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A model predicting carbonation depth of concrete containing silica fume

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Abstract

Silica fume (SF) has been used since long as a mineral admixture to improve durability and produce high strength and high performance concrete. Due to the pozzolanic reaction between calcium hydroxide and silica fume, compared with ordinary Portland cement, the carbonation of concrete containing silica fume is much more complex. In this paper, based on a multi-component concept, a numerical model is built which can predict the carbonation of concrete containing silica fume. The proposed model starts with the mix proportions of concrete and considers both Portland cement hydration reaction and pozzolanic reaction. The amount of hydration products which are susceptible to carbonate, such as calcium hydroxide (CH) and calcium silicate hydrate (CSH), as well as porosity can be obtained as associated results of the proposed model during the hydration period. The influence of water-binder ratio and silica fume content on carbonation is considered. The predicted results agree well with experimental results.

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References

  1. Kumar Metha P (2006) Concrete-microstructure, properties and materials. MacGraw-Hill, New York

    Google Scholar 

  2. Matala S (1997) Carbonation mechanism in the granulate blast furnace slag concrete. In: Chandra S (ed) Proceedings of tenth international congress chemistry of cement. Gothenburg, 1997

  3. Papadakis VG, Vayenas CG, Fardis MN (1991) Fundamental modeling and experimental investigation of concrete carbonation. ACI Mater J 88:363–373

    Google Scholar 

  4. Nagataki S, Ohga H, Kim EK (1986)Effects of curing conditions on the carbonation of concrete with fly ash and the corrosion of reinforcement in long-term tests. In: Proceedings of second international conference on the use of fly ash, silica fume, slag and natural pozzolans in concrete, SP 91, Madrid, 1986

  5. Nagataki S, Mansur MA, Ohga H (1988) Carbonation of mortar in relation to ferrocement construction. ACI Mater J 85:17–25

    Google Scholar 

  6. Tuutti K (1982) Corrosion of steel in concrete. Swedish Cement and Concrete Research Institute, Stockholm

    Google Scholar 

  7. Papadakis VG, Vayenas CG, Fardis MN (1991) Physical and chemical characteristics affecting the durability of concrete. ACI Mater J 88:186–196

    Google Scholar 

  8. Papadakis VG, Vayenas CG, Fardis MN (1991) Experimental investigation and mathematical modeling of the concrete carbonation problem. Chem Eng Sci 46:1333–1338. doi:10.1016/0009-2509(91)85060-B

    Article  Google Scholar 

  9. Jiang LX, Zhang Y, Liu YQ, Zhang X, Xie HF, Wang J (1996) Experiment study and calculation formula of carbonation depth. Chin J Concr 4:12–16

    Google Scholar 

  10. Jiang L, Lin B, Cai Y (2000) A model for predicting carbonation of high volume concrete, cement and concrete research. Cement Concr Res 30:699–702. doi:10.1016/S0008-8846(00)00227-1

    Article  Google Scholar 

  11. Papadakis VG (1999) Experimental investigation and theoretical modeling of silica fume activity in concrete. Cement Concr Res 29:79–86. doi:10.1016/S0008-8846(98)00171-9

    Article  Google Scholar 

  12. Papadakis VG, Tsimas S (2000) Effect of supplementary cementing materials on concrete resistance against carbonation and chloride ingress. Cement Concr Res 30:291–299. doi:10.1016/S0008-8846(99)00249-5

    Article  Google Scholar 

  13. Papadakis VG (1999) Effect of fly ash on Portland cement systems, Part I: low-calcium fly ash. Cement Concr Res 29:1727–1736. doi:10.1016/S0008-8846(99)00153-2

    Article  Google Scholar 

  14. Papadakis VG (2000) Effect of fly ash on Portland cement systems, Part II: high calcium fly ash. Cement Concr Res 30:1647–1654. doi:10.1016/S0008-8846(00)00388-4

