Abstract
The relationship between microstructure evolution and thermal conductivity of the Mg–Sn–Ca alloys with various contents was investigated. The microstructures of Mg–2Sn–xCa alloys showed significant changes with different Ca contents. The addition of Ca can effectively improve the thermal conductivity of Mg–2Sn alloy. The thermal conductivity was remarkably improved to 147 W/(m·K) when the Sn/Ca atomic ratio was 1:1. The significant increase owes to the consumption of solute atoms and elimination of high-resistance Sn-rich regions. Mg–Sn–Ca alloys with Sn/Ca atomic ratio of 1 exhibited different solidification behaviors as the content increased. The thermal conductivity decreased linearly when the Sn content was below 3 wt% and then decreased rapidly at Sn content above 3 wt%. The former was dominated by the precipitated phase, while the latter was caused by Sn-enriched regions with high resistance.
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References
T. Xu, Y. Yang, X. Peng, J. Song, F. Pan, Overview of advancement and development trend on magnesium alloy. J. Magnes. Alloy. 7(3), 536 (2019)
C. Li, S. Yang, J. Du, H. Liao, G. Luo, Synergistic refining mechanism of Mg-3%Al alloy refining by carbon inoculation combining with Ca addition. J. Magnes. Alloy. 8(4), 1090 (2020)
V.V. Ramalingam, P. Ramasamy, M.D. Kovukkal, G. Myilsamy, Research and development in magnesium alloys for industrial and biomedical applications: a review. Metals Mater. Int. 26(4), 409 (2020)
A. Vinogradov, Effect of severe plastic deformation on tensile and fatigue properties of fine-grained magnesium alloy ZK60. J. Mater. Res. 32(23), 4362 (2017)
A.A. Luo, R.K. Mishra, B.R. Powell, A.K. Sachdev, Magnesium alloy development for automotive applications. Mater. Sci. Forum. 706–709, 69 (2012)
A. Huang, K.H. Lin, H.Y. Wei, Thermal performance enhancement with DRX in 5G millimeter wave communication system. IEEE Access. 9, 34692 (2021)
S. Li, X. Yang, J. Hou, W. Du, A review on thermal conductivity of magnesium and its alloys. J. Magnes. Alloy. 8(1), 78 (2020)
H. Pan, F. Pan, R. Yang, J. Peng, A. Tang, Q. Huang, K. Song, Z. Gao, Thermal and electrical conductivity of Mg–Zn–Al alloys. Mater. Sci. Tech-Lond. 30(8), 988 (2014)
A. Rudajevová, P. Lukáč, Comparison of the thermal properties of AM20 and AS21 magnesium alloys. Mater. Sci. Eng. A 397(1–2), 16 (2005)
H. Pan, F. Pan, R. Yang, J. Peng, C. Zhao, J. She, Z. Gao, A. Tang, Thermal and electrical conductivity of binary magnesium alloys. J. Mater. Sci. 49(8), 3107 (2014)
L. Zhong, J. Peng, S. Sun, Y. Wang, Y. Lu, F. Pan, Microstructure and thermal conductivity of as-cast and as-solutionized Mg–rare earth binary alloys. J. Mater. Sci. Technol. 33(11), 1240 (2017)
X. Zhao, Z. Li, W. Zhou, D. Li, M. Qin, X. Zeng, Effect of Al content on microstructure, thermal conductivity, and mechanical properties of Mg–La–Al–Mn alloys. J. Mater. Res. 36(15), 3145 (2021)
C. Su, D. Li, A.A. Luo, T. Ying, X. Zeng, Effect of solute atoms and second phases on the thermal conductivity of Mg-RE alloys: a quantitative study. J. Alloys Compd. 747, 431 (2018)
A. Rudajevová, M. Staněk, P. Luká, Determination of thermal diffusivity and thermal conductivity of Mg-Al alloys. Mater. Sci. Eng. A 341(1–2), 152 (2003)
H. Pan, F. Pan, X. Wang, J. Peng, J. Gou, J. She, A. Tang, Correlation on the electrical and thermal conductivity for binary Mg–Al and Mg–Zn alloys. Int. J. Thermophys. 34(7), 1336 (2013)
T. Ying, M.Y. Zheng, Z.T. Li, X.G. Qiao, Thermal conductivity of as-cast and as-extruded binary Mg-Al alloys. J. Alloys Compds. 608, 19 (2014)
G. Yuan, G. You, S. Bai, W. Guo, Effects of heat treatment on the thermal properties of AZ91D magnesium alloys in different casting processes. J. Alloys Compd. 766, 410 (2018)
Y.F. Liu, X.J. Jia, X.G. Qiao, S.W. Xu, M.Y. Zheng, Effect of La content on microstructure, thermal conductivity and mechanical properties of Mg–4Al magnesium alloys. J. Alloys Compd. 806, 71 (2019)
W. Chunming, C. Yungui, X. Sufen, D. Wucheng, L. Xia, Thermal conductivity and mechanical properties of as-cast Mg-3Zn-(05∼35)Sn alloys. Rare Metal Mater. Eng. 42(10), 2019 (2013)
H. Pan, F. Pan, X. Wang, J. Peng, J. She, C. Zhao, Q. Huang, K. Song, Z. Gao, High conductivity and high strength Mg–Zn–Cu alloy. Mater. Sci. Tech-Lond. 30(7), 759 (2013)
