Skip to main content
Log in

Hydration kinetics of high-performance cementitious systems under different curing conditions

  • Original Article
  • Published:
Materials and Structures Aims and scope Submit manuscript

Abstract

Curing plays an essential role in the modern concrete technology, since it has a crucial effect on the development of concrete properties. High-performance cementitious systems are especially sensitive to the applied curing methods because of self-desiccation and high sensitivity to early-age cracking. Thus, it is of particular interest to compare the efficiency of internal curing and traditional curing techniques such as sealing and water ponding. In this study, the efficiency of different types of curing was estimated by means of isothermal calorimetry. Four different water to cement (w/c) ratios in the range of 0.21–0.45 and four types of curing were studied, including sealing, water ponding with different amount of water, internal curing by saturated lightweight aggregate and super-absorbent polymer. The hydration degree was determined using heat of hydration data. Compressive strength of the tested specimens was measured and analyzed. The results indicate that efficiency of different types of curing strongly depends on w/c ratio.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16

Similar content being viewed by others

References

  1. Price WH (1951) Factors influencing concrete strength. J Am Concr Inst 47:417–432

    Google Scholar 

  2. Meeks KW, Carino NJ (1999) Curing of high-performance concrete: Report of the state-of-the-art, NISTIR 6295

  3. Kovler K, Zhutovsky S (2006) Overview and future trends of shrinkage research. Mater Struct 39:827–847

    Article  Google Scholar 

  4. Aïtcin PC (1998) High-performance concrete, E&FN SPON

  5. Aïtcin PC, Neville AM (1993) High-performance concrete demystified. Concr Int 15:6–21

    Google Scholar 

  6. Gjorv OE (1991) Norwegian experience with condensed silica fume in concrete. In: Malhotra VM (ed) Proceedings of CANMET/ACI international workshop on the use of silica fume in concrete, Washington, pp 47–64

  7. Hansi L, Gallias JL, Salomon M (1994) Influence of the curing method on the durability of high performance concretes. In: Malhotra VM (ed) Proceedings of the third international conference “durability of concrete”, SP-145, Nice, France, pp 131–155

  8. Torii K, Kawamura M (1994) Mechanical and durability-related properties of high-strength concrete containing silica fume. In: Malhotra VM (ed) Proceedings of ACI international conference on high-performance concrete, SP-149, Farmington Hills (MI), pp 461–474

  9. Garboczi EJ (1993) Computational materials science of cement based materials. Mater Struct 26:191–195

    Article  Google Scholar 

  10. Powers TC, Brownyard TL (1948) Studies of the physical properties of hardened Portland cement paste (PCA Bulletin 22). Portland Cement Association, Skokie

  11. Zhutovsky S, Kovler K (2010) Chemical shrinkage of high-strength/high-performance cementitious materials. Int Rev Civil Eng 1:110–118

    Google Scholar 

  12. Bentz DP, Snyder KA, Stutzman PE (1997) Microstructural modeling of self-desiccation during hydration. In: Persson B, Fagerlund G (eds) Proceeding of an international research seminar on self-desiccation and its importance in concrete technology, Lund, Sweden, pp 132–140

  13. Report of JCI Committee on Autogenous Shrinkage of Concrete (1998). In: E Tazawa (ed) Proceedings of international workshop on autogenous shrinkage of concrete. Japan Concrete Institute, Hiroshima, pp 5–28

  14. Patel R, Killoh D, Parrott L, Gutteridge W (1988) Influence of curing at different relative humidities upon compound reactions and porosity in Portland cement paste. Mater Struct 21:192–197

    Article  Google Scholar 

  15. Powers TC (1947) A discussion of cement hydration in relation to the curing of concrete. Proc Highw Res Board 27:178–188

    Google Scholar 

  16. Pailère AM, Buil M, Serrano JJ (1989) Effect of fiber addition on the autogenous shrinkage of silica fume concrete. ACI Mater J 86:139–144