    Article  Google Scholar 

  15. Papadakis VG, Vayenas CG, Fardis MN (1992) Hydration and carbonation of pozzolanic cements. ACI Mater J 89:119–130

    Google Scholar 

  16. Rosin P, Rammler E (1933) Regularities in the distribution of cement particles. J Inst Fuel 7:29–33

    Google Scholar 

  17. Navi P, Pignat C (1996) Simulation of cement hydration and the connectivity of the capillary pore space. Adv Cement Base Mater 4:58–67

    Google Scholar 

  18. Park K-B, Noguchib T, Plawsky J (2005) Modeling of hydration reaction using neural network to predict the average properties of cement paste. Cement Concr Res 35:1676–1684. doi:10.1016/j.cemconres.2004.08.004

    Article  Google Scholar 

  19. Tomosawa F (1997) Development of a kinetic model for hydration of cement. In: Chandra S (ed) Proceedings of tenth international congress chemistry of cement. Gothenburg, 1997

  20. Brouwers HJH (2004) The work of powers and Brownyard revisited: part 1. Cement Concr Res 34:1697–1716. doi:10.1016/j.cemconres.2004.05.031

    Article  Google Scholar 

  21. Maruyama I (2003) Numerical model for hydration of Portland cement. In: Proceedings of the international conference of civil and environmental engineering, Hiroshima, 2003

  22. Takemoto K, Uchikawa H (1980) Hydration of pozzolanic cement. In: Proceedings of the 7th international congress on chemistry of cement, Paris, 1980

  23. Saeki T, Monteiro PJM (2005) A model to predict the amount of calcium hydroxide in concrete containing mineral admixture. Cement Concr Res 35:1914–1921. doi:10.1016/j.cemconres.2004.11.018

    Article  Google Scholar 

  24. Pane I, Hansen W (2005) Investigation of blended cement hydration by isothermal calorimetry and thermal analysis. Cement Concr Res 35:1155–1164. doi:10.1016/j.cemconres.2004.10.027

    Article  Google Scholar 

  25. Maruyama I, Masahiro S, Ryoichi S (2005) Prediction of temperature in ultra high-strength concrete based on temperature dependent hydration model. In: Proceedings of 7th international symposium on high performance concrete, 2005

  26. Jensen OM, Hansen PF (2001) Water-entrained cement-based materials, I: principles and theoretical background. Cement Concr Res 31:647–654. doi:10.1016/S0008-8846(01)00463-X

    Article  Google Scholar 

  27. Matsushita T, Hoshino S, Maruyama I, Noguchi T, Yamada K (2007) Effect of curing temperature and water to cement ratio on hydration of cement compounds. In: Beaudoin J (ed) Proceedings of 12th international congress chemistry of cement, Montreal, 2007

  28. Goldman A, Bentur A (1989) Bond effects in high-strength silica fume concretes. ACI Mater J 86:440–449

    Google Scholar 

  29. Houst YF (1996) The role of moisture in the carbonation of cementitious materials, Internationale Zeitschrift für Bauinstandsetzen 2. Jahrgang 1:49–66

    Google Scholar 

  30. Parrot LJ (1991) Carbonation, moisture and empty pores. Adv Cement Res 4:111–118

    Google Scholar 

  31. Sulapha P, Wong SF, Wee TH, Swaddiwudhipong S (2003) Carbonation of concrete containing mineral admixtures. J Mater Civ Eng 15:134–143. doi:10.1061/(ASCE)0899-1561(2003)15:2(134)

    Article  Google Scholar 

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Acknowledgement

The authors are grateful to the reviewers for their valuable comments.

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Correspondence to Han-Seung Lee.

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Wang, XY., Lee, HS. A model predicting carbonation depth of concrete containing silica fume. Mater Struct 42, 691–704 (2009). https://doi.org/10.1617/s11527-008-9413-7

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  • DOI: https://doi.org/10.1617/s11527-008-9413-7

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