Skip to main content
Log in

Application of molasses in improving water purification efficiency of diatomaceous earth waste ceramic membranes

  • Original Paper
  • Published:
MRS Advances Aims and scope Submit manuscript

Abstract

The World Health Organization predicts that 90.0% of the 2.3 million people who die annually due to water-borne diseases come from developing countries. At the same time fluorosis occurrence in the world’s geological fluoride belts has left many people maimed due to drinking highly fluoridated water. This work reports on the use of molasses in making carbon-activated diatomaceous earth waste (DE-waste) ceramic membranes with improved mechanical strength and water purification efficiency. The fabricated diatomaceous membranes were soaked in molasses for 24.0 h and fired at 600.0 for 3.0 h. The carbon-activated membranes were used to filter water contaminated with Escherichia coli, Rotavirus, and sodium fluoride. The activated carbon obtained in this work had a bulk density of 450.0 kg/m3 and it reduced the porosity of the DE-waste membranes by 18.0%. The activated carbon improved the modulus of rupture (MOR) of the DE-waste membrane by 47.8% and the average pore size of the active DE-waste membrane was 50.0 nm. The filtration process was found to be dependent on the contaminant’s size, concentration, and the external pressure applied to the water during the filtration process. The filtration efficiency of > 99.9 in E. coli was dependent on concentration and pressure. Membranes reported efficiency of 97.1% and 98.9% in deflouridation and Rotavirus filtration. Thus, molasses is potential material in fabrication of water membranes.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

Data availability

The data will be available at the submission of the paper.

References

  1. A. Parsai, V. Rokade, Water quality monitoring infrastructure for tackling water-borne diseases in the state of Madhya Pradesh, India and its implication on the sustainable development goals, in The relevance of hygiene to health in developing countries. ed. by N. Potgieter, A. Ndama, T. Hoffman (IntechOpen, London, 2019), p.118

    Google Scholar 

  2. M.D. Sobsey, C.E. Stauber, L.M. Casanova, J.M. Brown, M.A. Elliott, Point of use household drinking water filtration: a practical, effective solution for providing sustained access to safe drinking water in the developing world. Environ. Sci. Technol. 42(12), 4261–4267 (2008)

    Article  CAS  Google Scholar 

  3. P.R. Hunter, Household water treatment in developing countries: comparing different intervention types using meta-regression. Environ. Sci. Technol. 43(23), 8991–8997 (2009)

    Article  CAS  Google Scholar 

  4. T.F. Clasen, J. Brown, S. Collin, O. Suntura, S. Cairncross, Reducing diarrhea through the use of household-based ceramic water filters: a randomized, controlled trial in rural Bolivia. Am. J. Trop. Med. Hyg. 70(6), 651–657 (2004)

    Article  Google Scholar 

  5. I. Yakub et al., Porosity, flow, and filtration characteristics of frustum-shaped ceramic water filters. J. Environ. Eng. 139(7), 986–994 (2013). https://doi.org/10.1061/(ASCE)EE.1943-7870.0000669

    Article  CAS  Google Scholar 

  6. J.J. Murray and W. H. Organization, Appropriate use of fluorides for human health. World Health Organization (1986)

  7. J. Fito, H. Said, S. Feleke, A. Worku, Fluoride removal from aqueous solution onto activated carbon of Catha edulis through the adsorption treatment technology. Environ. Syst. Res. 8(1), 25 (2019)

    Article  Google Scholar 

  8. E.N. Nyanchaga, T. Bailey, Fluoride contamination in drinking water in the Rift Valley, Kenya and evaluation of the efficiency of a locally manufactured defluoridation filter. J. Civ. Eng. JKUAT 8(1), 79–88 (2003)

    Google Scholar 

  9. C.A. Bower, J.T. Hatcher, Adsorption of fluoride by soils and minerals. Soil Sci. 103(3), 151–154 (1967)

    Article  CAS  Google Scholar 

  10. M. Mohapatra, S. Anand, B.K. Mishra, D.E. Giles, P. Singh, Review of fluoride removal from drinking water. J. Environ. Manage. 91(1), 67–77 (2009)

    Article  CAS  Google Scholar 

  11. J.A.I. Omueti, R.L. Jones, Fluoride adsorption by illinois soils. J. Soil Sci. 28(4), 564–572 (1977). https://doi.org/10.1111/j.1365-2389.1977.tb02264.x

    Article  CAS  Google Scholar 

  12. A.K. Chaturvedi, K.C. Pathak, V.N. Singh, Fluoride removal from water by adsorption on china clay. Appl. Clay Sci. 3(4), 337–346 (1988)

