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Organic Semiconductor Devices with Enhanced Field and Environmental Responses for Novel Applications

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Abstract

We discuss some recent advances in the use of organic semiconductor devices with additional or enhanced functionality beyond simple electrical switching. These include diodes that act as local temperature sensors or that filter reverse-bias currents at tens of megahertz frequency. Transistors are described with a range of sensing and reporting functions, for such properties as pressure, magnetic field, and chemical vapor. Because these devices will likely be employed in arrays and assemblies, we also present concepts of some larger, integrated components such as artificial skin, sensor arrays, and wireless power systems. The common theme of these devices is that they build on an extensive and growing understanding of the parent transistors and diodes, but represent a departure into new physical phenomena and application areas.

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References

  1. F. Faupel, C. Dimitrakopoulos, A. Kahn, C. Woll, J. Mater. Res. 19, 1887 (2004).

    CAS  Google Scholar 

  2. D. Gamota, P. Brazis, K. Kalyanasundaram, Printed Organic and Molecular Electronics (Kluwer Academic Publishers, Norwell, MA, 2004).

    Google Scholar 

  3. S. Jenekhe, Chem. Mater. 16, 4381 (2004).

    CAS  Google Scholar 

  4. C. Kagan, P. Andry, Thin Film Transistors (Marcel Dekker, New York, 2004).

    Google Scholar 

  5. G. Malliaras, R. Friend, Phys. Today 58, 53 (2005).

    CAS  Google Scholar 

  6. Y.M. Sun, Y.Q. Liu, D.B. Zhu, J. Mater. Chem. 15, 53 (2005).

    CAS  Google Scholar 

  7. K.P. Zauner, Crit. Rev. Solid State Mater. Sci. 30, 33 (2005).

    CAS  Google Scholar 

  8. H.E. Katz, Chem. Mater. 16, 4748 (2004).

    CAS  Google Scholar 

  9. H.E. Katz, C. Kloc, Z. Bao, J. Zaumseil, V. Sundar, J. Mater. Res. 19, 1995 (2004).

    CAS  Google Scholar 

  10. A. Facchetti, M.-H. Yoon, T.J. Marks, Chem. Mater. 16, 4715 (2004).

    CAS  Google Scholar 

  11. A. Dodabalapur, Mater. Today 9, 24 (2006).

    CAS  Google Scholar 

  12. T.B. Singh, N.S. Sariciftci, Annu. Rev. Mater. Res. 36, 199 (2006).

    CAS  Google Scholar 

  13. Q.X. Tang, R.J. Li, H.F. Wang, H.X. Li, W.P. Hu, Prog. Chem. 18, 1538 (2006).

    CAS  Google Scholar 

  14. D. Gamota, Printed Organic and Molecular Electronics (Springer, New York, 2004).

    Google Scholar 

  15. Z. Bao, J. Locklin, Eds., Organic Field-Effect Transistors (CRC Press, Boca Raton, FL, 2007).

  16. C. Kagan, P. Andry, Thin-film Transistors (Marcel Dekker, Inc., New York, 2003).

    Google Scholar 

  17. E. Holder, B.M.W. Langeveld, U.S. Schubert, Adv. Mater. 17, 1109 (2005).

    CAS  Google Scholar 

  18. T. Ishibashi, J. Yamada, T. Hirano, Y. Iwase, Y. Sato, R. Nakagawa, M. Sekiya, T. Sasaoka, T. Urabe Jpn. J. Appl. Phys., Part 1 45, 4392 (2006).

    CAS  Google Scholar 

  19. R.U.A. Khan, C. Hunziker, P. Gunter, J. Mater. Sci.: Mater. Electron. 17, 467 (2006).

    CAS  Google Scholar 

  20. F. Carpi, D. De Rossi, Opt. Laser Technol. 38, 292 (2006).

    CAS  Google Scholar 

  21. H. Antoniadis, M.W. Lui, J. Soc. Inf. Display 13, 389 (2005).

    Google Scholar 

  22. http://www.tmcnet.com/ce/articles/11643-sony-launch-organic-light-emitting-diode-oled-tvs.html.

  23. http://www.reuters.com/article/technologyNews/idUST32201620070412).

