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Electrical conductivity to determine maturity and activation energy in concretes

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Abstract

The concepts of maturity and activation energy have been primarily used for prediction of compressive strength. Less frequently, these principles have been used for investigation of the temperature–time relationship of other properties. In this research, electrical conductivity was monitored over time for the period of 1–28 days for 10 concrete mixtures. It was found that the typical relationship that holds for compressive strength in relation to the maturity does not hold for conductivity. In addition, activation energy was determined by the Arrhenius relationship using four methods of calculating the rate constant. Values calculated for activation energy varied considerably depending on the method used with the exponential rate constant giving the lowest values. Comparing results to published literature, the linear hyperbolic method most often cited gives similar values of activation energy in this research to those published for either hydration or strength.

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References

  1. Abdel-Jawad YA (2006) The maturity method: modifications to improve estimation of concrete strength at later ages. Constr Build Mater 20:893–900

    Article  Google Scholar 

  2. ASTM (2011) C1074 Standard practice for estimating concrete strength by the maturity method. ASTM International, West Conshohocken. doi:10.1520/C1074-11

  3. ASTM (2012a) ASTM C150 (Standard specification for portland cement). ASTM International, West Conoshohoken

  4. ASTM (2012b) ASTM C1202 (Standard test method for electrical indication of concrete’s ability to resist chloride ion penetration). ASTM International, West Conshohocken, PA

  5. ASTM (2012) ASTM C 1760 (Standard Test Method for Bulk Electrical Conductivity of Hardened Concrete). ASTM International, West Conoshohocken

    Google Scholar 

  6. ASTM (2013) ASTM C 918 (Standard Test Method for Measuring Early-Age Compressive Strength and Projecting Later-Age Strength). ASTM International, West Conshohocken

    Google Scholar 

  7. Barnett S, Soutsos M, Millard S, Bungey J (2006) Strength development of mortars containing ground granulated blast-furnace slag: effect of curing temperature and determination of apparent activation energies. Cem Concr Res 36:434–440

    Article  Google Scholar 

  8. Bernhardt C (1956) Hardening of concrete at different temperatures. In: Proceedings of RILEM Symposium

  9. Brooks AG, Schindler AK, Barnes RW (2007) Maturity method evaluated for various cementitious materials. J Mater Civ Eng 19:1017–1025

    Article  Google Scholar 

  10. Carino NJ (1984) The maturity method: theory and application. Cem Concr Aggreg 6:61–73

    Article  Google Scholar 

  11. Carino NJ, Lew H (2001) The maturity method: from theory to application. In: Chang PC (ed) Structures congress and exposition. ASCE, Washington, DC, p 19

    Google Scholar 

  12. Carino NJ, Tank RC (1992) Maturity function for concretes made with various cements and admixtures. ACI Mater J 89:188–196

    Google Scholar 

  13. Chrisp TM, Starrs G, McCarter WJ, Rouchotas E, Blewett J (2001) Temperature-conductivity relationships for concrete: an activation energy approach. J Mater Sci Lett 20:1085–1087. doi:10.1023/A:1010926426753

    Article  Google Scholar 

  14. Ezziane K, Kadri E, Hallal A, Duval R (2010) Effect of mineral additives on the setting of blended cement by the maturity method. Mater Struct 43:393–401

    Article  Google Scholar 

  15. Freiesleben Hansen P, Pedersen EJ (1977) Maturity computer for controlled curing and hardening of concrete. Nordisk Berong 1:19–34

    Google Scholar 

  16. Garcia A, Castro-Fresno D, Polanco JA (2008) Maturity approach applied to concrete by means of vicat tests. ACI Mater J 105:445–450

    Google Scholar 

  17. Geiker M (1983) Studies of Portland cement hydration by measurements of chemical shrinkage and a systematic evaluation of hydration curves by means of the dispersion model. PhD, PhD, Technical University of Denmark

  18. Han M-C, Han C-G (2010) Use of maturity methods to estimate the setting time of concrete containing super retarding agents. Cem Concr Compos 32:164–172. doi:10.1016/j.cemconcomp.2009.11.008

    Article  Google Scholar 

  19. Han S-H, Kim J-K, Park Y-D (2003) Prediction of compressive strength of fly ash concrete by new apparent activation energy function. Cem Concr Res 33:965–971. doi:10.1016/S0008-8846(03)00007-3

