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Highly efficient solar steam generation of polyamide 6 membrane modified with graphene oxide and Au nanoparticles

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Abstract

Solar steam generation (SSG) system greatly improves the efficiency of water evaporation through heat localization, which has broad application prospects at seawater desalination and wastewater treatment. In this paper, polyamide 6-graphene oxide (PA6-GO) membrane was fabricated by nonsolvent-induced phase separation of a solution with GO-modified PA6 in formic acid. Furthermore, the PA6-GO membrane was modified by vacuum filtration of self-assembly gold nanoparticles on its surface for solar stem generation. The composite membrane obtained a light absorption rate of nearly 99.8%. Under the irradiation of 1 kW m−2, the evaporation rate of 1.1 kg m−2 h−1 was obtained and the evaporation efficiency also reached to 75.6%. The evaporation system has the characteristics of low cost, high stability, strong acid, and alkali corrosion resistance, suggesting great potentials in seawater desalination and sewage treatment.

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References

  1. L. Zhao, Q. Yang, W. Guo, H. Liu, T. Ma, F. Qu, Co2.67S4-based photothermal membrane with high mechanical properties for efficient solar water evaporation and photothermal antibacterial applications. ACS Appl. Mater. Interfaces 11, 20820–20827 (2019)

    Article  CAS  Google Scholar 

  2. C. Chen, Y. Li, J. Song, Z. Yang, Y. Kuang, E. Hitz, C. Jia, A. Gong, F. Jiang, J.Y. Zhu, B. Yang, J. Xie, L. Hu, Highly flexible and efficient solar steam generation device. Adv. Mater. 29, 1701756 (2017)

    Article  CAS  Google Scholar 

  3. Y. Liu, Y. Zhang, G. Jia, Photothermal conversion of Bi2Se3 nanosheets and efficient steam generation by capillary siphoning. Energy Rep. 6, 1304–1311 (2020)

    Article  Google Scholar 

  4. X. Han, W. Wang, K. Zuo, L. Chen, L. Yuan, J. Liang, Q. Li, P.M. Ajayan, Y. Zhao, J. Lou, Bio-derived ultrathin membrane for solar driven water purification. Nano Energy 60, 567–575 (2019)

    Article  CAS  Google Scholar 

  5. M.A. Shannon, P.W. Bohn, M. Elimelech, J.G. Georgiadis, B.J. Marinas, A.M. Mayes, Science and technology for water purification in the coming decades, in Nanoscience and Technology, (2009) pp. 337–346.

  6. G. Wang, Y. Fu, X. Ma, W. Pi, D. Liu, X. Wang, Reusable reduced graphene oxide based double-layer system modified by polyethylenimine for solar steam generation. Carbon 114, 117–124 (2017)

    Article  CAS  Google Scholar 

  7. G. Baffou, R. Quidant, F.J.G. de Abajo, Nanoscale control of optical heating in complex plasmonic systems. ACS Nano 4, 709–716 (2010)

    Article  CAS  Google Scholar 

  8. Z.Y. Fang, Y.R. Zhen, O. Neumann, A. Polman, F.J.G. de Abajo, P. Nordlander, N.J. Halas, Evolution of light-induced vapor generation at a liquid-immersed metallic nanoparticle. Nano Lett. 13, 1736–1742 (2013)

    Article  CAS  Google Scholar 

  9. N.J. Halas, O. Neumann, A. Urban, N. Hogan, Z.Y. Fang, A. Pimpinelli, S. Lal, P. Nordlander, Solar vapor generation enabled by nanoparticles. Abstr. Pap. Am. Chem. Soc 246, 42–49 (2013)

    Google Scholar 

  10. J.L. Li, D. Day, M. Gu, Ultra-low energy threshold for cancer photothermal therapy using transferrin-conjugated gold nanorods. Adv. Mater. 20, 3866–3871 (2008)

    Article  CAS  Google Scholar 

  11. H.Y. Liu, D. Chen, L.L. Li, T.L. Liu, L.F. Tan, X.L. Wu, F.Q. Tang, Multifunctional gold nanoshells on silica nanorattles: a platform for the combination of photothermal therapy and chemotherapy with low systemic toxicity. Angew. Chem.-Int. Ed. 50, 891–895 (2011)

    Article  CAS  Google Scholar 

  12. M. Reismann, J.C. Bretschneider, G. von Plessen, U. Simon, Reversible photothermal melting of DNA in DNA-gold-nanoparticle networks. Small 4, 607–610 (2008)

    Article  CAS  Google Scholar 

  13. K. Manthiram, A.P. Alivisatos, Tunable localized surface plasmon resonances in tungsten oxide nanocrystals. J. Am. Chem. Soc. 134, 3995–3998 (2012)

    Article  CAS  Google Scholar 

  14. J.C. Liu, O. Margeat, W. Dachraoui, X.J. Liu, M. Fahlman, J. Ackermann, Gram-scale synthesis of ultrathin tungsten oxide nanowires and their aspect ratio-dependent photocatalytic activity. Adv. Funct. Mater. 24, 6029–6037 (2014)

