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Analysis of structural and electrical properties on rubidium doped barium titanate ceramics

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Abstract

Pure and Rb-doped Barium Titanate with various concentrations (1 mol%, 5 mol%, and 10 mol%) were synthesized via solid-state reaction method and are reported. The effect of Rb substitution on the structure, ferroelectric and dielectric properties of Barium Titanate (BT) was systematically investigated. The XRD analysis confirmed the presence of a tetragonal structure with the P4mm space group. FTIR analysis confirmed the presence of Rb on the BT lattice. The dielectric and ferroelectric properties have shown the introduction of additional dipoles into the lattice enhances the polarization and lowers the energy barrier for the domain wall motion, making it a good candidate for energy storage devices and low-power applications.

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The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

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All authors contributed to the material preparation, data collection and analysis. The first draft of the manuscript was written by Ms. P.S. Sowmiya. Supervision and scientific discussions were performed by Dr. K. Prabha, Dr. P. S. Mayagopal and Dr. N.P. Rajesh. All authors read and approved the final manuscript. The authors declare that no fund, grant or other support were received during the preparation of this manuscript.

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Correspondence to N. P. Rajesh.

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Sowmiya, P.S., Prabha, K., Mayagopal, P.S. et al. Analysis of structural and electrical properties on rubidium doped barium titanate ceramics. MRS Advances (2024). https://doi.org/10.1557/s43580-024-00858-5

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