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Formability of low-molecular weight polyethylene oxide reinforced by tempo-oxidized nanocellulose for lithium-ion battery solid polymer electrolyte

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Abstract

Utilizing low-molecular weight polyethylene oxide (L-PEO) for SPE using free-solvent casting technique presented a challenge in terms of electrochemical properties and formability issues. In this study, TEMPO-oxidized NC is utilized as a reinforcing agent to increase free volume and segmental motion of a solid-state L-PEO composite, which allows Li+ ion transport and prevents mechanical instability. During the breaking-forming process of Li–O bonds, ion transport occurs at a 40 EO/Li molar ratio, which is stabilized by NC structural network via intrachain or interchain hooping. The ion transport of the SPE-C electrolyte membrane fullfill Arrhenius behavior with increasing ionic conductivity.

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Acknowledgments

The authors are grateful to the Japan Society for the Promotion of Science for financial support of this work through the JSPS RONPAKU Program and the BRIN-JSPS Bilateral Project. The authors gratefully recognize the Advanced Characterization Laboratories in Serpong, the Research Center for Advanced Materials at the National Research and Innovation Agency, and Osaka University for their facilities and technical assistance.

Funding

This work was supported by the Japan Society for The Promotion of Science in the form of RONPAKU Program, the BRIN-JSPS Bilateral Project and Research Center for Advanced Material, and the National Research and Innovation Agency.

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Authors and Affiliations

  1. Research Center for Advanced Materials, National Research and Innovation Agency (BRIN), South Tangerang, 15314, Banten, Indonesia

    Qolby Sabrina, Riyani Tri Yulianti, Khusnul Khotimah, Achmad Subhan, Nurhalis Majid & Rike Yudianti

  2. Research Center for Biomass and Bioproducts, National Research and Innovation Agency of Indonesia (BRIN), Cibinong, 16911, Indonesia

    Nanang Masruchin

  3. Department of Applied Chemistry, Graduate School of Engineering, Osaka University Suita, Osaka, 565-0871, Japan

    Qolby Sabrina, Akihide Sugawara, Yu-I. Hsu & Hiroshi Uyama

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  1. Qolby Sabrina
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Contributions

QS: contributed to conceptualization, methodology, visualization, and writing of the original draft. RTY, KK, and NM: contributed to data curation. AS: carried out measurements. NM, AS, and Y-IH: contributed to resources and supervision. RY: contributed to conceptualization, visualization, writing of the original draft, and supervision. HU: contributed to conceptualization, supervision, and funding acquisition.

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Correspondence to Qolby Sabrina.

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Sabrina, Q., Tri Yulianti, R., Khotimah, K. et al. Formability of low-molecular weight polyethylene oxide reinforced by tempo-oxidized nanocellulose for lithium-ion battery solid polymer electrolyte. MRS Communications (2024). https://doi.org/10.1557/s43579-024-00514-x

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