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Polysilicon TFTs fabricated using poly-tetrasilane ink

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Abstract

In the last decade, cyclopentasilane (CPS) and poly-CPS have been developed as precursors of silicon layer in the fabrication of high-performance polysilicon thin-film transistors (TFTs). Their synthesis, however, has required multiple reactions and high-cost reagents, which has until now created major bottle necks in the supply and development of CPS-based devices. In this report, NMOS and PMOS polysilicon TFTs were fabricated using n-tetrasilane polymerized with novel single-step reaction. TFTs fabricated using poly-TTS-based ink exhibited mobility of approximately 60 cm2 V−1 s−1 for PMOS and 160 cm2 V−1 s−1 for NMOS, which is equivalent to TFTs fabricated using poly-CPS ink.

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References

  1. T. Shimoda, Y. Matsuki, M. Furusawa, T. Aoki, I. Yudasaka, H. Tanaka, H. Iwasawa, D. Wang, M. Miyasaka, Y. Takeuchi, Solution-processed silicon films and transistors. Nature 440, 783 (2006)

    Article  CAS  Google Scholar 

  2. M. Trifunovic, T. Shimoda, R. Ishihara, Solution-processed polycrystalline silicon on paper. Appl. Phys. Lett. 106, 163502 (2015)

    Article  Google Scholar 

  3. M. Trifunovic, P.M. Sberna, T. Shimoda, R. Ishihara, N solution-based polycrystalline silicon transistors produced on a paper substrate. npj Flex. Electron. (2017). https://doi.org/10.1038/s41528-017-0013-x

    Article  Google Scholar 

  4. R. Ishihara, V. Rana, M. He, Y. Hiroshima, S. Inoue, W. Metselaar, K. Beenakker, High performance n- and p-channel strained single grain silicon TFTs using excimer laser. Solid State Electron. 52, 353 (2008)

    Article  CAS  Google Scholar 

  5. T. Masuda, H. Takagishi, K. Yamazaki, T. Shimoda, Direct imprinting of liquid silicon. ACS Appl. Mater. Interfaces 8(15), 9969–9976 (2016)

    Article  CAS  Google Scholar 

  6. T. Masuda, N. Sotani, H. Hamada, Y. Matsuki, T. Shimoda, Fabrication of solution-processed hydrogenated amorphous silicon single-junction solar cells. Appl. Phys. Lett. 100(25), 253908 (2012)

    Article  Google Scholar 

  7. T. Masuda, N. Tatsuda, K. Yano, T. Shimoda, Silicon deposition in nanopores using a liquid precursor. Sci. Rep. 6(1), 37689 (2016)

    Article  CAS  Google Scholar 

  8. T. Masuda, M. Nakayama, K. Saito, H. Katayama, A. Terakawa, Inkjet printing of liquid silicon. Macromol. Rapid Commun. 41, 2000362 (2020)

    Article  CAS  Google Scholar 

  9. T. Masuda, M. Nakayama, K. Saito, H. Katayama, A. Terakawa, A cyclopentasilane–borane compound as a liquid precursor for p-type semiconducting Si. J. Mater. Chem. C 9, 5387 (2021)

    Article  CAS  Google Scholar 

  10. T. Masuda, M. Mori, Direct writing of silicon nanostructures using liquid-phase electron beam induced deposition of hydrosilanes. Nanotechnology 32, 195301 (2021)

    Article  CAS  Google Scholar 

  11. M. Ito, A. Kamath, Fabrication and characterization of entirely inkjet-printed polysilicon thin film transistors. Flex. Print. Electron. 6, 015001 (2021)

    Article  CAS  Google Scholar 

  12. M. Ito, A. Kamath, Slot-die coating of silicon ink for volume production of CMOS polysilicon TFTs. Jpn. J. Appl. Phys. 60, 101001 (2021)

    Article  CAS  Google Scholar 

  13. E. Hengge, G. Bauer, Cyclopentasilane, the first unsubstituted cyclic silicon hydride. Angew. Chem. Int. Ed. 12, 316 (1973)

    Article  Google Scholar 

  14. W. Guo, V. Dioumaev, J. Rockenberger, B. Ridley, Polysilane compositions, methods for their synthesis and films formed therefrom, US-7723457-B1

  15. K. Kunze, G. Nyce, W. Guo, Methods of polymerizing silanes and cyclosilanes using N-heterocyclic carbenes and metal complexes having N-heterocyclic carbene ligands, US-8900654-B2

  16. M. Gerwig, A. Shaukat, D. Neubert, S. Polster, U. Böhme, G. Franze, M. Rosenkranz, A. Popov, I. Ponomarev, M. Jank, C. Viehweger, E. Brendler, L. Frey, P. Kroll, E. Kroke, From cyclopentasilane to thin-film transistors. Adv. Electron. Mater. 7, 2000422 (2021)

    Article  CAS  Google Scholar 

  17. T. Masuda, Y. Matsuki, T. Shimoda, Pyrolytic transformation from polydihydrosilane to hydrogenated amorphous silicon film. Thin Solid Films 520(21), 6603–6607 (2012)

    Article  CAS  Google Scholar 

  18. W. Beyer, Diffusion and evolution of hydrogen in hydrogenated amorphous and microcrystalline silicon. Sol. Energy Mater. Sol. Cells 78, 235 (2006)

    Article  Google Scholar 

  19. Y. Sugawara, Y. Uraoka, H. Yano, T. Hatayama, T. Fuyuki, A. Mimura, Crystallization of double-layered silicon thin films by solid green laser annealing and its application to low temperature poly-Si thin film transistors. ECS Trans. 3, 8 (2006)

    Article  Google Scholar 

  20. T.-C. Chang, Y.-C. Tsao, P.-H. Chen, M.-C. Tai, S.-P. Huang, W.-C. Su, G.-F. Chen, Flexible low-temperature polycrystalline silicon thin-film transistors. Mater. Today Adv. 5, 100040 (2020)

    Article  Google Scholar 

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Acknowledgments

The authors deeply appreciate the efforts and contributions of the employees at Kovio and Thin Film Electronics, without which this work would not have been possible.

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Correspondence to Mao Ito.

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Ito, M., Kamath, A. Polysilicon TFTs fabricated using poly-tetrasilane ink. MRS Communications 12, 124–129 (2022). https://doi.org/10.1557/s43579-022-00152-1

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