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Simultaneous catalytic removal of NO and chlorobenzene over Sn–Mn–Ce–Co–Ox double-way catalyst

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Abstract

Mn-based catalysts are often used for catalytic reduction of NO and catalytic degradation of chlorobenzene. In this work, the promotion mechanism of SnO2 modification was investigated. The activities of Sn–Mn–Ce–Co–Ox catalyst were the best when the SnO2 content was 8%. In the temperature range from 120 to 330 ℃, the NO conversion was above 90%, and the T50 and T90 of CB decreased to 127 ℃ and 183 ℃. The structure of the catalyst was characterized, and it was found that the catalytic effects of SnO2 on pollutant degradation performance of Sn–Mn–Ce–Co–Ox catalyst were mainly as follows: (1) leading to the formation of a large number of Mn4+; (2) increasing the amount of chemisorbed oxygen on the catalyst surface; and (3) improving the redox performance of the catalyst. CHCl3, CCl4, C2HCl3, and C2Cl4 intermediate products were generated in the catalytic reaction, covering the catalytic site.

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Acknowledgments

This work is supported by the National Key Research and Development Program of China (2021YFB3500600, 2021YFB3500605), Key R&D Program of Jiangsu Province (BE2018074), Jiangsu International Cooperation Project (BZ2021018), Nanjing Science and Technology Top Experts Gathering Plan, Science and Technology Plan of Suzhou (SGC2020092), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

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Authors and Affiliations

  1. CCSC Nanjing Luzhou Environment Protection Co., Nanjing, 211100, People’s Republic of China

    Jisai Chen & Xiaohuan Zhi

  2. School of Environmental Science and Engineering, Nanjing Tech University, No. 5 Xinmofan Road, Nanjing, 210009, People’s Republic of China

    Mutao Xu, Qijie Jin, Xiaohuan Zhi, Xue Li, Yao Lu & Haitao Xu

  3. College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing, 210009, People’s Republic of China

    Yingwen Chen

  4. KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia

    Yan Wang

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  1. Jisai Chen
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Correspondence to Haitao Xu.

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Chen, J., Xu, M., Jin, Q. et al. Simultaneous catalytic removal of NO and chlorobenzene over Sn–Mn–Ce–Co–Ox double-way catalyst. Journal of Materials Research 37, 1390–1402 (2022). https://doi.org/10.1557/s43578-022-00542-0

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