre-reinforced concrete. Mater Design 188:108473. https://doi.org/10.1016/j.matdes.2020.108473

    Article  Google Scholar 

  39. Wang JB, Niu DT, He H (2019) Frost durability and stress-strain relationship of lining shotcrete in cold environment. Constr Build Mater 198:58–69. https://doi.org/10.1016/j.conbuildmat.2018.11.264

    Article  Google Scholar 

  40. Zhan BJ, Xuan DX, Poon CS, Shi CJ (2016) Effect of curing parameters on CO2 curing of concrete blocks containing recycled aggregates. Cem Concr Compos 71:122–130. https://doi.org/10.1016/j.cemconcomp.2016.05.002

    Article  Google Scholar 

  41. Xuan DX, Zhan BJ, Poon CS (2018) A maturity approach to estimate compressive strength development of CO2-cured concrete blocks. Cem Concr Compos 85:153–160. https://doi.org/10.1016/j.cemconcomp.2017.10.005

    Article  Google Scholar 

  42. Yan DM, Lu JY, Sun YF, Wang T, Meng T, Zeng Q, Liu Y (2021) CO2 pretreatment to aerated concrete with high-volume industry wastes enables a sustainable precast concrete industry. ACS Sustain Chem Eng 9(8):3363–3375. https://doi.org/10.1021/acssuschemeng.1c00001

    Article  Google Scholar 

  43. Lu JY, Ruan SQ, Liu Y, Wang T, Zeng Q, Yan DM (2022) Morphological characteristics of calcium carbonate crystallization in CO2 pre-cured aerated concrete. RSC Adv 12(23):14610–14620. https://doi.org/10.1039/d2ra01901a

    Article  Google Scholar 

  44. Chinese standard, GB/T 5008-2019 (2019) Standard for test methods for physical and mechanical properties of concrete (in Chinese)

  45. Lu B, Drissi S, Liu JH, Hu X, Song BX, Shi CJ (2022) Effect of temperature on CO2 curing, compressive strength and microstructure of cement paste. Cem Concr Res 157:106827. https://doi.org/10.1016/j.cemconres.2022.106827

    Article  Google Scholar 

  46. Pan XY, Shi CJ, Farzadnia N, Hu X, Zheng JL (2019) Properties and microstructure of CO2 surface treated cement mortars with subsequent lime-saturated water curing. Cem Concr Compos 99:89–99. https://doi.org/10.1016/j.cemconcomp.2019.03.006

    Article  Google Scholar 

  47. Guo BB, Chu GX, Yu RC, Wang Y, Yu Q, Niu DT (2023) Effects of sufficient carbonation on the strength and microstructure of CO2-cured concrete. J Build Eng 76:107311. https://doi.org/10.1016/j.jobe.2023.107311

    Article  Google Scholar 

  48. Sharma R, Kim H, Lee NK, Park JJ, Jang JG (2023) Microstructural characteristics and CO2 uptake of calcium sulfoaluminate cement by carbonation curing at different water-to-cement ratios. Cem Concr Res 163:107012. https://doi.org/10.1016/j.cemconres.2022.107012

    Article  Google Scholar 

  49. Xian XP, Shao YX (2021) Microstructure of cement paste subject to ambient pressure carbonation curing. Constr Build Mater 296:123652. https://doi.org/10.1016/j.conbuildmat.2021.123652

    Article  Google Scholar 

  50. Kim J, Choi YC, Choi S (2018) Fractal characteristics of pore structures in GGBFS-based cement pastes. Appl Surf Sci 428:304–314. https://doi.org/10.1016/j.apsusc.2017.09.165

    Article  Google Scholar 

  51. Zhang ZD, Angst U (2022) Microstructure and moisture transport in carbonated cement-based materials incorporating cellulose nanofibrils. Cem Concr Res 162:106990. https://doi.org/10.2139/ssrn.4040765

    Article  Google Scholar 

  52. Shah V, Scrivener K, Bhatacharjee B, Bishnoi S (2018) Changes in microstructure characteristics of cement paste on carbonation. Cem Concr Res 109:184–197. https://doi.org/10.1016/j.cemconres.2018.04.016

    Article  Google Scholar 

  53. Wang FM, Li SF (1997) Determination of the surface fractal dimension for porous media by capillary condensation. Ind Eng Chem Res 36(5):1598–1602. https://doi.org/10.1021/ie960555w

    Article  Google Scholar 

  54. Zeng Q, Li KF, Fen-chong T, Dangla P (2010) Surface fractal analysis of pore structure of high-volume fly-ash cement pastes. Appl Surf Sci 257(3):762–768. https://doi.org/10.1016/j.apsusc.2010.07.061

    Article  Google Scholar 

  55. Zeng Q, Chen S, Yang PC, Peng Y, Wang JY, Zhou CS, Wang ZD, Yan DM (2020) Reassessment of mercury intrusion porosimetry for characterizing the pore structure of cement-based porous materials by monitoring the mercury entrapments with X-ray computed tomography. Cem Concr Compos 113:103726. https://doi.org/10.1016/j.cemconcomp.2020.103726

