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Temperature dependence of the ferromagnetic resonance (FMR) for MnxCo1−xFe2O4 (0 ≤ x ≤ 1) nanoparticles

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Abstract

Ferromagnetic resonance was used to study the temperature dependence of mixed manganese-cobalt ferrite nanoparticles with a size range between 5 and 42 nm synthesized by the hydrothermal method. Structural characterization was carried out using X-ray diffraction, scanning, and transmission electron microscopy. M(H) curves as a function of the Mn2+ content at 2.5 and 300 K, and FMR in the temperature range of 80 < T < 700 K were used for the magnetic characterization. Temperature dependence of the resonance field shows three regions that can be interpreted in terms of agglomeration, dispersion and superparamagnetism in the samples. The HR and \({\Delta H}_{\text{PP}}\) as a function of the temperature and Mn2+ content allows us to elucidate the key characteristics of the deviation from the ideal superparamagnetic behavior observed by magnetic measurements and open up new research possibilities for evaluating interparticle interactions in nanoparticles.

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Acknowledgments

Thanks to the FONACIT for the financing of the PEII 2011001368 and MPPCTI- ECOS-Nord (V13PS01). The authors thank the CNRS, the University of Montpellier, and the Venezuelan Institute for Scientific Research (IVIC) for financial support. We also thank the Platform of Analysis and Characterizations of ICGM for measurements.

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Authors and Affiliations

  1. Instituto Venezolano de Investigaciones Cientifícas (IVIC), Apartado 232, Caracas, 1020-A, Venezuela

    Yeni Sánchez, Sarah Briceño & Pedro Silva

  2. School of Physical Sciences and Nanotechnology, Yachay Tech University, 100119, Urcuquí, Ecuador

    Sarah Briceño

  3. ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier, France

    J. Larionova, J. Long & Y. Guari

  4. Escuela Politecnica Superior del Litoral (ESPOL), Departamento de Física, FCNM, Campus Gustavo Galindo, Guayaquil, Ecuador

    Pedro Silva

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  1. Yeni Sánchez
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Correspondence to Pedro Silva.

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Sánchez, Y., Briceño, S., Larionova, J. et al. Temperature dependence of the ferromagnetic resonance (FMR) for MnxCo1−xFe2O4 (0 ≤ x ≤ 1) nanoparticles. Journal of Materials Research 36, 3329–3338 (2021). https://doi.org/10.1557/s43578-021-00345-9

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