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⍺-NSA doped PPy @ Ti3C2Tx hybrid material as a high-performance supercapacitor electrode

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  • FOCUS ISSUE: Two-dimensional Materials for Future Generation Energy Storage Applications
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Abstract

Herein, a hybrid material composed of doped Polypyrrole (PPy) on two-dimensional Ti3C2Tx MXene surface is presented as a high-performance electrochemical supercapacitor electrode. PPy is deposited on the synthesized Ti3C2Tx surfaces employing in-situ chemical polymerization to fabricate PPy @Ti3C2Tx electrodes. The improvement of electrochemical performance of PPy@Ti3C2Tx is investigated by introducing two anionic dopants: α-naphthalene sulfonic acid (α-NSA) and a mixture of anthraquinone-2-sulfonic acid sodium salt monohydrate/5-sulfosalicylic acid dihydrate (AQSANa,SSCA). While the maximum specific capacitances of the Ti3C2Tx, PPy@Ti3C2Tx and AQSANa,SSCA doped PPy@Ti3C2Tx are 232.2, 154.4, 105.9 F g−1 at the scan rate of 5 mV s−1, respectively; they retain less than 70% of their initial capacitance over 2000 cycles. α-NSA doped PPy@Ti3C2Tx exhibits the best electrochemical performance with the highest specific capacitance (347.6 F g−1) and significantly more capacitance retention (90% over more than 4000 cycles). This notable improvement proposes α-NSA doped PPy @Ti3C2Tx MXene nano structured material as a high-performance supercapacitor electrode.

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Acknowledgments

This work was supported by Iran National Science Foundation (Grant Number 98004078). The authors would like to thank Dr. Mohajerzadeh and Ms. Salehi for their kind support in Nanoelectronics laboratory.

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Authors and Affiliations

  1. School of Materials Science and Metallurgy Engineering, College of Engineering, University of Tehran, Tehran, Iran

    Bahar Ronnasi

  2. Nano-Electronics and Thin Film Lab, School of Electrical and Computer Engineering, University of Tehran, P.O. Box 14395/515, Tehran, Iran

    Mehrnoosh Mahmoodian

  3. Hamava Innovation Factory, Tehran, Iran

    Mehrnoosh Mahmoodian

  4. School of Engineering Science, College of Engineering, University of Tehran, Tehran, Iran

    Somayeh Mohammadi

  5. Nano-Fabricated Energy Devices Laboratory, School of Electrical and Computer Engineering, College of Engineering, University of Tehran, Tehran, Iran

    Mohammadreza Yasoubi & Zeinab Sanaee

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  1. Bahar Ronnasi
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  2. Mehrnoosh Mahmoodian
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  3. Somayeh Mohammadi
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Correspondence to Somayeh Mohammadi.

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Ronnasi, B., Mahmoodian, M., Mohammadi, S. et al. ⍺-NSA doped PPy @ Ti3C2Tx hybrid material as a high-performance supercapacitor electrode. Journal of Materials Research 37, 3965–3975 (2022). https://doi.org/10.1557/s43578-022-00527-z

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  • DOI: https://doi.org/10.1557/s43578-022-00527-z

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