Skip to main content

Advertisement

Log in

Graphene Metrology Using Fluorescence Quenching of Different Fluorescent Dyes

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

The unique structure and properties of graphene initiated broad fundamental and technological research, and highlighted graphene as a new candidate for various applications such as energy storage, solar cells and electronic devices. Chemical vapor deposition (CVD) has been utilized for industrial large-scale synthesis of graphene. Regardless of the synthesis process, graphene should be transferred to arbitrary substrates for different applications. The transfer processes, introduce defects such as wrinkles and cracks in graphene which compromise the properties and applications. In recent years, fundamental research has been focused on characterization of graphene to develop new techniques for large-scale, high-resolution graphene metrology. Herein, a complementary high throughput metrology technique using fluorescent quenching is further investigated for different fluorescent dyes to characterize CVD synthesized graphene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. K. Geim, K. S. Novoselov, “The rise of graphene ”, nature materials, Vol. 6, 183–191 (2007).

    Article  CAS  Google Scholar 

  2. A. H. Castro Neto, F. Guinea, N. M. R. Peres, K. S. Novoselov, A. K. Geim, “The electronic properties of graphene ”, Rev. Mod. Phys., Vol. 81, No.1, 109–161 (2009).

    Article  CAS  Google Scholar 

  3. C. Mattevi, H. Kim, M. Chhuwalla, “A review of chemical vapour deposition of graphene on copper ”, J. Mater. Chem., 21, 3324–3334 (2011).

    Article  CAS  Google Scholar 

  4. R. R. Nair, P. Blake, A. N. Grigorenko, K. S. Novoselov, T. J. Booth, T. Stauber, N. M. R. Peres, A. K. Geim, “Fine Structure Constant Defines Visual Transparency of Graphene ”, Science, 320, 1308 (2008).

    Article  CAS  Google Scholar 

  5. J. R. Kyle, C. S. Ozkan, M. Ozkan, “Industrial graphene metrology ”, Nanoscale, 4, 3807–3819 (2012).

    Article  CAS  Google Scholar 

  6. E. Treossi, M. Melucci, A. Liscio, M. Gazzano, P. Samori, V. Palermo, “High-Contrast Visualization of Graphene Oxide on Dye-Sensitized Glass, Quartz, and Silicon by Fluorescence Quenching ”, J. Am. Chem. Soc., 131, 15576–15577 (2009).

    Article  CAS  Google Scholar 

  7. J. Kim, L. J. Cote, F. Kim, J. Huang, “Visualizing Graphene Based Sheets by Fluorescence Quenching Microscopy ”, J. Am. Chem. Soc., 132, 260–267 (2009).

    Article  CAS  Google Scholar 

  8. J. R. Kyle, A. Guvenc, W. Wang, M. Ghazinejad, J. Lin, S. Guo, C. S. Ozkan, M. Ozkan, “Centimeter-Scale High-Resolution Metrology of Entire CVD-Grown Graphene Sheets ”, Small, Vol. 7, No.18, 2599–2606 (2011).

    Article  CAS  Google Scholar 

  9. H. S. S. Ramakrishna Matte, K. S. Subrahmanyam, K. Venkata Rao, S. J. George, C. N. R. Rao, “Quenching of fluorescence of aromatic molecules by graphene due to electron transfer ”, Chemical Physics Letters, 506, 260–264 (2011).

    Article  CAS  Google Scholar 

  10. R. S. Swathi, K. L. Sebastian, “Resonance energy transfer from a dye molecule to graphene ”, J. Chem. Phys. 129, 054703 (2008).

    Article  CAS  Google Scholar 

  11. R. S. Swathi, K. L. Sebastian, “Distance dependence of fluorescence resonance energy transfer ”, J. Chem. Sci., 121, 777–787 (2009).

    Article  CAS  Google Scholar 

  12. R. S. Swathi, K. L. Sebastian, “Long range resonance energy transfer from a dye molecule to graphene has (distance)−4 dependence ”, J. Chem. Phys., 130, 086101 (2009).

    Article  CAS  Google Scholar 

  13. S. L. Bondarev, V. N. Knyokshto, V. I Stepuro, A. P. Stupak, A. A. Turban, “Fluorescence and Electronic Structure of the Laser Dye DCM in Solution and in Polymethylmethacrylate ”, J. of Applied Spectroscopy, Vol. 71, No.2, 194–201 (2004).

    Article  CAS  Google Scholar 

  14. Y. Liu, C. Liu, Y. Liu, “Investigation on fluorescence quenching of dyes by graphite oxide and graphene ”, Applied Surface Science, 257, 5513–5518 (2011).

    Article  CAS  Google Scholar 

  15. Y Urano, M. Kamia, K. Kanda, T. Ueno, K. Hirose, T. Nagano, “Evolution of Fluorescein as a Platform for Finely Tunable Fluorescence Probes ”, J. Am. Chem. Soc., 127, 4888–4894 (2005).

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We gratefully acknowledge financial support for this work by the Riverside Public Utilities, the CMMI Division of the National Science Foundation (Award: 0800680), the Materials Research Science and Engineering Center (NSF-MRSEC) on Polymers (Award: 0213695), the Winston Chung Global Energy Center at UCR, and the Nanoscale Science and Engineering Center (NSF-NSEC) on hierarchical manufacturing (CHM, Award: 0531171).

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bay, H.H., Ghazinejad, M., Penchev, M. et al. Graphene Metrology Using Fluorescence Quenching of Different Fluorescent Dyes. MRS Online Proceedings Library 1451, 51–56 (2012). https://doi.org/10.1557/opl.2012.1454

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/opl.2012.1454

Navigation