Abstract
It is significant to fabricate the oxide nanoparticle/graphene composite for improving the electromagnetic wave absorption properties. In this work, the monodisperse manganese oxide (MnO) nanoparticle/reduced graphene oxide (rGO) composite was obtained via the hydrophobic interaction in the colloidal solution. The monodisperse MnO nanoparticle is about 55 nm with a uniform distribution due to the modification of oleylamine. When it was used for the electromagnetic (EM) wave absorption, an excellent EM wave absorption in the 2–18 GHz band was displayed. Its effective EM absorption bandwidth can be up to 4.2 GHz at 1.5 mm thickness, and the minimum reflection loss can be up to − 44.67 dB at 2 mm thickness. This is because the monodisperse MnO nanoparticles with the uniform distribution could provide more interfacial polarization active sites, which enhanced the interfacial polarization effect. This uniform hybrid is expected to be a potential candidate for the outstanding EM wave absorption performance.
Graphical Abstract
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The data that support the findings of this study are available from the corresponding author upon reasonable request
References
A. Namai, S. Sakurai, M. Nakajima, T. Suemoto, K. Matsumoto, M. Goto, S. Sasaki, S.-I. Ohkoshi, Synthesis of an electromagnetic wave absorber for high-speed wireless communication. J. Am. Chem. Soc. 131, 1170–1173 (2009)
Y. Zhang, Y. Huang, T.F. Zhang, H.C. Chang, P.S. Xiao, H.H. Chen, Z.Y. Huang, Y.S. Chen, Broadband and tunable high-performance microwave absorption of an ultralight and highly compressible graphene foam. Adv. Mater. 27, 2049–2053 (2015)
A.K. Geim, Graphene: status and prospects. Science 324, 1530–1534 (2009)
M. Fu, Q.Z. Jiao, Y. Zhao, Preparation of NiFe2O4 nanorod-graphene composites via an ionic liquid assisted one-step hydrothermal approach and their microwave absorbing properties. J. Mater. Chem. A 1, 5577–5586 (2013)
B. Wen, M.S. Cao, M.M. Lu, W.Q. Cao, H.L. Shi, J. Liu, X.X. Wang, H.B. Jin, X.Y. Fang, W.Z. Wang, J. Yuan, Reduced graphene oxides: light-weight and high-efficiency electromagnetic interference shielding at elevated temperatures. Adv. Mater. 26, 3484–3489 (2014)
W. Yan, F. He, S.L. Gai, P. Gao, Y.J. Chen, P.P. Yang, A novel 3D structured reduced graphene oxide/TiO2 composite: synthesis and photocatalytic performance. J. Mater. Chem. A 2, 3605–3612 (2014)
L.N. Liu, F. Yan, K.Y. Li, C.L. Zhu, Y. Xie, X.T. Zhang, Y.J. Chen, Ultrasmall FeNi3N particles with an exposed active (110) surface anchored on nitrogen-doped graphene for multifunctional electrocatalysts. J. Mater. Chem. A 7, 1083–1091 (2019)
Y.J. Chen, Z.Y. Lei, H.Y. Wu, C.L. Zhu, P. Gao, Q.Y. Ouyang, L.H. Qi, W. Qin, Electromagnetic absorption properties of graphene/Fe nanocomposites. Mater. Res. Bull. 48, 3362–3366 (2013)
B. Qu, C.L. Zhu, C.Y. Li, X.T. Zhang, Y.J. Chen, Coupling hollow Fe3O4-Fe nanoparticles with graphene sheets for high-performance electromagnetic wave absorbing material. ACS Appl. Mater. Interfaces 8, 3730–3735 (2016)
X. Zhang, J. Xu, H. Yuan, S. Zhang, Q. Ouyang, C. Zhu, X. Zhang, Y. Chen, Large-scale synthesis of three-dimensional reduced graphene oxide/nitrogen-doped carbon nanotube heteronanostructures as highly efficient electromagnetic wave absorbing materials. ACS Appl. Mater. Interfaces 11, 39100–39108 (2019)
H. Zhang, M. Hong, P. Chen, A.J. Xie, Y.H. Shen, 3D and ternary rGO/MCNTs/Fe3O4 composite hydrogels: synthesis, characterization and their electromagnetic wave absorption properties. J. Alloys Compd. 665, 381–387 (2016)
F.B. Meng, H.G. Wang, F. Huang, Y.F. Guo, Z.Y. Wang, D. Hui, Z.W. Zhou, Graphene-based microwave absorbing composites: a review and prospective. Compos. Part B-Eng. 137, 260–277 (2018)
K.C. Zhang, X.B. Gao, Q. Zhang, T.P. Li, H. Chen, X.F. Chen, Preparation and microwave absorption properties of asphalt carbon coated reduced graphene oxide/magnetic CoFe2O4 hollow particles modified multi-wall carbon nanotube composites. J. Alloys Compd. 723, 912–921 (2017)
