Abstract
Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5f elements. Nanoscale control of actinide materials is emerging, as shown by the creation of a considerable range of cluster and tubular topologies. Departures from established structural trends for actinyl ions are provided by cation-cation interactions in which an O atom of one actinyl ion is an equatorial ligand of a bipyramid of another actinyl ion. The solid-state structural complexity of actinide materials has been further demonstrated by open framework materials with interesting properties. The U(VI) tetraoxide core has been added to this cation’s repertoire of coordination possibilities. The emergence of pentavalent uranium solid-state and coordination chemistry has resulted from the prudent selection of ligands. Finally, analogues of the uranyl ion have challenged our understanding of this normally unreactive functional group.
Similar content being viewed by others
References
P.L. Arnold, J.B. Love, D. Patel, Coord. Chem. Rev. 253, 1973 (2009).
S. Fortier, T.W. Hayton, Coord. Chem. Rev. 254, 197 (2010).
T.W. Hayton, Dalton Trans. 39, 1145 (2010).
S.T. Liddle, Proc. R. Soc. Lond. A: Math. Phys. Sci. 465, 1673 (2009).
P. Maldivi, L. Petit, C. Adamo, V. Vetere, C.R. Chim. 10, 888 (2007).
B.J. Mincher, G. Modolo, S.P. Mezyk, Solvent Extr. Ion Exch. 27, 579 (2009).
K.T. Moore, G. van der Laan, Rev. Mod. Phys. 81, 235 (2009).
P. Santini, S. Carretta, G. Amoretti, R. Caciuffo, N. Magnani, G.H. Lander, Rev. Mod. Phys. 81, 807 (2009).
G. Schreckenbach, G.A. Shamov, Acc. Chem. Res. 43, 19 (2010).
P.C. Burns, Can. Mineral. 43, 1839 (2005).
T.Z. Forbes, P.C. Burns, S. Skanthakumar, L. Soderholm, J. Am. Chem. Soc. 129, 2760 (2007).
T.Z. Forbes, P.C. Burns, L. Soderholm, S. Skanthakumar, Chem. Mater. 18, 1643 (2006).
T.Z. Forbes, C. Wallace, P.C. Burns, Can. Mineral. 46, 1623 (2008).
M.S. Grigoriev, I.A. Charushnikova, N.N. Krot, Radiochemistry 47, 549 (2005).
M.S. Grigoriev, A.M. Fedoseev, N.A. Budantseva, M.Y. Antipin, Radiochemistry 47, 545 (2005).
A.G.D. Nelson, T.H. Bray, T.E. Albrecht-Schmitt, Angew. Chem. Int. Ed. 47, 6252 (2008).
A.G.D. Nelson, T.H. Bray, W. Zhan, R.G. Haire, T.S. Sayler, T.E. Albrecht-Schmitt, Inorg. Chem. 47, 4945 (2008).
S.A. Wang, E.V. Alekseev, J. Ling, S. Skanthakumar, L. Soderholm, W. Depmeier, T.E. Albrecht-Schmitt, Angew. Chem. Int. Ed. 49, 1263 (2010).
L. Soderholm, P.M. Almond, S. Skanthakumar, R.E. Wilson, P.C. Burns, Angew. Chem. Int. Ed. 47, 298 (2008).
R.E. Wilson, S. Skanthakumar, P.C. Burns, L. Soderholm, Angew. Chem. Int. Ed. 46, 8043 (2007).
R.E. Wilson, S. Skanthakumar, G. Sigmon, P.C. Burns, L. Soderholm, Inorg. Chem. 46, 2368 (2007).
L.R. Morss, N.M. Edelstein, J. Fuger, J.J. Katz, The Chemistry of the Actinide and Transactinide Elements (Springer, Dordrecht, 2006), p. 3440.
P.C. Burns, R.C. Ewing, F.C. Hawthorne, Can. Mineral. 35, 1551 (1997).
D.L. Long, R. Tsunashima, L. Cronin, Angew. Chem. Int. Ed. 49, 1736 (2010).