  24. F. So, B. Krummacher, M.K. Mathai, D. Poplavskyy, S.A. Choulis, V.E. Choong. J. Appl. Phys. 102 (9), 091101 (2007).

    Google Scholar 

  25. J. Ackermann, C. Videlot, A. El Kassmi, R. Guglielmetti, F. Fages, Adv. Funct. Mater. 15, 810 (2005).

    CAS  Google Scholar 

  26. C.-W. Chu, Y. Shao, V. Shrotriya, Y. Yang, Appl. Phys. Lett. 86, 243506 (2005).

    Google Scholar 

  27. S.R. Forrest, MRS Bull. 30 (1), 28 (2005).

    CAS  Google Scholar 

  28. K. Hara, T. Sato, R. Katoh, A. Furube, T. Yoshihara, M. Murai, M. Kurashige, S. Ito, A. Shinpo, S. Suga, H. Arakawa, Adv. Funct. Mater. 15, 246 (2005).

    CAS  Google Scholar 

  29. L. Schmidt-Mende, U. Bach, R. Humphry-Baker, T. Horiuchi,. H. Miura, S. Ito, S. Uchida, M. Gratzel, Adv. Mater. 17, 813 (2005).

    CAS  Google Scholar 

  30. M. Velusamy, K.R.J. Thomas, J.T. Lin, Y.C. Hsu, K.C. Ho, Org. Lett. 7, 1899 (2005).

    CAS  Google Scholar 

  31. F. Yang, M. Shtein, S.R. Forrest, Nat. Mater. 4, 37 (2005).

    Google Scholar 

  32. X.N. Yang, J. Loos, S.C. Veenstra, W.J.H. Verhees, M.M. Wienk, J.M. Kroon, M.A.J. Michels, R.A.J. Janssen, Nano Lett. 5, 579 (2005).

    CAS  Google Scholar 

  33. M.M. Alam, S.A. Jenekhe, Chem. Mater. 16, 4647 (2004).

    CAS  Google Scholar 

  34. G. Dennler, N.S. Sariciftci, Proc. IEEE 93, 1429 (2005).

    CAS  Google Scholar 

  35. J. Nakamura, C. Yokoe, K. Murata, K. Takahashi, J. Appl. Phys. 96, 6878 (2004).

    CAS  Google Scholar 

  36. J.G. Xue, S. Uchida, B.P. Rand, S.R. Forrest, Appl. Phys. Lett. 84, 3013 (2004).

    CAS  Google Scholar 

  37. S. Yoo, B. Domercq, B. Kippelen, Appl. Phys. Lett. 85, 5427 (2004).

    CAS  Google Scholar 

  38. J.G. Xue, B.P. Rand, S. Uchida, S.R. Forrest, J. Appl. Phys. 98 (2005).

  39. W. Ma, C. Yang, X. Gong, K. Lee, A.J. Heeger, Adv. Funct. Mater. 15, 1617 (2005).

    CAS  Google Scholar 

  40. G. Li, V. Shrotriya, J. Huang, Y. Yao, T. Moriarty, K. Emery, Y. Yang, Nat. Mater. 4, 864 (2005).

    CAS  Google Scholar 

  41. H.K. Tian, J. Wang, J. Shi, D. Yan, L. Wang, Y. Geng, F. Wang, J. Mater. Chem. 15, 3026 (2005).

    CAS  Google Scholar 

  42. D.J. Crouch, P.J. Skabara, D. Sparrowe, M. Heeney, I. McCulloch, S.J. Coles, M.B. Hursthouse, Chem. Commun. 1465 (2005).

  43. Y.N. Li, Y.L. Wu, S. Gardner, B.S. Ong, Adv. Mater. 17, 849 (2005).

    CAS  Google Scholar 

  44. M. Mas-Torrent, P. Hadley, S.T. Bromley, N. Crivillers, J. Veciana, C. Rovira, Appl. Phys. Lett. 86, 012110 (2005).

    Google Scholar 

  45. H. Meng, F. Sun, M.B. Goldfinger, G.D. Jaycox, Z. Li, W.J. Marshall, G.S. Blackman, J. Am. Chem. Soc. 127, 2406 (2005).

    CAS  Google Scholar 

  46. J.A. Merlo, C.R. Newman, C.P. Gerlach, T.W. Kelley, D.V. Muyres, S.E. Fritz, M.F. Toney, C.D. Frisbie, J. Am. Chem. Soc. 127, 3997 (2005).