F. Yan, S. Zhang, X. Zhang, C.Y. Li, C.L. Zhu, X.T. Zhang, Y.J. Chen, Growth of CoFe2O4 hollow nanoparticles on graphene sheets for high-performance electromagnetic wave absorbers. J. Mater. Chem. C. 6, 12781–12787 (2018)
C.L. Zhu, S. Zhang, Y. Sun, Y.J. Chen, Incorporation of CoO@Co yolk-shell nanoparticles and ZnO nanoparticles with graphene sheets as lightweight and high-performance electromagnetic wave absorbing material. J. Alloys Compd. 711, 552–559 (2017)
L. Wang, H.L. Xing, S.T. Gao, X.L. Ji, Z.Y. Shen, Porous flower-like NiO@graphene composites with superior microwave absorption properties. J. Mater. Chem. C 5, 2005–2014 (2017)
X. Jian, B. Wu, Y. Wei, S.X. Dou, X. Wang, W. He, N. Mahmood, Facile synthesis of Fe3O4/GCs composites and their enhanced microwave absorption properties. ACS Appl. Mater. Interfaces 8, 6101–6109 (2016)
T.K. Gupta, B.P. Singh, V.N. Singh, S. Teotia, A.P. Singh, I. Elizabeth, S.R. Dhakate, S.K. Dhawan, R.B. Mathur, MnO2 decorated graphene nanoribbons with superior permittivity and excellent microwave shielding properties. J. Mater. Chem. A 2, 4256–4263 (2014)
Y. Wang, H.T. Guan, C.J. Dong, X.C. Xiao, S.F. Du, Y.D. Wang, Reduced graphene oxide (RGO)/Mn3O4 nanocomposites for dielectric loss properties and electromagnetic interference shielding effectiveness at high frequency. Ceram. Int. 42, 936–942 (2016)
J.T. Yuan, K.Z. Li, Z.F. Liu, S.W. Jin, S.K. Li, H. Zhang, Preparation of reduced graphene oxide/MnO composite and its electromagnetic wave absorption performance. Russ. J. Phys. Chem. A 92, 342–345 (2018)
N. Bao, L. Shen, Y. Wang, P. Padhan, A. Gupta, A facile thermolysis route to monodisperse ferrite nanocrystals. J. Am. Chem. Soc. 129, 12374–12375 (2007)
J. Park, K. An, Y. Hwang, J.-G. Park, H.-J. Noh, J.-Y. Kim, J.-H. Park, N.-M. Hwang, T. Hyeon, Ultra-large-scale syntheses of monodisperse nanocrystals. Nat. Mater. 3, 891–895 (2004)
T. Li, B. Xue, B. Wang, G. Guo, D. Han, Y. Yan, A. Dong, Tubular monolayer superlattices of hollow Mn3O4 nanocrystals and their oxygen reduction activity. J. Am. Chem. Soc. 139, 12133–12136 (2017)
Y. Xiao, X. Wang, W. Wang, D. Zhao, M. Cao, Engineering hybrid between MnO and N-doped carbon to achieve exceptionally high capacity for lithium-ion battery anode. ACS Appl. Mater. Interfaces 6, 2051–2058 (2014)
G.B. Xu, F. Jiang, Z.A. Ren, L.W. Yang, Polyhedral MnO nanocrystals anchored on reduced graphene oxide as an anode material with superior lithium storage capability. Ceram. Int. 41, 10680–10688 (2015)
J. Yu, J.-D. Luo, H. Zhang, Z. Zhang, J. Wei, Z. Yang, Renewable agaric-based hierarchically porous cocoon-like MnO/carbon composites enable high-energy and high-rate Li-ion batteries. Electrochim. Acta 322, 134757 (2019)
P. Miles, W. Westphal, A. Von Hippel, Dielectric spectroscopy of ferromagnetic semiconductors. Rev. Mod. Phys. 29, 279–307 (1957)
J.T. Yuan, Q.C. Liu, S.K. Li, Y. Lu, S.W. Jin, K.Z. Li, H. Chen, H. Zhang, Metal organic framework (MOF)-derived carbonaceous Co3O4/Co microframes anchored on RGO with enhanced electromagnetic wave absorption performances. Synth. Met. 228, 32–40 (2017)
X.H. Li, J. Feng, Y.P. Du, J.T. Bai, H.M. Fan, H.L. Zhang, Y. Peng, F.S. Li, One-pot synthesis of CoFe2O4/graphene oxide hybrids and their conversion into FeCo/graphene hybrids for lightweight and highly efficient microwave absorber. J. Mater. Chem. A 3, 5535–5546 (2015)
X.L. Zheng, J. Feng, Y. Zong, H. Miao, X.Y. Hu, J.T. Bai, X.H. Li, Hydrophobic graphene nanosheets decorated by monodispersed superparamagnetic Fe3O4 nanocrystals as synergistic electromagnetic wave absorbers. J. Mater. Chem. C 3, 4452–4463 (2015)
H.R. Yuan, X. Zhang, F. Yan, S. Zhang, C.L. Zhu, C.Y. Li, X.T. Zhang, Y.J. Chen, Nitrogen-doped carbon nanosheets containing Fe3C nanoparticles encapsulated in nitrogen-doped graphene shells for high-performance electromagnetic wave absorbing materials. Carbon 140, 368–376 (2018)