T.E. Albrecht-Schmitt, Angew. Chem. Int. Ed. 44, 4836 (2005).
P.C. Burns, K.A. Kubatko, G. Sigmon, B.J. Fryer, J.E. Gagnon, M.R. Antonio, L. Soderholm, Angew. Chem. Int. Ed. 44, 2135 (2005).
T.Z. Forbes, J.G. McAlpin, R. Murphy, P.C. Burns, Angew. Chem. Int. Ed. 47, 2824 (2008).
S.V. Krivovichev, V. Kahlenberg, I.G. Tananaev, R. Kaindil, E. Mersdorf, B.F. Myasoedov, J. Am. Chem. Soc. 127, 1072 (2005).
G. Sigmon, J. Ling, D.K. Unruh, L. Moore-Shay, M. Ward, B. Weaver, P.C. Burns, J. Am. Chem. Soc. 131, 16648 (2009).
G.E. Sigmon, D.K. Unruh, J. Ling, B. Weaver, M. Ward, L. Pressprich, A. Simonetti, P.C. Burns, Angew. Chem. Int. Ed. 48, 2737 (2009).
G.E. Sigmon, B. Weaver, K.A. Kubatko, P.C. Burns, Inorg. Chem. 48, 10907 (2009).
E.V. Alekseev, S.V. Krivovichev, W. Depmeier, Angew. Chem. Int. Ed. 47, 549 (2008).
J.C. Sullivan, A.J. Zielen, J.C. Hindman, J. Am. Chem. Soc. 83, 3373 (1961).
M.S. Grigoriev, A.I. Yanovskii, A.M. Fedoseev, N.A. Budantseva, Y.T. Struchkov, N.N. Krot, V.I. Spitsyn, Dokl. Akad. Nauk SSSR 300, 618 (1988).
E.V. Alekseev, S.V. Krivovichev, T. Malcherek, W. Depmeier, Inorg. Chem. 46, 8442 (2007).
S.A. Wang, E.V. Alekseev, D.W. Juan, W.H. Casey, B.L. Phillips, W. Depmeier, T.E. Albrecht-Schmitt, Angew. Chem. Int. Ed. 49, 1057 (2010).
R.E. Wilson, S. Skanthakumar, K.E. Knope, C.L. Cahill, L. Soderholm, Inorg. Chem. 47, 9321 (2008).
K.M. Ok, J. Sung, G. Hu, R.M.J. Jacobs, D. O’Hare, J. Am. Chem. Soc. 130, 3762 (2008).
S.J. Wu, J. Ling, S.A. Wang, S. Skanthakumar, L. Soderholm, T.E. Albrecht-Schmitt, E.V. Alekseev, S.V. Krivovichev, W. Depmeier, Eur. J. Inorg. Chem. 4039 (2009).
A. Ekstrom, Inorg. Chem. 13, 2237 (1974).
T.W. Newton, F.B. Baker, Inorg. Chem. 4, 1166 (1965).
R.D. Saini, P.K. Bhattacharyya, R.M. Iyer, J. Photochem. Photobiol. A, Chem. 47, 181 (1989).
A. Ikeda, C. Hennig, S. Tsushima, K. Takao, Y. Ikeda, A.C. Scheinost, G. Bernhard, Inorg. Chem. 46, 4212 (2007).
K. Mizuoka, I. Grenthe, Y. Ikeda, Inorg. Chem. 44, 4472 (2005).
J.C. Berthet, M. Ephritikhine, J. Chem. Soc. Chem. Commun. 1566 (1993).
C.R. Graves, J.L. Kiplinger, Chem. Commun. 3831 (2009).
C.R. Graves, A.E. Vaughn, E.J. Schelter, B.L. Scott, J.D. Thompson, D.E. Morris, J.L. Kiplinger, Inorg. Chem. 47, 11879 (2008).
C.R. Graves, B.L. Scott, D.E. Morris, J.L. Kiplinger, J. Am. Chem. Soc. 129, 11914 (2007).