J. Peng, L. Zhong, Y. Wang, J. Yang, Y. Lu, F. Pan, Effect of Ce addition on thermal conductivity of Mg–2Zn–1Mn alloy. J. Alloys Compd. 639, 556 (2015)
Y. Huang, X. Zhou, J. Du, Microstructure, thermal conductivity and mechanical properties of the Mg–Zn–Sb ternary alloys. Metals Mater. Int. 27(11), 4477–4486 (2020)
J. Peng, L. Zhong, Y. Wang, Y. Lu, F. Pan, Effect of extrusion temperature on the microstructure and thermal conductivity of Mg–20Zn–10Mn–02Ce alloys. Mater. Des. 87, 914 (2015)
B. Li, L. Hou, R. Wu, J. Zhang, X. Li, M. Zhang, A. Dong, B. Sun, Microstructure and thermal conductivity of Mg-2Zn-Zr alloy. J. Alloys Compd. 722, 772 (2017)
K.R. Athul, U.T.S. Pillai, A. Srinivasan, B.C. Pai, A review of different creep mechanisms in Mg alloys based on stress exponent and activation energy. Adv. Eng. Mater. 18(5), 770 (2016)
Y. Feng, Y. Yang, Z. Xiao, X. Meng, G. Zhou, J. Leng, X. Teng, Effect of Al on the microstructure and mechanical properties of Mg–Sn–Ca–Mn wrought alloy. Metals Mater. Int. 28(6), 1480–1487 (2021)
N. El-Mahallawy, H. Palkowski, H.-G. Breitinger, A. Klingner, M. Shoeib, A. Diaa, Microstructure, mechanical properties, cytotoxicity, and bio-corrosion of micro-alloyed Mg–xSn–0.04Mn alloys for biodegradable orthopedic applications: effect of processing techniques. J. Mater. Res. 36(7), 1456–1474 (2021)
H. Pan, G. Qin, Y. Huang, Y. Ren, X. Sha, X. Han, Z.-Q. Liu, C. Li, X. Wu, H. Chen, C. He, L. Chai, Y. Wang, J.-F. Nie, Development of low-alloyed and rare-earth-free magnesium alloys having ultra-high strength. Acta Mater. 149, 350 (2018)
T.T. Sasaki, F.R. Elsayed, T. Nakata, T. Ohkubo, S. Kamado, K. Hono, Strong and ductile heat-treatable Mg–Sn–Zn–Al wrought alloys. Acta Mater. 99, 176 (2015)
C. Wang, Z. Cui, H. Liu, Y. Chen, W. Ding, S. Xiao, Electrical and thermal conductivity in Mg–5Sn Alloy at different aging status. Mater. Des. 84, 48 (2015)
Q. Huang, A. Tang, S. Ma, H. Pan, B. Song, Z. Gao, M. Rashad, F. Pan, Enhancing thermal conductivity of Mg-Sn alloy sheet by cold rolling and aging. J. Mater. Eng. Perform. 25(6), 2356 (2016)
C. Wang, Z. Liu, S. Xiao, Y. Chen, Effects of Sn Ca additions on thermal conductivity of Mg matrix alloys. Mater. Sci. Tech-Lond. 1, 15 (2016)
Y.H. Kim, J.H. Kim, H.S. Yoo, H.T. Son, Analysis of microstructure and thermal conductivity in Mg–Sn–Ca alloy. J. Nanosci. Nanotechnol. 16(11), 11277–11280 (2016)
A. Kozlov, M. Ohno, R. Arroyave, Z.K. Liu, R. Schmid-Fetzer, Phase equilibria, thermodynamics and solidification microstructures of Mg–Sn–Ca alloys, Part 1: Experimental investigation and thermodynamic modeling of the ternary Mg–Sn–Ca system. Intermetallics 16(2), 299 (2008)
A. Kozlov, M. Ohno, T.A. Leil, N. Hort, K.U. Kainer, R. Schmid-Fetzer, Phase equilibria, thermodynamics and solidification microstructures of Mg–Sn–Ca alloys, Part 2: Prediction of phase formation in Mg-rich Mg–Sn–Ca cast alloys. Intermetallics 16(2), 316 (2008)
H. Okamoto, Phase diagram for binary alloys. Desk Hand Book 315, 15 (2000)
G. Nayyeri, R. Mahmudi, Effects of Ca additions on the microstructural stability and mechanical properties of Mg–5%Sn alloy. Mater. Des. 32(3), 1571 (2011)
A.K. Ganguli, A.M. Guloy, J.D. Corbett, Concerning the Ca2−xMgxTt systems, Tt=Sn Pb. J. Solid State Chem. 152(2), 474 (2000)
G. Luo, Y. Huang, C. Li, Z. Huang, J. Du, Microstructures and mechanical properties of Al-2Fe-xCo ternary alloys with high thermal conductivity. Materials 13(17), 15 (2020)
S. Nagarjuna, K. Balasubramanian, D.S. Sarma, Effect of Ti additions on the electrical resistivity of copper. Mater. Sci. Eng. A 225(1), 118 (1997)
C. Su, D. Li, T. Ying, L. Zhou, L. Li, X. Zeng, Effect of Nd content and heat treatment on the thermal conductivity of Mg Nd alloys. J. Alloys Compd. 685, 114 (2016)
M. Schick, A. Watson, M. Baben, K. Hack, A modified Neumann-Kopp treatment of the heat capacity of stoichiometric phases for use in computational thermodynamics. J. Phase Equilib. Diffus. 40(1), 104 (2019)
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Zhou, X., Luo, G., Mo, L. et al. Relationship between microstructure evolution and thermal conductivity of Mg–Sn–Ca alloys. Journal of Materials Research 37, 3720–3730 (2022). https://doi.org/10.1557/s43578-022-00746-4
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DOI: https://doi.org/10.1557/s43578-022-00746-4