    Google Scholar 

  17. Jensen OM, Hansen PF (1995) Autogenous relative humidity change in silica fume-modified cement paste. Adv Cem Res 7:33–38

    Article  Google Scholar 

  18. Jensen OM (1995) Thermodynamic limitation of self-desiccation. Cem Concr Res 25:157–164

    Article  Google Scholar 

  19. Mjörnell KN (1997) A model on self-desiccation in high-performance concrete. In: Persson B, Fagerlund G (eds) Proceedings of an international research seminar on self-desiccation and its importance in concrete technology, Lund, Sweden, pp 141–157

  20. Koenders EAB, van Breugel K (1997) Modeling dimensional changes in low water/cement ratio pastes. In: Persson B, Fagerlund G (eds) Proceedings of an international research seminar on self-desiccation and its importance in concrete technology, Lund, Sweden, pp 158–173

  21. Kovler K, Jensen OM (2005) Novel technologies of concrete curing. Concr Int 27:39–42

    Google Scholar 

  22. Philleo R (1991) Concrete science and reality. In: Skalny JP, Mindess S (eds) Materials science of concrete II. American Ceramic Society, Westerville (OH), pp 1–8

    Google Scholar 

  23. Vaysburd AM (1996) Durability of lightweight concrete bridges in severe environments. Concr Int 18:33–38

    Google Scholar 

  24. Weber S, Reinhardt HW (1996) A blend of aggregates to support curing of concrete. In: Holand I, Hammer TA, Fluge F (eds) Proceedings of international symposium on structural lightweight concrete, Sandefjord, Norway, pp 662–671

  25. Weber S, Reinhardt HW (1997) A new generation of high performance concrete: concrete with autogenous curing. Adv Cem Based Mater 6:59–68

    Article  Google Scholar 

  26. Bentur A, Igarashi S, Kovler K (1999) Control of autogenous shrinkage stresses and cracking in high strength concretes. In: Proceedings of 5th international symposium of high strength/high performance concrete, Sandefjord, Norway, pp 1017–1026

  27. Lura P, van Breugel K (2000) Moisture exchange as a basic phenomenon to understand volume changes of lightweight aggregate concrete at early age. In: Baroghel-Bouny V, Aitcin PC (eds) Proceedings of international workshop on shrinkage of concrete, Paris, pp 533–546

  28. Zhutovsky S, Kovler K, Bentur A (2002) Efficiency of lightweight aggregates for internal curing of high strength concrete to eliminate autogenous shrinkage. Mater Struct 35:97–101

    Google Scholar 

  29. Schwesinger P, Sickert G (2000) Reducing shrinkage in HPC by internal curing by using pre-soaked LWA. In: Proceedings of international workshop on control of cracking in early-age concrete. Tohoku University, Sendai, pp 313–318

  30. van Breugel K, Outwerk H, de Vries J (2000) Effect of mixture composition and size effect on shrinkage of high strength concrete. In: Baroghel-Bouny V, Aitcin PC (eds) Proceedings of international workshop on shrinkage of concrete, Paris, pp 161–177

  31. RILEM TC-196 (2007) Internal curing of concrete, state-of-the-art report of RILEM technical committee 196-ICC. In: Kovler K, Jensen OM (eds) RILEM Publications S.A.R.L. France, Bagneux

  32. Zhutovsky S, Kovler K, Bentur A (2004) Influence of cement paste matrix properties on the autogenous curing of high-performance concrete. Cem Concr Compos 26:499–507

    Article  Google Scholar 

  33. Zhutovsky S, Kovler K (2012) Effect of internal curing on durability-related properties of high performance concrete. Cem Concr Res 42:20–26

    Article  Google Scholar 

  34. Jensen OM, Hansen PF (2001) Water-entrained cement-based materials, I: principles and theoretical background. Cem Concr Res 31:647–654

    Article  Google Scholar 

  35. Jensen OM, Hansen PF (2002) Water-entrained cement-based materials II: experimental observations. Cem Concr Res 32:973–978

