Skip to main content
Log in

Coupled AC impedance and thermomechanical analysis of freezing phenomena in cement paste

  • Original Article
  • Published:
Materials and Structures Aims and scope Submit manuscript

Abstract

Freezing and thawing properties of cement paste were studied using an alternating current impedance spectroscopy (ACIS) technique coupled with the thermomechanical analysis (TMA). The measurements from the ACIS were analyzed in association with the length change of the cement paste determined by TMA. The micro-scale behavior of cement paste observed by the ACIS technique was well correlated with the residual expansion of cement paste after the freezing and thawing cycle. The efficacy of the ACIS technique for assessing the durability of cement paste to frost action was confirmed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Bager DH, Sellevold EJ (1986) Ice formation in hardened cement paste—Part I: Room temperature cured pastes with variable moisture contents. Cem Concr Res 16:709–720

    Article  Google Scholar 

  2. Christensen BJ, Coverdale RT, Olson RA, Ford SJ, Garboczi EJ, Jennings HM, Mason TO (1994) Impedance spectroscopy of hydrating cement-based materials: measurement, interpretation, and application. J Am Ceram Soc 77(11):2789–2804

    Article  Google Scholar 

  3. Helmuth RA (1960) Capillary size restrictions on ice formation in hardened Portland cement paste. In: Fourth international symposium on the chemistry of cement, Washington, DC, USA, pp 855–869

  4. Litvan GG (1972) Phase transitions of adsorbates: IV. Mechanism of frost action in hardened cement paste. J Am Ceram Soc 55(1):38–42

    Article  Google Scholar 

  5. McCarter WJ, Brousseau R (1990) The A.C. response of hardened cement paste. Cem Concr Res 20:891–900

    Article  Google Scholar 

  6. McCarter WJ, Garvin S, Bouzid N (1988) Impedance measurements on cement paste. J Mater Sci Lett 7:1056–1057

    Article  Google Scholar 

  7. Macphee DE, Sinclair DC, Cormack SL (1997) Development of an equivalent circuit model for cement pastes from microstructural considerations. J Am Ceram Soc 80(11):2876–2884

    Article  Google Scholar 

  8. Olson RA, Christensen BJ, Coverdale RT, Ford SJ, Moss GM, Jennings HM, Masonand TO, Garboczi EJ (1995) Interpretation of the impedance spectroscopy of cement paste via computer modeling. J Mater Sci 30(20):5078–5086

    Article  Google Scholar 

  9. Perron S, Beaudoin JJ (2002) Freezing of water in Portland cement paste—an AC impedance spectroscopy study. Cem Concr Compos 24:467–475

    Article  Google Scholar 

  10. Powers TC, Helmuth RA (1953) Theory of volume changes in hardened Portland cement paste during freezing. Mater Constr 46:285–297

    Google Scholar 

  11. Sato T, Beaudoin JJ (2003) An AC impedence spectroscopy study of freezing phenomena in wollastonite micro-fiber reinforced cement paste. In: Proceedings of the international symposium on role of cement science in sustainable development, Scotland, UK, Sep 3–4, pp 379–388

  12. Setzer MJ (1997) Action of frost and deicing chemicals: basic phenomena and testing. In: Marchand J, Pigeon M, Setzer M (eds) Freeze-thaw durability of concrete. E & FN Spon, London, pp 3–22

    Google Scholar 

  13. Xie P, Gu P, Xu Z, Beaudoin JJ (1993) A rationalized A.C. impedance model for microstructural characterization of hydrating cement systems. Cem Concr Res 23:359–367

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Taijiro Sato.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sato, T., Beaudoin, J.J. Coupled AC impedance and thermomechanical analysis of freezing phenomena in cement paste. Mater Struct 44, 405–414 (2011). https://doi.org/10.1617/s11527-010-9635-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1617/s11527-010-9635-3

Keywords

Navigation