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Unraveling synergistic mixing of SnO2–TiO2 composite as anode for Li-ion battery and their electrochemical properties

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  • Focus issue: Advanced Nanocatalysts for Electrochemical Energy Storage and Generation
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Abstract

The effect of Sn/Ti ratio on the electrochemical properties of the anode is studied in Sn-doped TiO2 and SnO2–TiO2 nanofibers synthesized using a pilot-scale electrospinning system. Changes in the lattice structure of TiO2 due to the presence of Sn are studied through X-ray diffraction and high-resolution transmission electron microscopy. Lowering of electrochemical potential (vs Li/Li+) is observed alongside the enhanced capacity (400–600 mAh g−1) with increasing Sn content. Formation of SnO2 grain in sample with high Sn content (70 wt%) shows detrimental effect on cycling stability due to severe volume changes during lithiation/delithiation. We show that the relative fraction of TiO2 and SnO2 framework determines whether the composite is high capacity or high stability. In overall, SnO2–TiO2 composite anode with optimized Sn/Ti ratio can be used for high energy density, cycling stability and working potential lithium-ion battery.

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The relative fraction of TiO2 and SnO2 framework determines whether the composite is high capacity or high stability

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All data generated or analyzed during this study are included in this published article [and its supplementary information files].

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Acknowledgments

This work is funded by the Fundamental Research Grant Scheme of the Ministry of Education, Govt. of Malaysia through FRGS/1/2019/STG07/UMP/01/1. Ling JK acknowledges the financial support from Post-graduate Research Scheme (PGRS) by Universiti Malaysia Pahang (http://www.ump.edu.my) through UMP.05.02/26.10/03/03/PGRS2003123. The authors would like to express gratitude to Battery Research Centre of Green Energy (BRCGE) of Ming Chi University of Technology, New Taipei City, Taiwan, R.O.C. (https://www.mcut.edu.tw/) and Taiwan Experience Education Program (TEEP@AsiaPlus) for their research financial support.

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Authors and Affiliations

  1. Nanostructured Renewable Energy Material Laboratory, Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, 26300, Kuantan, Pahang, Malaysia

    JinKiong Ling, Bhupender Pal & Rajan Jose

  2. Battery Research Center for Green Energy (BRCGE), Ming Chi University of Technology, No. 84 Gongzhuan Road, Taishan District, New Taipei City, Taiwan

    Chelladurai Karuppiah & Chun-Chen Yang

  3. Centre of Excellent in Transportation Electrification and Energy Storage (CETEES), Institute of Research Hydro-Québec, Lionel-Boulet Blvd, Varennes, QC, J3X 1S1, Canada

    M. V. Reddy

  4. Department of Inorganic Chemistry, University of Chemistry and Technology Prague, Technicka 5, 166 28, Prague 6, Czech Republic

    Bhupender Pal

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Ling, J., Karuppiah, C., Reddy, M.V. et al. Unraveling synergistic mixing of SnO2–TiO2 composite as anode for Li-ion battery and their electrochemical properties. Journal of Materials Research 36, 4120–4130 (2021). https://doi.org/10.1557/s43578-021-00313-3

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