    Article  CAS  Google Scholar 

  15. M.K. Gupta, S.C. Kaushik, Exergy analysis and investigation for various feed water heaters of direct steam generation solar-thermal power plant. Renew. Energy 35, 1228–1235 (2010)

    Article  Google Scholar 

  16. W. Fang, L. Zhao, H. Chen, X. He, W. Li, X. Du, Z. Sun, T. Zhang, Y. Shen, Graphene oxide foam fabricated with surfactant foaming method for efficient solar vapor generation. J. Mater. Sci. 54, 12782–12793 (2019)

    Article  CAS  Google Scholar 

  17. X. Zhao, X.-J. Zha, J.-H. Pu, L. Bai, R.-Y. Bao, Z.-Y. Liu, M.-B. Yang, W. Yang, Macroporous three-dimensional MXene architectures for highly efficient solar steam generation. J. Mater. Chem. A 7, 10446–10455 (2019)

    Article  CAS  Google Scholar 

  18. F. Zhao, Y.H. Guo, X.Y. Zhou, W. Shi, G.H. Yu, Materials for solar-powered water evaporation. Nat. Rev. Mater. 5, 388–401 (2020)

    Article  Google Scholar 

  19. M. Zhu, A. Xia, Q. Feng, X. Wu, C. Zhang, D. Wu, H. Zhu, Biomass carbon materials for efficient solar steam generation prepared from carbonized enteromorpha prolifera. Energy Technol. 8, 1901215 (2019)

    Article  CAS  Google Scholar 

  20. F. Jiang, T. Li, Y. Li, Y. Zhang, A. Gong, J. Dai, E. Hitz, W. Luo, L. Hu, Wood-based nanotechnologies toward sustainability. Adv. Mater. 30, 1703453 (2018)

    Article  CAS  Google Scholar 

  21. G. Li, F. Li, J. Liu, C.J.J.S.S.C. Fan, Fe-based MOFs for photocatalytic N 2 reduction: key role of transition metal iron in nitrogen activation. J. Solid State Chem. 285, 121245 (2020)

    Article  CAS  Google Scholar 

  22. Y. Chen, C. Sha, W. Wang, F. Yang, Solar-driven steam generation on nitrogen-doped graphene in a 2D water path isolation system. Mater. Res. Express 7, 015507 (2020)

    Article  CAS  Google Scholar 

  23. S.H. Hong, Y. Shi, R.Y. Li, C.L. Zhang, Y. Jin, P. Wang, Nature-inspired, 3D origami solar steam generator toward near full utilization of solar energy. ACS Appl. Mater. Interfaces 10, 28517–28524 (2018)

    Article  CAS  Google Scholar 

  24. X. Wang, Y. He, X. Liu, G. Cheng, J. Zhu, Solar steam generation through bio-inspired interface heating of broadband-absorbing plasmonic membranes. Appl. Energy 195, 414–425 (2017)

    Article  CAS  Google Scholar 

  25. Y. Li, T. Gao, Z. Yang, C. Chen, W. Luo, J. Song, E. Hitz, C. Jia, Y. Zhou, B. Liu, B. Yang, L. Hu, 3D-printed, all-in-one evaporator for high-efficiency solar steam generation under 1 sun illumination. Adv. Mater. 29, 1700981 (2017)

    Article  CAS  Google Scholar 

  26. K.K. Liu, Q. Jiang, S. Tadepalli, R. Raliya, P. Biswas, R.R. Naik, S. Singamaneni, Wood-graphene oxide composite for highly efficient solar steam generation and desalination. ACS Appl. Mater. Interfaces 9, 7675–7681 (2017)

    Article  CAS  Google Scholar 

  27. Q.S. Jiang, L.M. Tian, K.K. Liu, S. Tadepalli, R. Raliya, P. Biswas, R.R. Naik, S. Singamaneni, Bilayered biofoam for highly efficient solar steam generation. Adv. Mater. 28, 9400–9407 (2016)

    Article  CAS  Google Scholar 

  28. Y. Ito, Y. Tanabe, J. Han, T. Fujita, K. Tanigaki, M. Chen, Multifunctional porous graphene for high-efficiency steam generation by heat localization. Adv. Mater. 27, 4302–4307 (2015)

    Article  CAS  Google Scholar 

  29. H.T. Kieu, K. Zhou, A.W.K. Law, Surface morphology effect on the evaporation of water on graphene oxide: a molecular dynamics study. Appl. Surf. Sci. 488, 335–342 (2019)

    Article  CAS  Google Scholar 

  30. Y. Chang, Z. Wang, Y.-E. Shi, X. Ma, L. Ma, Y. Zhang, J. Zhan, Hydrophobic W18O49 mesocrystal on hydrophilic PTFE membrane as an efficient solar steam generation device under one sun. J. Mater. Chem. A 6, 10939–10946 (2018)

