Skip to main content
Log in

Alkali silica reaction of waste glass aggregate in alkali activated fly ash and GGBFS mortars

  • Original Article
  • Published:
Materials and Structures Aims and scope Submit manuscript

Abstract

This paper evaluates the alkali silica reaction (ASR) susceptibility of waste glass aggregate in alkali activated fly ash and ground granulated blast furnace slag (GGBFS) mortars as compared to that in ordinary Portland cement (OPC) mortars. In accelerated mortar bar tests, glass fine aggregate showed much lower expansions in alkali activated fly ash and GGBFS blended mortars than in OPC mortars or alkali activated neat fly ash or GGBFS mortars. Glass aggregate was classified as non-reactive with alkali activated fly ash and GGBFS blends according to 10-day and 21-day expansion limits of the Australian Standard. Microstructural studies revealed that glass aggregate produced typical ASR products in OPC mortars and alkali activated neat GGBFS mortars due to the presence of high calcium. However, alkali activated fly ash and GGBFS blended mortars produced reaction products of low Ca/Si and high Al/Si ratios that reduced the dissolution of reactive silica present in glass aggregate causing less expansions. The observed expansion of the alkali activated neat fly ash mortar is attributed to the analcime phase found in the X-Ray diffraction of this mortar.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. Saha AK, Khan MNN, Sarker PK (2018) Value added utilization of by-product electric furnace ferronickel slag as construction materials: a review. Resour Conserv Recycl 134:10–24

    Article  Google Scholar 

  2. Navarro R, Alcocel EG, Sanchez I, Garces P, Zornoza E (2018) Mechanical properties of alkali activated ground SiMn slag mortars with different types of aggregates. Constr Build Mater 186:79–89

    Article  Google Scholar 

  3. Hajimohammadi A, Ngo T, Kashani A (2018) Glass waste versus sand as aggregates: the characteristics of the evolving geopolymer binders. J Cleaner Prod 193:593–603

    Article  Google Scholar 

  4. Hajimohammadi A, Ngo T, Kashani A (2018) Sustainable one-part geopolymer foams with glass fines versus sand as aggregates. Constr Build Mater 171:223–231

    Article  Google Scholar 

  5. Zhang S (2015) Waste glass as partial binder precursor and fine aggregate replacement in alkali activated slag/fly ash system. M.Sc thesis, Delft University of Technology

  6. Rajabipour F, Giannini E, Dunant C, Ideker JH, Thomas MDA (2015) Alkali–silica reaction: current understanding of the reaction mechanisms and the knowledge gaps. Cem Concr Res 76:130–146

    Article  Google Scholar 

  7. Shafaatian SMH, Akhavan A, Maraghechi H, Rajabipour F (2013) How does fly ash mitigate alkali–silica reaction (ASR) in accelerated mortar bar test (ASTM C1567)? Cem Concr Compos 37:143–153

    Article  Google Scholar 

  8. Lee G, Ling TC, Wong YL, Poon CS (2011) Effects of crushed glass cullet sizes, casting methods and pozzolanic materials on ASR of concrete blocks. Constr Build Mater 25(5):2611–2618

    Article  Google Scholar 

  9. Tan KH, Du H (2013) Use of waste glass as sand in mortar: part I—fresh, mechanical and durability properties. Cem Concr Compos 35(1):109–117

    Article  Google Scholar 

  10. Zhu H, Chen W, Zhou W, Byars EA (2009) Expansion behaviour of glass aggregates in different testing for alkali-silica reactivity. Mater Struct 42(4):485–494

    Article  Google Scholar 

  11. Shi C, Shi Z, Hu X, Zhao R, Chong L (2015) A review on alkali-aggregate reactions in alkali-activated mortars/concretes made with alkali-reactive aggregates. Mater Struct 48:621–628

    Article  Google Scholar 

  12. Liu Y, Shi C, Zhang Z, Li N (2019) An overview on the reuse of waste glasses in alkali-activated materials. Resour Conserv Recycl 144:297–309

    Article  Google Scholar 

  13. Fernandez-Jimenez A, Puertas F (2002) The alkali–silica reaction in alkali-activated granulated slag mortars with reactive aggregate. Cem Concr Res 32:1019–1024

    Article  Google Scholar 

  14. Puertas F, Palacios M, Gil-Maroto A, Vazquez T (2009) Alkali-aggregate behaviour of alkali-activated slag mortars: effect of aggregate type. Cem Concr Compos 31:277–284

    Article  Google Scholar 

  15. Shi Z, Shi C, Zhao R, Wan S (2015) Comparison of alkali–silica reactions in alkali-activated slag and Portland cement mortars. Mater Struct 48:743–751

    Article  Google Scholar 

  16. Fernandez-Jimenez A, Garcia-Lodeiro I, Palomo A (2007) Durability of alkali-activated fly ash cementitious materials. J Mater Sci 42:3055–3065

    Article  Google Scholar 

  17. Kupwade-Patil K, Allouche EN (2013) Impact of alkali silica reaction on fly ash-based geopolymer concrete. J Mater Civ Eng 25(1):131–139

    Article  Google Scholar 

  18. Bakharev T, Sanjayan J, Cheng Y-B (2001) Resistance of alkali-activated slag concrete to alkali–aggregate reaction. Cem Concr Res 31:331–334