    Article  Google Scholar 

  56. Zeng Q, Wang XH, Yang PC, Wang JY, Zhou CS (2019) Tracing mercury entrapment in porous cement paste after mercury intrusion test by X-ray computed tomography and implications for pore structure characterization. Mater Charact 151:203–215. https://doi.org/10.1016/j.matchar.2019.02.014

    Article  Google Scholar 

  57. Qi YX, Liu KX, Peng Y, Wang JY, Zhou CS, Yan DM, Zeng Q (2021) Visualization of mercury percolation in porous hardened cement paste by means of X-ray computed tomography. Cem Concr Comp 122:104111. https://doi.org/10.1016/j.cemconcomp.2021.104111

    Article  Google Scholar 

  58. Diamond S (2000) Mercury porosimetry: an inappropriate method for the measurement of pore size distributions in cement-based materials. Cem Concr Res 30(10):1517–1525. https://doi.org/10.1016/S0008-8846(00)00370-7

    Article  Google Scholar 

  59. Guo ZH (1999) The strength and deformation of concrete-experimental results and constitutive relationship. Tsinghua University Press, Beijing

    Google Scholar 

  60. Zeng Q, Li KF, Fen-chong T, Dangla P (2012) Pore structure characterization of cement pastes blended with high-volume fly-ash. Cem Concr Res 42(1):194–204. https://doi.org/10.1016/j.cemconres.2011.09.012

    Article  Google Scholar 

  61. Liu X, Feng P, Cai YX, Yu XH, Yu C, Ran QP (2022) Carbonation behavior of calcium silicate hydrate (C–S–H): its potential for CO2 capture. Chem Eng J 431:134243. https://doi.org/10.1016/j.cej.2021.134243

    Article  Google Scholar 

  62. Wang JJ, Xie JH, Wang YL, Liu YL, Ding YH (2020) Rheological properties, compressive strength, hydration products and microstructure of seawater-mixed cement pastes. Cem Concr Compos 114:103770. https://doi.org/10.1016/j.cemconcomp.2020.103770

    Article  Google Scholar 

  63. Suryavanshi AK, Swamy RN (1996) Stability of Friedel’s salt in carbonated concrete structural elements. Cem Concr Res 26(5):729–741. https://doi.org/10.1016/s0008-8846(96)85010-1

    Article  Google Scholar 

  64. Liu J, Qiu QW, Chen XC, Xing F, Han NX, He YJ, Ma YS (2017) Understanding the interacted mechanism between carbonation and chloride aerosol attack in ordinary Portland cement concrete. Cem Concr Res 95:217–225. https://doi.org/10.1016/j.cemconres.2017.02.032

    Article  Google Scholar 

  65. Rao GA, Prasad BKR (2002) Fracture energy and softening behavior of high-strength concrete. Cem Concr Res 32(2):247–252. https://doi.org/10.1016/s0008-8846(01)00667-6

    Article  Google Scholar 

  66. Vishalakshi KP, Revathi V, Reddy SS (2018) Effect of type of coarse aggregate on the strength properties and fracture energy of normal and high strength concrete. Eng Fract Mech 194:52–60. https://doi.org/10.1016/j.engfracmech.2018.02.029

    Article  Google Scholar 

  67. Tasdemir C, Tasdemir MA, Lydon FD, Barr BIG (1996) Effects of silica fume and aggregate size on the brittleness of concrete. Cem Concr Res 26(1):63–68. https://doi.org/10.1016/0008-8846(95)00180-8

    Article  Google Scholar 

  68. Giaccio G, de Sensale GR, Zerbino R (2007) Failure mechanism of normal and high-strength concrete with rice-husk ash. Cem Concr Compos 29(7):566–574. https://doi.org/10.1016/j.cemconcomp.2007.04.005

    Article  Google Scholar 

  69. Chen TF, Gao XJ (2020) Use of carbonation curing to improve mechanical strength and durability of pervious concrete. ACS Sustain Chem Eng 8(9):3872–3884. https://doi.org/10.1021/acssuschemeng.9b07348

    Article  Google Scholar 

  70. Ravikumar D, Zhang D, Keoleian G, Miller S, Sick V, Li V (2021) Carbon dioxide utilization in concrete curing or mixing might not produce a net climate benefit. Nat Commun. https://doi.org/10.1038/s41467-021-21148-w

    Article  Google Scholar 

Download references

Acknowledgements

The authors are grateful to the financial support from Nature Science Foundation of China (Project No.: 51908453) and Shenzhen Science and Technology Innovation Commission (Project No.: CJGJZD20220517141806015).

Author information

Authors and Affiliations

Authors

Contributions

Bingbing Guo: Writing, Conceptualization, Investigation, Data Analysis, Funding acquisition; Jia Chu: Writing, Investigation, Data Analysis; Ruichang Yu: Investigation, Data Analysis; Yan Wang: Review, Conceptualization; Qiang Fu: Review, Data Analysis; Ditao Niu: Supervision, Project administration; Feng Zhang: Review, Data Analysis.

Corresponding author

Correspondence to Bingbing Guo.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Guo, B., Chu, J., Yu, R. et al. Pore structure of CO2-cured seawater sea-sand concrete with sufficient carbonation and its mechanical behaviors under uniaxial compression. Mater Struct 57, 111 (2024). https://doi.org/10.1617/s11527-024-02394-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1617/s11527-024-02394-y

Keywords

Navigation