Abstract
The following article is an edited transcript based on the MRS Medalist presentation given by C. Jeffrey Brinker (Sandia National Laboratories and the University of New Mexico) on December 3, 2003, at the Materials Research Society Fall Meeting in Boston. Brinker received the Medal for “his pioneering application of principles of sol-gel chemistry to the self-assembly of functional nanoscale materials.” Nature combines hard and soft materials, often in hierarchical architectures, to obtain synergistic, optimized properties with proven, complex functionalities. Emulating natural designs in robust engineering materials using efficient processing approaches represents a fundamental challenge to materials chemists. This presentation reviews progress on understanding so-called evaporation-induced silica/surfactant self-assembly (EISA) as a simple, general means of preparing porous thin-film nanostructures. Such porous materials are of interest for membranes, low-dielectric-constant (low-k) insulators, and even ‘”nano-valves” that open and close in response to an external stimulus. EISA can also be used to simultaneously organize hydrophilic and hydrophobic precursors into hybrid nanocomposites that are optically or chemically polymerizable, patternable, or adjustable.
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References
G.M. Whitesides and B. Grzybowski, Science 295 (2002) p. 2418.
C. Kresge, M. Leonowicz, W. Roth, C. Vartuli, and J. Beck, Nature 359 (1992) p. 710.
C.J. Brinker and G.W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, San Diego, 1990).
Y. Lu, R. Ganguli, C. Drewien, M. Anderson, C. Brinker, W. Gong, Y. Guo, H. Soyez, B. Dunn, M. Huang, and J. Zink, Nature 389 (1997) p. 364.
H. Fan, Y. Lu, A. Stump, S. Reed, T. Baer, R. Schunk, V. Perez-Luna, G. Lopez, and C. Brinker, Nature 405 (2000) p. 56.
D. Doshi, N. Huesing, M. Lu, H. Fan, Y. Lu, K. Simmons-Potter, B. Potter, A. Hurd, and C. Brinker, Science 290 (2000) p. 107.
Y. Lu, H. Fan, A. Stump, T. Ward, T. Rieker, and C. Brinker, Nature 398 (1999) p. 223.
C. Brinker, Y. Lu, A. Sellinger, and H. Fan, Adv. Mater. 11 (1999) p. 579.
D. Doshi, A. Gibaud, V. Goletto, M. Lu, H. Gerung, B. Ocko, S. Han, C. Brinker, J. Am. Chem. Soc. 125 (2003) p. 11646.
D. Doshi, A. Gibaud, N. Liu, D. Sturmayr, A. Malanoski, D. Dunphy, H. Chen, S. Narayanan, A. MacPhee, J. Wang, S. Reed, A. Hurd, F. van Swol, and C. Brinker, J. Phys. Chem. B 107 (2003) p. 7683.
A. Gibaud, D. Grosso, B. Smarsly, A. Baptiste, J. Bardeau, F. Babonneau, D. Doshi, Z. Chen, C. Brinker, and C. Sanchez, J. Phys. Chem. B 107 (2003) p. 6114.
A. Sellinger, P. Weiss, A. Nguyen, Y. Lu, R. Assink, W. Gong, and C. Brinker, Nature 394 (1998) p. 256.
Y. Lu, Y. Yang, A. Sellinger, M. Lu, J. Huang, H. Fan, R. Haddad, G. Lopez, A. Burns, D. Sasaki, J. Shelnutt, and C. Brinker, Nature 410 (2001) p. 913.
Y. Yang, Y. Lu, M. Lu, J. Huang, R. Haddad, G. Xomeritakis, N. Liu, A. Malanoski, D. Sturmayr, H. Fan, D. Sasaki, R. Assink, J. Shelnutt, F. van Swol, G. Lopez, A. Burns, and C. Brinker, J. Am. Chem. Soc. 125 (2003) p. 1269.
J.N. Israelachvili, Intermolecular and Surface Forces (Academic Press, San Diego, 1992).
J.N. Israelachvili, D.J. Mitchell, and B.W. Ninham, J. Chem. Soc. 2 (1976) p. 1525.
H. Fan, K. Yang, D.M. Boye, T. Sigmon, K.J. Malloy, G.P. Lopez, C.J. Brinker, and H. Xu, Science 304 (2004) p. 567.
J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, and J.L. Schlenker, J. Am. Chem. Soc. 114 (1992) p. 10834.
C.B. Murray, C.R. Kagan, and M.G. Bawendi, Science 270 (1995) p. 1335.