    Article  Google Scholar 

  20. Hansen PF, Pedersen E, Konstruktionsinstituttet B (1984) Curing of concrete structures. BKI

  21. Helland S (1987) Temperatur og Fasthetsutvikling i Betong med v/c Iavere enn 0.40 (in Norwegian). J Nord Concr Fed 5:26–29

    Google Scholar 

  22. Jonasson J (1985) Early strength growth in concrete—preliminary test results concerning hardening at elevated temperatures. In: Proceedings of 3rd International RILEM symposium on winter concreting, pp 249–254

  23. Julio-Betancourt G, Hooton R (2004) Study of the Joule effect on rapid chloride permeability values and evaluation of related electrical properties of concretes. Cem Concr Res 34:1007–1015

    Article  Google Scholar 

  24. Kada-Benameur H, Wirquin E, Duthoit B (2000) Determination of apparent activation energy of concrete by isothermal calorimetry. Cem Concr Res 30:301–305

  25. Kjellsen K, Detwiler R (1993) Later-age strength prediction by a modified maturity model. ACI Mater J 90:220–227

    Google Scholar 

  26. Knudsen T (1980) On particle size distribution in cement hydration. In: Proceedings, pp 1–170

  27. Knudsen T (1984) The dispersion model for hydration of Portland cement I: General Concepts. Cem Concr Res 14:622–630

    Article  Google Scholar 

  28. Lachemi M, Hossain K, Anagnostopoulos C, Sabouni A (2007) Application of maturity method to slipforming operations: performance validation. Cem Concr Compos 29:290–299

    Article  Google Scholar 

  29. Lei WG, Struble LJ (1997) Microstructure and flow behavior of fresh cement paste. J Am Ceram Soc 80:2021–2028

    Article  Google Scholar 

  30. Lew H, Reichard T (1978) Prediction of strength of concrete from maturity. In: Malhotra VM (ed) Accelerated strength testing. American Concrete Institute, Detroit, pp 229–248

    Google Scholar 

  31. Liao WC, Lee B, Kang C (2008) A humidity-adjusted maturity function for the early age strength prediction of concrete. Cem Concr Compos 30:515–523

    Article  Google Scholar 

  32. Ma W, Sample D, Martin R, Brown P (1994) Calorimetric study of cement blends containing fly ash, silica fume, and slag at elevated temperatures. Cem Concr Aggreg 16:93–99

  33. McCarter W, Starrs G, Chrisp T (2000) Electrical conductivity, diffusion, and permeability of Portland cement-based mortars. Cem Concr Res 30:1395–1400

    Article  Google Scholar 

  34. McGrath PF (1997) Development of test methods for predicting chloride penetration into high performance concrete. University of Toronto

  35. Myers JJ (2000) The use of maturity method as a quality control tool for HPC bridge decks. In: PCI/FHWA/FIB International Symposium on High Performance Concrete

  36. Naik TR (1992) Maturity of concrete: its applications and limitations, Department of Civil Engineering and Mechanics, College of Engineering report

  37. Neville AM (1996) Properties of concrete, 4th edn. John Wiley & Sons, New York

    Google Scholar 

  38. Parrott LJ, Geiker M, Gutteridge WA, Killoh D (1990) Monitoring Portland cement hydration: comparison of methods. Cem Concr Res 20:919–926

    Article  Google Scholar 

  39. Pinto R, Hover K (2000) Combined effects of silica fume, superplasticizer and temperature on setting behaviour. Mag Concr Res 52:345–352

    Article  Google Scholar 

  40. Pinto R, Schindler A (2010) Unified modeling of setting and strength development. Cem Concr Res 40:58–65

    Article  Google Scholar 

  41. Pinto RC (1997) The effect of curing temperatures on the development of mechanical properties of fresh and hardened high-strength silica fume mixtures: a maturity approach. Cornell University

  42. Plowman JM (1956) Maturity and the strength of concrete. Mag Concr Res 8:13–22

    Article  Google Scholar 

  43. Poole JL, Riding KA, Folliard KJ, Juenger MCG, Schindler AK (2007) Methods for calculating activation energy for Portland cement. ACI Mater J 104:86–94