    CAS  Google Scholar 

  47. T. Mori, H. Takeuchi, H. Fujikawa, J. Appl. Phys. 97, 066102 (2005).

    Google Scholar 

  48. M.M. Payne, S.R. Parkin, J.E. Anthony, C.C. Kuo, T.N. Jackson, J. Am. Chem. Soc. 127, 4986 (2005).

    CAS  Google Scholar 

  49. S.A. Ponomarenko, S. Kirchmeyer, M. Halik, H. Klauk, U. Zschieschang, G. Schmid, A. Karbach, D. Drechsler, N.M. Alpatova, Synth. Met. 149, 231 (2005).

    CAS  Google Scholar 

  50. V.A.L. Roy, Y.G. Zhi, Z.X. Xu, S.C. Yu, P.W.H. Chan, C.M. Che, Adv. Mater. 17, 1258 (2005).

    CAS  Google Scholar 

  51. K. Takimiya, Y. Kunugi, Y. Toyoshima, T. Otsubo, J. Am. Chem. Soc. 127, 3605 (2005).

    CAS  Google Scholar 

  52. A.J.J.M. van Breemen, P.T. Herwig, C.H.T. Chlon, J. Sweelssen, H.F.M. Schoo, E.M. Benito, D.M. de Leeuw, C. Tanase, J. Wildeman, P.W.M. Blom, Adv. Funct. Mater. 15, 872 (2005).

    Google Scholar 

  53. K. Takimiya, H. Ebata, K. Sakamoto, T. Izawa, T. Otsubo, Y. Kunugi, J. Am. Chem. Soc. 128, 12604 (2006).

    CAS  Google Scholar 

  54. D.A. da Silva, E.G. Kim, J.L. Bredas, Adv. Mater. 17, 1072 (2005).

    Google Scholar 

  55. E. Menard, , V. Podzorov, S.-H. Hur, A. Gaur, M.E. Gershenson, J.A. Rogers, Adv. Mater. 16, 2097 (2004).

    CAS  Google Scholar 

  56. B.S. Ong, Y.L. Wu, P. Liu, S. Gardner, Adv. Mater. 17, 1141 (2005).

    CAS  Google Scholar 

  57. Y.O. Wu, P. Liu, B.S. Ong, T. Srikumar,. N. Zhao, G. Botton, S. Zhu, Appl. Phys. Lett. 86, 142102 (2005).

    Google Scholar 

  58. D.M. deLeeuw, M.M.J. Simenon, A.R. Brown, R.E.F. Einerhand, Synth. Met. 87, 53 (1997).

    CAS  Google Scholar 

  59. Z.A. Bao, A.J. Lovinger, J. Brown, J. Am. Chem. Soc. 120, 207 (1998).

    CAS  Google Scholar 

  60. A. Ghosh, P.G. Gassman, J. Almlof, J. Am. Chem. Soc. 116, 1932 (1994).

    CAS  Google Scholar 

  61. D. Schlettwein, K. Hesse, N.E. Gruhn, P.A. Lee, K.W. Nebesny, N.R. Armstrong, J. Phys. Chem. B 105, 4791 (2001).

    CAS  Google Scholar 

  62. H.E. Katz, J. Johnson, A.J. Lovinger, W.J. Li, J. Am. Chem. Soc. 122, 7787 (2000).

    CAS  Google Scholar 

  63. H.E. Katz, A.J. Lovinger, J. Johnson, C. Kloc, T. Siegrist, W. Li, Y.-Y. Lin, A. Dodabalapur, Nature 404, 478 (2000).

    CAS  Google Scholar 

  64. H.E. Katz, J. Otsuki, K. Yamazaki, A. Suka, T. Takido, A.J. Lovinger, K. Raghavachari, Chem. Lett. 32, 508 (2003).

    CAS  Google Scholar 

  65. M.H. Yoon, S.A. DiBenedetto, A. Facchetti, T.J. Marks, J. Am. Chem. Soc. 127, 1348 (2005).

    CAS  Google Scholar 

  66. H.Z. Chen, M.-M. Shi, T. Aernouts, M. Wang, G. Borghs, P. Heremans, Sol. Energy Mater. Sol. Cells 87, 521 (2005).

    CAS  Google Scholar 

  67. B.A. Jones, M.J. Ahrens, M. Yoon, A. Facchetti, T.J. Marks, M.R. Wasielewski, Angew. Chem., Int. Ed. 43, 6363 (2004).

