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Constructing FeCoNiCrAl high entropy alloys with tunable nanograin size and crystal structure to boost polarization loss for enhanced microwave absorption performances

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Abstract

Understanding of the relationship between grain size and crystal structure and electromagnetic wave absorption properties of high-entropy alloys (HEAs) is essential for the design of enhanced HEAs absorbers. In this work, the FeCoNiCrAl HEAs with tunable grain size and crystal structure are prepared by ball milling and annealing. It is found that the A-85h sample with a four-phase structure (BCC, FCC, B2, and NiFe2O4 phases) and small grain size has the best absorption performance at an ultra-thin matching thickness (1.5 mm), where the minimum reflection loss (RLmin) is − 45.0 dB and the maximum absorption bandwidth (EAB) is 4.3 GHz. The complex crystal structure and small grain size lead to enhanced polarization loss, which enables effective complementarity of dielectric and magnetic losses, and improves impedance matching and attenuation constants to enhance absorption. This work provides a valuable reference for designing high-performance microwave absorption materials.

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Microwave absorption performance of A-85h sample

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 52271174, 12304213, and 12227806) and the Natural Science Foundation of Zhejiang Province (No. LQ22A040008 and LY23E010007).

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Authors and Affiliations

  1. Institute of Advanced Magnetic Materials, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou, 310012, People’s Republic of China

    Tong Wang, Yanan Zhang, Guohua Bai & Xianguo Liu

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  1. Tong Wang
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  2. Yanan Zhang
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  3. Guohua Bai
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  4. Xianguo Liu
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TW has executed the work. YZ has made the initial manuscript and reviewed the manuscript. GB has reviewed the manuscript. XL has supervised the experimental process and results.

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Correspondence to Yanan Zhang.

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Wang, T., Zhang, Y., Bai, G. et al. Constructing FeCoNiCrAl high entropy alloys with tunable nanograin size and crystal structure to boost polarization loss for enhanced microwave absorption performances. Journal of Materials Research 39, 248–261 (2024). https://doi.org/10.1557/s43578-023-01219-y

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