    Article  Google Scholar 

  19. Xie Z, Xiang W, Xi Y (2003) ASR potentials of glass aggregates in water-glass activated fly ash and portland cement mortars. J Mater Civ Eng 15(1):67–74

    Article  Google Scholar 

  20. Garcia-Lodeiro I, Palomo A, Fernandez-Jimenez A (2007) Alkali–aggregate reaction in activated fly ash systems. Cem Concr Res 37:175–183

    Article  Google Scholar 

  21. Pouhet R, Cyr M (2015) Alkali–silica reaction in metakaolin-based geopolymer mortar. Mater Struct 48:571–583

    Article  Google Scholar 

  22. Angulo-Ramírez DE, De Gutierrez RM, Medeiros M (2018) Alkali-activated Portland blast furnace slag cement mortars: performance to alkali-aggregate reaction. Constr Build Mater 179:49–56

    Article  Google Scholar 

  23. AS 1141.60.1. (2014) Method for sampling and testing aggregates, potential alkali silica reactivity-accelerated mortar bar method. Sydney, Australia: Standards Australia

  24. ASTM C618 (2001) Standard specification for coal fly ash and raw or calcined natural pozzolan for use as a mineral admixture in concrete. ASTM International, West Conshohocken

    Google Scholar 

  25. Tennakoon CK (2016) Assessment of properties of ambient cured geopolymer concrete for construction applications. Ph.D. thesis, Swinburne University of Technology

  26. Hay R, Ostertag CP (2019) On utilization and mechanisms of waste aluminium in mitigating alkali-silica reaction (ASR) in concrete. J Cleaner Prod 212:864–879

    Article  Google Scholar 

  27. Rashidian-Dezfouli H, Afshinnia K, Rangaraju PR (2018) Efficiency of Ground Glass Fiber as a cementitious material, in mitigation of alkali-silica reaction of glass aggregates in mortars and concrete. J Build Engg 15:171–180

    Article  Google Scholar 

  28. Shi Z, Shi C, Zhang J, Wan S, Zhang Z, Ou Z (2018) Alkali-silica reaction in waterglass-activated slag mortars incorporating fly ash and metakaolin. Cem Concr Res 108:10–19

    Article  Google Scholar 

  29. ASTM C1260 (2007) Standard test method for potential alkali reactivity of aggregates (mortar-bar method). ASTM International, West Conshohocken

    Google Scholar 

  30. Shi Z, Shi C, Wan S, Ou Z (2017) Effect of alkali dosage on alkali-silica reaction in sodium hydroxide activated slag mortars. Constr Build Mater 143:16–23

    Article  Google Scholar 

  31. Hong SY, Glasser FP (2002) Alkali sorption by C–S–H and C–A–S–H gels: part II. Role of alumina. Cem Concr Res 32(7):1101–1111

    Article  Google Scholar 

  32. Saha AK, Sarker PK (2019) Mitigation of the potential alkali–silica reaction of FNS using ground FNS as a supplementary binder. Adv Cem Res (Ahead of Print)

  33. Saha AK, Sarker PK (2018) Potential alkali silica reaction expansion mitigation of ferronickel slag aggregate by fly ash. Struct Concr 19:1376–1386

    Article  Google Scholar 

  34. Rafeet A, Vinai R, Soutsos M, Sha W (2019) Effects of slag substitution on physical and mechanical properties of fly ash based alkali activated binders (AABs). Cem Concr Res 122:118–135

    Article  Google Scholar 

  35. Shin J, Struble LJ, Kirkpatrick RJ (2015) Microstructural changes due to alkali-silica reaction during standard mortar test. Materials 8(12):8292–8303

    Article  Google Scholar 

  36. Saha AK, Khan MNN, Sarker PK, Shaikh FA, Pramanik A (2018) The ASR mechanism of reactive aggregates in concrete and its mitigation by fly ash: a critical review. Constr Build Mater 171:743–758

    Article  Google Scholar 

  37. Saha AK, Sarker PK (2016) Expansion due to alkali-silica reaction of ferronickel slag fine aggregate in OPC and blended cement mortars. Constr Build Mater 123:135–142

    Article  Google Scholar 

  38. Leemann A, Le Saout G, Winnefeld F, Rentsch D, Lothenbach B (2011) Alkali–silica reaction: the influence of calcium on silica dissolution and the formation of reaction products. J Am Ceram Soc 94:1243–1249

    Article  Google Scholar 

  39. Hong SY, Glasser FP (1999) Alkali binding in cement pastes: part I. The C–S–H phase. Cem Concr Res 29(12):1893–1903

    Article  Google Scholar 

Download references

Acknowledgements

Part of this research was undertaken using the EM instrumentation (ARC LE130100053) at the John de Laeter Centre, Curtin University.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Md. Nabi Newaz Khan.

Ethics declarations

Conflict of interest

The authors declare that there is no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 2914 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khan, M.N., Sarker, P.K. Alkali silica reaction of waste glass aggregate in alkali activated fly ash and GGBFS mortars. Mater Struct 52, 93 (2019). https://doi.org/10.1617/s11527-019-1392-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1617/s11527-019-1392-3

Keywords

Navigation