    CAS  Google Scholar 

  68. S. Tatemichi, M. Ichikawa, T. Koyama, Y. Taniguchi, Appl. Phys. Lett. 89 (2006).

  69. Y. Inoue, Y. Sakamoto, T. Suzuki, M. Kobayashi, Y. Gao, S. Tokito, Jpn. J. Appl. Phys., Part 1 44, 3663 (2005).

    CAS  Google Scholar 

  70. J.-i. Nishida, Naraso, S. Murai, E. Fujiwara, H. Tada, M. Tomura, Y. Yamashita, Org. Lett. 6, 2007 (2004).

    CAS  Google Scholar 

  71. A. Babel, S.A. Jenekhe, J. Am. Chem. Soc. 125, 13656 (2003).

    CAS  Google Scholar 

  72. T. Someya, Y. Kato, T. Sekitani, S. Iba, Y. Noguchi, Y. Murase, H. Kawaguchi, T. Sakurai, Proc. Natl. Acad. Sci. U.S.A. 102, 12321 (2005).

    CAS  Google Scholar 

  73. M. Ghovanloo, K. Najafi, IEEE Trans. Neural Syst. Rehabil. Eng. 15, 449 (2007).

    Google Scholar 

  74. R.A. Potyrailo, W.G. Morris, Rev. Sci. Instrum. 78 (2007).

  75. V. Subramanian, P.C. Chang, J.B. Lee, S.E. Molesa, S.K. Volkman, IEEE Trans. Components Packaging Technol. 28, 742 (2005).

    CAS  Google Scholar 

  76. Y. Ai, S. Gowrisanker, H. Jia, I. Trachtenberg, E. Vogel, R.M. Wallace, B.E. Gnade, R. Barnett, H. Stiegler, H. Edwards, Appl. Phys. Lett. 90, 262105 (2007).

    Google Scholar 

  77. S. Steudel, S. de Vusser, K. Myny, M. Lenes, J. Genoe, P. Heremans, J. Appl. Phys. 99, 114519 (2006).

    Google Scholar 

  78. S. Steudel, K. Myny, V. Arkhipov, C. Deibel, S. de Vusser, J. Genoe, P. Heremans, Nat. Mater. 4, 597 (2005).

    CAS  Google Scholar 

  79. L.P. Ma, J. Ouyang, Y. Yang, Appl. Phys. Lett. 84, 4786 (2004).

    CAS  Google Scholar 

  80. B. Pradhan, S.K. Batabyal, A.J. Pal, Appl. Phys. Lett. 89 (2006).

  81. S.J. Jiao, Z.Z. Zhang, Y.M. Lu, D.Z. Shen, B. Yao, J.Y. Zhang, B.H. Li, D.X. Zhao, X.W. Fan, Z.K. Tang, Appl. Phys. Lett. 88, 031911 (2006).

    Google Scholar 

  82. D.K. Hwang, H.S. Kim, J.H. Lim, J.Y. Oh, J.H. Yang, S.J. Park, K.K. Kim, D.C. Look, Y.S. Park, Appl. Phys. Lett. 86, 151917 (2005).

    Google Scholar 

  83. J.M. Bian, X.M. Li, C.Y. Zhang, W.D. Yu, X.D. Gao, Appl. Phys. Lett. 85, 4070 (2004).

    CAS  Google Scholar 

  84. Y. Hirose, W. Chen, E.I. Haskal, S.R. Forrest, A. Kahn, Appl. Phys. Lett. 64, 3482 (1994).

    CAS  Google Scholar 

  85. B.N. Pal, J. Sun, B.J. Jung, E. Choi, A.G. Anreou, H.E. Katz, Adv. Mater 20, 1023 (2008).

    CAS  Google Scholar 

  86. S. Steudel, K. Myny, V. Arkhipov, C. Deibel, S. De Vusser, J. Genoe, and P. Heremans, Nat. Mater. 2005, 4, 597.

    CAS  Google Scholar 

  87. L. Torsi, A. Dodabalapur, L. Sabbatini, P.G. Zambonin, Sens. Actuators B 67, 312 (2000).

    CAS  Google Scholar 

  88. B. Crone, A. Dodabalapur, A. Gelperin, L. Torsi, H. E. Katz, A. J. Lovinger, Z. Bao, Appl. Phys. Lett. 78, 2229 (April 9, 2001).