X. Xu, F. Ran, H. Lai, Z. Cheng, T. Lv, L. Shao, Y. Liu, In Situ confined bimetallic metal-organic framework derived nanostructure within 3D interconnected bamboo-like carbon nanotube networks for boosting electromagnetic wave absorbing performances. ACS Appl. Mater. Interfaces. 11, 35999–36009 (2019)
J.Y. Fu, W. Yang, L.Q. Hou, Z. Chen, T. Qu, H.T. Yang, Y.F. Li, Enhanced electromagnetic microwave absorption performance of lightweight bowl-like carbon nanoparticles. Ind. Eng. Chem. Res 56, 11460–11466 (2017)
H. Chen, Z. Huang, Y. Huang, Y. Zhang, Z. Ge, B. Qin, Z. Liu, Q. Shi, P. Xiao, Y. Yang, T. Zhang, Y. Chen, Synergistically assembled MWCNT/graphene foam with highly efficient microwave absorption in both C and X bands. Carbon 124, 506–514 (2017)
H.R. Yuan, F. Yan, C.Y. Li, C.L. Zhu, X.T. Zhang, Y.J. Chen, Nickel nanoparticle encapsulated in few-layer nitrogen-doped graphene supported by nitrogen-doped graphite sheets as a high-performance electromagnetic wave absorbing material. ACS Appl. Mater. Interfaces 10, 1399–1407 (2018)
J.-Z. He, X.-X. Wang, Y.-L. Zhang, M.-S. Cao, Small magnetic nanoparticles decorating reduced graphene oxides to tune the electromagnetic attenuation capacity. J. Mater. Chem. C 4, 7130–7140 (2016)
M.K. Han, X.W. Yin, L. Kong, M. Li, W.Y. Duan, L.T. Zhang, L.F. Cheng, Graphene-wrapped ZnO hollow spheres with enhanced electromagnetic wave absorption properties. J. Mater. Chem. A 2, 16403–16409 (2014)
Y. Liu, C. Ji, X.L. Su, J. Xu, X.H. He, Electromagnetic and microwave absorption properties of Ti3SiC2 powders decorated with Ag particles. J. Alloys Compd. 820, 153154–153161 (2020)
W.S. Hummers Jr., R.E.J.J.O.T.A.C.S. Offeman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80, 1339–1339 (1958)
P. Feicht, J. Biskupek, T.E. Gorelik, J. Renner, C.E. Halbig, M. Maranska, F. Puchtler, U. Kaiser, S. Eigler, Brodie’s or hummers’ method: oxidation conditions determine the structure of graphene oxide. Chem.-Eur. J. 25, 8955–8959 (2019)
Y.M. Hunge, A.A. Yadav, A.G. Dhodamani, N. Suzuki, C. Terashima, A. Fujishima, Enhanced photocatalytic performance of ultrasound treated GO/TiO2 composite for photocatalytic degradation of salicylic acid under sunlight illumination. Ultrason. Sonochem. 61, 104849–10854 (2020)
V.M. Boychuk, V.O. Kotsyubynsky, K.V. Bandura, I.P. Yaremiy, S.V. Fedorchenko, Reduced graphene oxide obtained by hummers and marcano-tour methods: comparison of electrical properties. J. Nanosci. Nanotechnol. 19, 7320–7329 (2019)
L.J. Cote, F. Kim, J.X. Huang, Langmuir-blodgett assembly of graphite oxide single layers. J. Am. Chem. Soc. 131, 1043–1049 (2009)
M.J. Fernandez-Merino, L. Guardia, J.I. Paredes, S. Villar-Rodil, P. Solis-Fernandez, A. Martinez-Alonso, J.M.D. Tascon, Vitamin C is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions. J. Phys. Chem. C. 114, 6426–6432 (2010)
I.K. Moon, J. Lee, R.S. Ruoff, H. Lee, Reduced graphene oxide by chemical graphitization. Nat. Commun. 1, 73–78 (2010)
D. Han, G. Guo, Y. Yan, T. Li, B. Wang, A. Dong, Pomegranate-like: carbon-coated Fe3O4 nanoparticle superparticles for high-performance lithium storage. Energy Storage Mater. 10, 32–39 (2018)
Acknowledgments
We gratefully acknowledge the support of the National Natural Science Foundation of China (21473051), the Natural Science Foundation of Heilongjiang Province (LH2019B014), and Youth Science and Technology Innovation Team Project of Heilongjiang Province (2018-KYYWF-1593).
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Sun, Q., Liu, J., Xie, Y. et al. Monodisperse MnO nanoparticles in situ grown on reduced graphene oxide via hydrophobic interaction for excellent electromagnetic wave absorption. Journal of Materials Research 37, 2175–2184 (2022). https://doi.org/10.1557/s43578-022-00491-8
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DOI: https://doi.org/10.1557/s43578-022-00491-8