S.H. Sun, C.B. Murray, D. Weller, L. Folks, and A. Moser, Science 287 (2000) p. 1989.
C.B. Murray, C.R. Kagan, and M.G. Bawendi, Science 270 (1995) p. 1335.
A.P. Alivisatos, K.P. Johnsson, X.G. Peng, T.E. Wilson, C.J. Loweth, M.P. Bruchez, and P.G. Schultz, Nature 382 (1996) p. 609.
C.A. Mirkin, R.L. Letsinger, R.C. Mucic, and J.J. Storhoff, Nature 382 (1996) p. 607.
H. Grabert and M.H. Devoret, Single Charge Tunneling (Plenum Publishers, New York, 1992).
A.A. Middleton and N.S. Winggreen, Phys. Rev. Lett. 71 (1993) p. 3198.
A.J. Rimberg, T.R. Ho, and J. Clarke, Phys. Rev. Lett. 74 (1995) p. 4714.
C.T. Black, C.B. Murray, R.L. Sandstrom, and S.H. Sun, Science 290 (2000) p. 1131.
D.J. Beebe, J.S. Moore, J.M. Bauer, Q. Yu, R.H. Liu, C. Devadoss, and B.-H. Jo, Nature 404 (2000) p. 588.
Q. Yu, J.M. Bauer, J.S. Moore, and D.J. Beebe, Appl. Phys. Lett. 78 (2001) p. 2589.
R.H. Liu, Q. Yu, and D.J. Beebe, J. Microelectromech. Syst. 11 (2002) p. 45.
G. Garnweitner, B. Smarsly, R. Assink, W. Ruland, E. Bond, and C.J. Brinker, J. Am. Chem. Soc. 125 (2003) p. 5626.
R. Yoshida, K. Uchida, Y. Kaneko, K. Sakai, A. Kikuchi, Y. Sakurai, and T. Okano, Nature 374 (1995) p. 240.
N. Liu, Z. Chen, D. Dunphy, Y. Jiang, R. Assink, and C. Brinker, Angew. Chem., Int. Ed. Engl. 42 (2003) p. 1731.
N. Liu, D.R. Dunphy, P. Atanassov, S.D. Bunge, Z. Chen, G.P. Lopez, T.J. Boyle, C.J. Brinker, Nanolett. 4 (2004) p. 551.
N. Liu, D.R. Dunphy, M.A. Rodriguez, S. Singer, C.J. Brinker, Chem. Commun., (2003) p. 1144.
N.K. Mal, M. Fujiwara, and Y. Tanaka, Nature 421 (2003) p. 350.
H. Rau, in Photochemistry and Photophysics, Vol. II, edited by J. Rabek (CRC Press, Boca Raton, FL, 1990).
A. Natansohn, in Macromolecular Symposia, edited by H. Höcker, W. Guth, B. Jung, I. Meisel, and S. Spiegel (WILEY-VCH, Weinheim, Germany, 1999) p. 1.
K. Kataoka, H. Miyazaki, M. Bunya, T. Okano, and Y. Sakurai, J. Am. Chem. Soc. 120 (1998) p. 12694.
E. Kokufuta, Y.Q. Zhang, and T. Tanaka, Nature 351 (1991) p. 302.
T. Miyata, N. Asami, and T. Uragami, Nature 399 (1999) p. 766.
T. Tanaka, I. Nishio, S.T. Sun, and S. Uenonishio, Science 218 (1982) p. 467.
I.C. Kwon, Y.H. Bae, and S.W. Kim, Nature 354 (1991) p. 291.
G.S. Kumar and D.C. Neckers, Chem. Rev. 89 (1989) p. 1915.
M. Ueda, H.-B. Kim, T. Ikeda, and K. Ichimura, Chem. Mater. 4 (1992) p. 1229.
L.M. Siewierski, W.J. Brittain, S. Petrash, and M.D. Foster, Langmuir 12 (1996) p. 5838.
M. Ogawa, K. Kurodacd, and J.-I. Moric, Chem. Commun. (24) (2000) p. 2441.
J.G. Victor and J.M. Torkelson, Macromolecules 20 (1987) p. 2241.
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Brinker, C.J. Evaporation-Induced Self-Assembly: Functional Nanostructures Made Easy. MRS Bulletin 29, 631–640 (2004). https://doi.org/10.1557/mrs2004.183
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DOI: https://doi.org/10.1557/mrs2004.183