    Google Scholar 

  44. Poole JL, Riding KA, Juenger MCG, Folliard KJ, Schindler AK (2010) Effects of supplementary cementitious materials on apparent activation energy. J ASTM Int 7:1–6. doi:10.1520/JAI102893

    Google Scholar 

  45. Presuel-Moreno F, Liu Y (2012) Temperature effect on electrical resistivity measurements on mature saturated concrete In: Corrosion 2012, Salt Lake City, UT. NACE, pp 5678–5696

  46. Radlinski M, Olek J, Nantung T (2010) Development and application of maturity method for prediction of concrete’s resistance to chloride ion penetration. Transp Res Rec 2164:105–112

    Article  Google Scholar 

  47. Sant G, Rajabipour F, Weiss J (2008) The influence of temperature on electrical conductivity measurements and maturity predictions in cementitious materials during hydration. Indian Concr J 82:7–16

    Google Scholar 

  48. Schindler AK (2002) Concrete hydration, temperature development, and setting at early-ages. PhD, The University of Texas at Austin

  49. Schindler AK, Folliard KJ (2005) Heat of hydration models for cementitious materials. ACI Mater J 102:24–33

    Google Scholar 

  50. Spragg R, Villani C, Snyder K, Bentz D, Bullard JW, Weiss J (2013) Factors that influence electrical resistivity measurements in cementitious systems. Transp Res Rec 2342:90–98

    Article  Google Scholar 

  51. Tepke D, Tikalsky PJ (2001) Concrete maturity progress: survey of departments of transportation. Transp Res Rec 1775:125–131

    Article  Google Scholar 

  52. Tepke DG, Tikalsky PJ, Scheetz BE (2004) Concrete maturity field studies for highway applications. Transp Res Rec 1893:26–36

    Article  Google Scholar 

  53. Turcry P, Loukili A, Barcelo L, Casabonne JM (2002) Can the maturity concept be used to separate the autogenous shrinkage and thermal deformation of a cement paste at early age? Cem Concr Res 32:1443–1450

    Article  Google Scholar 

  54. Villagrán Zaccardi Y, Fullea García J, Huelamo P, Di Maio A (2009) Influence of temperature and humidity on Portland cement mortar resistivity monitored with inner sensors. Mater Corros 60:294–299

    Article  Google Scholar 

  55. Voigt T, Sun Z, Shah SP (2006) Comparison of ultrasonic wave reflection method and maturity method in evaluating early-age compressive strength of mortar. Cem Concr Compos 28:307–316

    Article  Google Scholar 

  56. Volz CK, Tucker RL, Burns NH, Lew H (1981) Maturity effects on concrete strength. Cem Concr Res 11:41–50

    Article  Google Scholar 

  57. Wade SA, Nixon JM, Schindler AK, Barnes RW (2010) Effect of temperature on the setting behavior of concrete. J Mater Civ Eng 22:214–222

    Article  Google Scholar 

  58. Wei X, Xiao L (2010) Determination of activation energy of cement hydration by electrical resistivity measurement. Paper presented at the 2nd International Symposium on Service Life Design for Infrastructure, Delft, The Netherlands

  59. Weiss J, Snyder K, Bullard J, Bentz D (2012) Using a saturation function to interpret the electrical properties of partially saturated concrete. J Mater Civ Eng 25:1097–1106

    Article  Google Scholar 

  60. Wirquin E, Broda M, Duthoit B (2002) Determination of the apparent activation energy of one concrete by calorimetric and mechanical means—influence of a superplasticizer. Cem Concr Res 32:1207–1213. doi:10.1016/S0008-8846(02)00770-6

    Article  Google Scholar 

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Acknowledgments

The author is grateful for funding obtained through the Natural Sciences and Engineering Research Council of Canada (NSERC). The assistance of undergraduate student Mr. Stephen Chun for the experimental work and to Dr. Attila Zsaki for the development of the automated measurements are appreciated.

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Correspondence to Michelle R. Nokken.

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Nokken, M.R. Electrical conductivity to determine maturity and activation energy in concretes. Mater Struct 49, 2209–2221 (2016). https://doi.org/10.1617/s11527-015-0644-0

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