Abstract
Monolayers of cobalt phthalocyanine (CoPc) and fluorinated cobalt phthalocyanine (F16CoPc) on silver (111) and on highly (0001) oriented pyrolytic graphite (HOPG) were imaged with a scanning tunneling microscope (STM) at cryogenic temperatures (around 30 K) at Chemnitz University of Technology. Domains of regular arrays with periodicity in two dimensions (2D) and a variety of plane symmetries were observed. Crystallographic image processing (CIP) was used to quantify deviations from the plane symmetry groups and to obtain symmetrized versions of the content of the average unit cells of some of these arrays. Conclusions on the point symmetry of the CoPc and F16CoPc molecules within the arrays were drawn.
This is a preview of subscription content, access via your institution.
References
X. Zou and S. Hovmöller, in: Industrial Applications of Electron Microscopy, edited by Z.R. Li, Marcel Dekker, New York, 2003, p. 583–614.
T. Oku, Solid State Commun. 127, 689 (2003).
D. G. Morgan, Q. M. Ramasse, and N. D. Browning, J. Electron Microsc. 58, 223 (2009).
P. Moeck, in: Microscopy: Science Technology, Applications and Education, Microscopy Book Series, Vol. 4, edited by A. Méndez-Vilas and J. Diaz, 2010, http://www.formatex.org/microscopy4/.
S. Park and C. F. Quate, J. Appl. Phys. 62, 312 (1987).
T. Hahn (editor), International Tables for Crystallography. Brief Teaching Edition of Volume A, Space-group Symmetry, 5th revised edition, Chester, International Union of Crystallography, 2005.
K. Kanatani, Inter. J. of Computer Vision 26, 171 (1998).
M. Hietschold, M. Lackinger, S. Griessl, W. M. Heckl, T. G. Gopakumar, and G. W. Flynn, Microelec. Engin. 82, 207 (2005).
P. Curie, J. de Physique 3, 393 (1894); see, e.g., the geometric-structural crystallography textbook by S. M. Allen and E. L. Thomas, The Structure of Materials, John Wiley & Sons, New York, 1999.
T. Kataoka, H. Fukagawa, S. Hosoumi, K. Nebashi, K. Sakamoto, and N. Ueno, Chem. Phys. Lett. 451, 43 (2008).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Moeck, P., Straton, J., Toader, M. et al. Crystallographic Processing of Scanning Tunneling Microscopy Images of Cobalt Phthalocyanines on Silver and Graphite. MRS Online Proceedings Library 1318, 105 (2011). https://doi.org/10.1557/opl.2011.278
Published:
DOI: https://doi.org/10.1557/opl.2011.278