    Article  Google Scholar 

  36. Mohr BJ, Premenko L, Nanko H, Kurtis KE (2005) Examination of wood-derived powders and fibers for internal curing of cement-based materials. In: Persson B, Bentz DP, Nilsson LO (eds) Proceedings of 4th international seminar on self-desiccation and its importance in concrete technology, Gaithersburg (MD), USA, pp 229–244

  37. Maruyama I, Sato R (2005) A trial of reducing autogenous shrinkage by recycled aggregate. In: Persson B, Bentz DP, Nilsson LO (eds) Proceedings 4th international seminar on self-desiccation and its importance in concrete technology, Gaithersburg (MD), USA, pp 264–270

  38. Zhutovsky S, Kovler K, Bentur A (2011) Revisiting the protected paste volume concept for internal curing of high-strength concretes. Cem Concr Res 41:981–986

    Article  Google Scholar 

  39. Soroka I (1979) Portland cement paste and concrete. The Macmillan Press Ltd., London

  40. Hewlett PC (2004) Lea’s chemistry of cement and concrete, 4th edn. Butterworth-Heinemann, Oxford

  41. Johansen NA, Millard MJ, Mezencevova AM, Garas VY, Kurtis KE (2009) New method for determination of absorption capacity of internal curing agents. Cem Concr Res 39:65–68

    Article  Google Scholar 

  42. Castro J, De la Varga I, Weiss J (2012) Using isothermal calorimetry to assess the water absorbed by fine LWA during mixing. J Mater Civ Eng 24:996–1005

    Article  Google Scholar 

  43. Wyrzykowsky, M, Lura P (2012) Controlling the coefficient of thermal expansion of cementitious materials—a new application for superabsorbent polymers. Cem Concr Compos. 10.1016/j.cemconcomp.2012.08.010

  44. Geiker M (1983) Measurements of chemical shrinkage and a systematic evaluation of hydration curves by means of the dispersion model. PhD dissertation, Technical University of Denmark

  45. Kovler K (1994) Testing system for determining the mechanical behavior of early age concrete under restrained and free uniaxial shrinkage. Mater Struct 27:324–330

    Article  Google Scholar 

  46. Taylor HFW (1997) Cement chemistry, 2nd edn. Thomas Telford Publishing, London

    Book  Google Scholar 

  47. Powers TC (1958) The physical structure and engineering properties of concrete, PCA Bulletin 90. Portland Cement Association, Skokie

  48. Scrivener KL, Nonat A (2011) Hydration of cementitious materials, present and future. Cem Concr Res 41:651–665

    Article  Google Scholar 

  49. Damidot D, Nonat A (1994) C3S hydration in diluted and stirred suspensions: (I) Study of the two kinetic steps. Adv Cem Res 6:27–35

    Article  Google Scholar 

  50. Mönnig S (2009) Superabsorbing additions in concrete: applications, modelling and comparison of different internal water sources. Dissertation, Stuttgart University

  51. Hasholt MT, Jensen OM, Kovler K, Zhutovsky S (2012) Can superabsorent polymers mitigate autogenous shrinkage of internally cured concrete without compromising the strength? Constr Build Mater 31:226–230

    Article  Google Scholar 

  52. Powers TC (1960) Physical properties of cement paste. In: Proceedings of the fourth international symposium on the chemistry of cement, session V, paper, V–1, Washington, pp 577–613

Download references

Acknowledgments

The authors acknowledge German-Israeli Foundation for Scientific Research and Development, and Jewish Communities of Germany Research Fund for supporting the study. The assistance of Dr. Dmitry Mologin in carrying out of the experiments is greatly acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Semion Zhutovsky.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhutovsky, S., Kovler, K. Hydration kinetics of high-performance cementitious systems under different curing conditions. Mater Struct 46, 1599–1611 (2013). https://doi.org/10.1617/s11527-012-0001-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1617/s11527-012-0001-5

Keywords

Navigation