C.R. Graves, P. Yang, S.A. Kozimor, A.E. Vaughn, D.L. Clark, S.D. Conradson, E.J. Schelter, B.L. Scott, J.D. Thompson, P.J. Hay, D.E. Morris, J.L. Kiplinger, J. Am. Chem. Soc. 130, 5272 (2008).
K. Mizuoka, Y. Ikeda, Inorg. Chem. 42, 3396 (2003).
K. Mizuoka, Y. Ikeda, Radiochim. Acta 92, 631 (2004).
K. Mizuoka, S.Y. Kim, M. Hasegawa, T. Hoshi, G. Uchiyama, Y. Ikeda, Inorg. Chem. 42, 1031 (2003).
K. Takao, M. Kato, S. Takao, A. Nagasawa, G. Bernhard, C. Hennig, Y. Ikeda, Inorg. Chem. 49, 2349 (2010).
K. Takao, S. Tsushima, S. Takao, A.C. Scheinost, G. Bernhard, Y. Ikeda, C. Hennig, Inorg. Chem. 48, 9602 (2009).
J.C. Berthet, M. Nierlich, M. Ephritikhine, Angew. Chem. Int. Ed. 42, 1952 (2003).
P.L. Arnold, D. Patel, A.J. Blake, C. Wilson, J.B. Love, J. Am. Chem. Soc. 128, 9610 (2006).
P.L. Arnold, D. Patel, C. Wilson, J.B. Love, Nature 451, 315 (2008).
J.C. Berthet, G. Siffredi, P. Thuery, M. Ephritikhine, Chem. Commun. 3184 (2006).
J.C. Berthet, G. Siffredi, P. Thuery, M. Ephritikhine, Dalton Trans. 3478 (2009).
F. Burdet, J. Pecaut, M. Mazzanti, J. Am. Chem. Soc. 128, 16512 (2006)
T.W. Hayton, G. Wu, Inorg. Chem. 47, 7415 (2008).
T.W. Hayton, G. Wu, J. Am. Chem. Soc. 130, 2005 (2008)
T.W. Hayton, G. Wu, Inorg. Chem. 48, 3065 (2009).
P. Horeglad, G. Nocton, Y. Filinchuk, J. Pecaut, M. Mazzanti, Chem. Commun. 1843 (2009).
L. Natrajan, F. Burdet, J. Pecaut, M. Mazzanti, J. Am. Chem. Soc. 128, 7152 (2006).
G. Nocton, P. Horeglad, J. Pecaut, M. Mazzanti, J. Am. Chem. Soc. 130, 16633 (2008).
G. Nocton, P. Horeglad, V. Vetere, J. Pecaut, L. Dubois, P. Maldivi, N.M. Edelstein, M. Mazzanti, J. Am. Chem. Soc. 132, 495 (2010).
L.P Spencer, E.J. Schelter, P. Yang, R.L. Gdula, B.L. Scott, J.D. Thompson, J.L. Kiplinger, E.R. Batista, J.M. Boncella, Angew. Chem. Int. Ed. 48, 3795 (2009).
D.R. Brown, R.G. Denning, Inorg. Chem. 35, 6158 (1996).
T.W. Hayton, J.M. Boncella, B.L. Scott, P.D. Palmer, E.R. Batista, P.J. Hay Science 310, 1941 (2005).
N. Kaltsoyannis, Inorg. Chem. 39, 6009 (2000).
V.C. Williams, M. Muller, M.A. Leech, R.G. Denning, M.L.H. Green, Inorg. Chem. 39, 2538 (2000).
M. Santos, J. Marcalo, A.P. de Matos, J.K. Gibson, R.G. Haire, Eur. J. Inorg. Chem. 3346 (2006).
K. Mizuoka, S. Tsushima, M. Hasegawa, T. Hoshi, Y. Ikeda, Inorg. Chem. 44, 6211 (2005).
Rights and permissions
About this article
Cite this article
Burns, P.C., Ikeda, Y. & Czerwinski, K. Advances in actinide solid-state and coordination chemistry. MRS Bulletin 35, 868–876 (2010). https://doi.org/10.1557/mrs2010.713
Published:
Issue Date:
DOI: https://doi.org/10.1557/mrs2010.713