Abstract
The search for materials that meet contemporary engineering challenges requires the exploration of structures only found beyond those achieved through conventional synthesis and processing techniques. These far-from-equilibrium materials are achievable through the application of one or multiple coupled extreme environments, allowing the systems to be kinetically trapped, or meta-equilibrated, in unique conditions across several length scales during processing. Here, we provide an overview of how coupled extreme environments, such as high temperature, high load or shear, irradiation and oxidation, may lead to the formation of materials with unique hierarchical microstructures with tolerance to harsh conditions beyond the capabilities of conventional materials. We discuss fundamentals, challenges, and opportunities of unprecedented performances for metals, oxides, and boride ceramics highlighting the distinctive characteristics that make these far-from-equilibrium materials exceptional for use in fields where multiple extreme conditions are met, such as the aerospace, nuclear energy, and energy-storage applications.
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Acknowledgments
L.S. acknowledges the contribution from Prof. W.G. Fahrenholtz and Prof. G.E. Hilmas from Missouri University of Science and Technology in Rolla for strength tests above 1600°C.
Funding
L.S. acknowledges the funds received from the NATO Science for Peace and Security Programme under Grant No. MYP-G5767 (SUSPENCE) and from the US AFOSR through the Cooperative Agreement No. FA9550-21-1-0399 (NACREOUS) with M.-J. Pan as contract monitor. R.C. thanks DMR Ceramics 2015650 and FAPESP 2022/04150-6. C.P. acknowledges support by the Laboratory Directed Research and Development program at the Pacific Northwest National Laboratory (PNNL) as part of the Solid Phase Processing Science Initiative. PNNL is a multiprogram national laboratory operated by Battelle for the US Department of Energy under Contract No. DEAC05-76RL01830. K.A.A. gratefully acknowledges financial support from the National Research Council Research Associateship Program. L.M.R. and K.A.A. are grateful to D. Miracle for insightful discussions and review. Any views expressed here are those of the authors’ and do not reflect the official policy or position of the US Air Force, Department of Defense, or the US Government. Distribution A; cleared for public release (AFR-2022-4227).
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Silvestroni, L., Rueschhoff, L.M., Acord, K.A. et al. Synthesis of far-from-equilibrium materials for extreme environments. MRS Bulletin 47, 1143–1153 (2022). https://doi.org/10.1557/s43577-022-00454-8
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DOI: https://doi.org/10.1557/s43577-022-00454-8