    Article  CAS  Google Scholar 

  31. G. Ni, G. Li, S.V. Boriskina, H.X. Li, W.L. Yang, T.J. Zhang, G. Chen, Steam generation under one sun enabled by a floating structure with thermal concentration. Nat. Energy 1, 16126 (2016)

    Article  CAS  Google Scholar 

  32. A. Politano, P. Argurio, G. Di Profio, V. Sanna, A. Cupolillo, S. Chakraborty, H.A. Arafat, E. Curcio, Photothermal membrane distillation for seawater desalination. Adv. Mater. 29, 1603504 (2017)

    Article  CAS  Google Scholar 

  33. Y. Xu, D. Liu, H. Xiang, S. Ren, Z. Zhu, D. Liu, H. Xu, F. Cui, W. Wang, Easily scaled-up photo-thermal membrane with structure-dependent auto-cleaning feature for high-efficient solar desalination. J. Membr. Sci. 586, 222–230 (2019)

    Article  CAS  Google Scholar 

  34. J. Hou, C. Bao, S. Qu, X. Hu, S. Nair, Y. Chen, Graphene oxide membranes for ion separation: detailed studies on the effects of fabricating conditions. Appl. Surf. Sci. 459, 185–193 (2018)

    Article  CAS  Google Scholar 

  35. Z. Yin, Y. Wang, C. Song, L. Zheng, N. Ma, X. Liu, S. Li, L. Lin, M. Li, Y. Xu, W. Li, G. Hu, Z. Fang, D. Ma, Hybrid Au-Ag nanostructures for enhanced plasmon-driven catalytic selective hydrogenation through visible light irradiation and surface-enhanced Raman scattering. J. Am. Chem. Soc. 140, 864–867 (2018)

    Article  CAS  Google Scholar 

  36. X. Han, J. Goebl, Z. Lu, Y. Yin, Role of salt in the spontaneous assembly of charged gold nanoparticles in ethanol. Langmuir 27, 5282–5289 (2011)

    Article  CAS  Google Scholar 

  37. Z. Xu, C. Gao, In situ polymerization approach to graphene-reinforced nylon-6 composites. Macromolecules 43, 6716–6723 (2010)

    Article  CAS  Google Scholar 

  38. Z. Yin, W. Zhang, Q. Fu, H. Yue, W. Wei, P. Tang, W. Li, W. Li, L. Lin, G. Ma, D. Ma, Construction of stable chainlike Au nanostructures via silica coating and exploration for potential photothermal therapy. Small 10, 3619–3624 (2014)

    Article  CAS  Google Scholar 

  39. Z. Li, W. Cai, X. Wang, Y. Hu, Z. Gui, Self-floating black phosphorous nanosheets as a carry-on solar vapor generator. J. Colloid Interface Sci. 582, 496–505 (2020)

    Article  CAS  Google Scholar 

  40. Y. Li, T. Gao, Z. Yang, C. Chen, Y. Kuang, J. Song, C. Jia, E.M. Hitz, B. Yang, L. Hu, Graphene oxide-based evaporator with one-dimensional water transport enabling high-efficiency solar desalination. Nano Energy 41, 201–209 (2017)

    Article  CAS  Google Scholar 

  41. G. Xue, K. Liu, Q. Chen, P. Yang, J. Li, T. Ding, J. Duan, B. Qi, J. Zhou, Robust and low-cost flame-treated wood for high-performance solar steam generation. ACS Appl. Mater. Interfaces 9, 15052–15057 (2017)

    Article  CAS  Google Scholar 

  42. W. Fang, L. Zhao, X. He, H. Chen, W. Li, X. Zeng, X. Chen, Y. Shen, W. Zhang, Carbonized rice husk foam constructed by surfactant foaming method for solar steam generation. Renew. Energy 151, 1067–1075 (2020)

    Article  CAS  Google Scholar 

  43. C. Boo, Y. Wang, I. Zucker, Y. Choo, C.O. Osuji, M. Elimelech, High performance nanofiltration membrane for effective removal of perfluoroalkyl substances at high water recovery. Environ. Sci. Technol. 52, 7279–7288 (2018)

    Article  CAS  Google Scholar 

  44. Q. Wang, Y. Qin, F. Jia, Y. Li, S. Song, Magnetic MoS2 nanosheets as recyclable solar-absorbers for high-performance solar steam generation. Renew. Energy 163, 146–153 (2021)

    Article  CAS  Google Scholar 

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Acknowledgments

This work was financially supported by Key R&D program of Tianjin municipal science and technology commission (20YFZCSN00930).

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Correspondence to Yingbo Chen.

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Xu, J., Chen, Y., Cao, M. et al. Highly efficient solar steam generation of polyamide 6 membrane modified with graphene oxide and Au nanoparticles. Journal of Materials Research 37, 1475–1485 (2022). https://doi.org/10.1557/s43578-022-00552-y

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