    Article  CAS  Google Scholar 

  13. A.K. Chaturvedi, K.P. Yadava, K.C. Pathak, V.N. Singh, Defluoridation of water by adsorption on fly ash. Water. Air. Soil Pollut. 49(1–2), 51–61 (1990)

    Article  CAS  Google Scholar 

  14. S. Hauge, R. Österberg, K. Bjorvatn, K.A. Selvig, Defluoridation of drinking water with pottery: effect of firing temperature. Eur. J. Oral Sci. 102(6), 329–333 (1994)

    Article  CAS  Google Scholar 

  15. C. Zevenbergen, L.P. Van Reeuwijk, G. Frapporti, R.J. Louws, R.D. Schuiling, A simple method for defluoridation of drinking water at village level by adsorption on Ando soil in Kenya. Sci. Total Environ. 188(2–3), 225–232 (1996)

    Article  CAS  Google Scholar 

  16. A.A. Izuagie, W.M. Gitari, J.R. Gumbo, Defluoridation of groundwater using diatomaceous earth: optimization of adsorption conditions, kinetics and leached metals risk assessment. Desalination Water Treat. 57(36), 16745–16757 (2016)

    CAS  Google Scholar 

  17. M.T. Simiyu, F.W. Nyongesa, B.O. Aduda, Z. Birech, G. Mwebaze, Application of an organic plant-derived binder in the fabrication of diatomaceous earth waste-based membranes for water purification systems. MRS Adv. (2020). https://doi.org/10.1557/adv.2020.123

    Article  Google Scholar 

  18. M.T. Simiyu et al. Use of organic binders to enhance defluoridation and pathogen removal efficiency of diatomaceous earth-based ceramic filters. Afr. J. Phys. Sci. 6 ISSN 2313–3317, (2021)

  19. G.K. McConell, B.J. Canny, M.C. Daddo, M.J. Nance, R.J. Snow, Effect of carbohydrate ingestion on glucose kinetics and muscle metabolism during intense endurance exercise. J. Appl. Physiol. 89(5), 1690–1698 (2000). https://doi.org/10.1152/jappl.2000.89.5.1690

    Article  CAS  Google Scholar 

  20. B.O. Aduda, F.W. Nyongesa, G. Obado, Improving the green and fired fracture strength of a kaolinte ceramic using some vegetable syrup. J. Mater. Sci. Lett. 18(20), 1653–1655 (1999)

    Article  CAS  Google Scholar 

  21. M.W. LeChevallier et al., Aeromonas sobria in chlorinated drinking water supplies. Microb. Ecol. 8(4), 325–333 (1982)

    Article  CAS  Google Scholar 

  22. J.F. Ma, N. Yamaji, Silicon uptake and accumulation in higher plants. Trends Plant Sci. 11(8), 392–397 (2006)

    Article  CAS  Google Scholar 

  23. L. Kittigul et al., An improved method for concentrating rotavirus from water samples. Mem. Inst. Oswaldo Cruz 96(6), 815–821 (2001). https://doi.org/10.1590/S0074-02762001000600013

    Article  CAS  Google Scholar 

  24. N. Kiulia, N. Hofstra, L. Vermeulen, M. Obara, G. Medema, J. Rose, Global occurrence and emission of rotaviruses to surface waters. Pathogens 4(2), 229–255 (2015). https://doi.org/10.3390/pathogens4020229

    Article  Google Scholar 

  25. K. Farkas, A. Varsani, L. Pang, Adsorption of rotavirus, MS2 bacteriophage and surface-modified silica nanoparticles to hydrophobic matter. Food Environ. Virol. 7(3), 261–268 (2015). https://doi.org/10.1007/s12560-014-9171-3

    Article  CAS  Google Scholar 

  26. Y.K. Siong, J. Idris, M. Atabaki, Performance of activated carbon in water filters. Water Resources (2013)

Download references

Funding

We wish to thank the International Science Program (ISP), the Gandhi Smarak Nidhi Foundation, and Kenya National Research Fund for their financial support. We further thank the African School Physics for mentorship.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mary T. Simiyu.

Ethics declarations

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Simiyu, M.T., Nyongesa, F.W., Aduda, B.O. et al. Application of molasses in improving water purification efficiency of diatomaceous earth waste ceramic membranes. MRS Advances 8, 538–544 (2023). https://doi.org/10.1557/s43580-023-00537-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/s43580-023-00537-x

Navigation