    CAS  Google Scholar 

  89. D. Li, E.-J. Borkent, R. Nortrup, H. Moon, H.E. Katz, Z. Bao, Appl. Phys. Lett. 86, 042105 (2005).

    Google Scholar 

  90. T. Sekitani, Y. Kato, S. Iba, H. Shinaoka, T. Someya, T. Sakurai, S. Takagi, Appl. Phys. Lett. 86, 073511 (2005).

    Google Scholar 

  91. T. Sekitani, S. Iba, Y. Kato, Y. Noguchi, T. Someya, T. Sakurai, Appl. Phys. Lett. 87, 173502 (2005).

    Google Scholar 

  92. T. Someya, Y. Kato, T. Sekitani, S. Iba, Y. Noguchi, Y. Murase, H. Kawaguchi, T. Sakurai, Proc. Natl. Acad. Sci. U.S.A. 101, 9966 (2004).

    CAS  Google Scholar 

  93. T. Someya, T. Sakurai, 2003 IEEE International Electron Devices Meeting (IEDM), 8.4, Technical Digest 102, 12321 (2003).

    Google Scholar 

  94. H. Kawaguchi, T. Someya, T. Sekitani, T. Sakurai, IEEE J. Solid-State Circuits 40, 177 (2005).

    Google Scholar 

  95. Y. Kato, T. Sekitani, M. Takamiya, M. Doi, K. Asaka, T. Sakurai, T. Someya, IEEE Trans. Electron Devices 54, 202 (2007).

    CAS  Google Scholar 

  96. M. Takamiya, T. Sekitani, Y. Kato, H. Kawaguchi, T. Someya, T. Sakurai, IEEE J. Solid-State Circuits 42, 93 (2007).

    Google Scholar 

  97. D. Cahen, R. Naaman, Z. Vager, Adv. Funct. Mater. 15, 1571 (2005).

    CAS  Google Scholar 

  98. L. Torsi, A. Dodabalapur, Anal. Chem. 77, 380A (2005).

    CAS  Google Scholar 

  99. M. Bouvet, Anal. Bioanal. Chem. 384, 366 (2006).

    CAS  Google Scholar 

  100. J. Locklin, Z.N. Bao, Anal. Bioanal. Chem. 384, 336 (2006).

    CAS  Google Scholar 

  101. J.T. Mabeck, G.G. Malliaras, Anal. Bioanal. Chem. 384, 343 (2006).

    CAS  Google Scholar 

  102. L. Wang, D. Fine, D. Sharma, L. Torsi, A. Dodabalapur, Anal. Bioanal. Chem. 384, 310 (2006).

    CAS  Google Scholar 

  103. H.E. Katz, J. Huang, T. Someya, in Organic Electronics, H. Klauk, Ed. (Wiley, Weinheim, Germany, 2006).

    Google Scholar 

  104. G. Guillaud, J. Simon, J.P. Germain, Coord. Chem. Rev. 180, 1433 (1998).

    Google Scholar 

  105. E.S. Kolesar Jr., C.P. Brothers Jr., C.P. Howe, T.J. Jenkins, A.T. Moosey, J.E. Shin, J.M. Wiseman, Thin Solid Films 220, 30 (1992).

    CAS  Google Scholar 

  106. L. Torsi, A. Dodabalapur, N. Cioffi, L. Sabbatini, P.G. Zambonin, Sens. Actuators B 77, 7 (2001).

    CAS  Google Scholar 

  107. L. Torsi, M.C. Tanese, N. Cioffi, M.C. Gallazzi, L. Sabbatini, P.G. Zambonin, Sens. Actuators B 98, 204 (2004).

    CAS  Google Scholar 

  108. F. Liao, C. Chen, V. Subramanian, Sens. Actuators B 107, 849 (2005).

    CAS  Google Scholar 

  109. L. Wang, D. Fine, S.I. Khondaker, T. Jung, A. Dodabalapur, Sens. Actuators B 11 3, 539 (2006).

    Google Scholar 

  110. J. Huang, J. Miragliotta, A. Becknell, H.E. Katz, J. Am. Chem. Soc. 129, 9366 (2007).

    CAS  Google Scholar 

  111. J. Huang, J. Sun, H.E. Katz, Adv. Mater., published online June 3, 2008, http://dx.doi.org/10.1002/adma.200703212.

  112. R.D. Yang, T. Gredig, C.N. Colesniuc, J. Park, I.K. Schuller, W.C. Trogler, A.C. Kummel, Appl. Phys. Lett. 90, 263506 (2007).

    Google Scholar 

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Someya, T., Pal, B., Huang, J. et al. Organic Semiconductor Devices with Enhanced Field and Environmental Responses for Novel Applications. MRS Bulletin 33, 690–696 (2008). https://doi.org/10.1557/mrs2008.141

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