Abstract
Oxide-based ceramic materials are rapidly proving to have exciting potential for application as hard coatings. The most commonly known oxide material is silica, with a well-known variety of polytypes. Many other oxides, especially those involving metals, are now also proving to be important for a variety of applications where, because of the chemical role played by metal delectrons, large oxygen coordinations can be sustained. Properties of a variety of oxides—from silica to metal-based oxides—are discussed, and the role of predictive computer modeling is shown to be valuable in guiding the search for potentially new superhard oxides.
Similar content being viewed by others
References
A. Badzian, Mater. Chem. Phys. 72 (2001) p. 110.
J. Haines, J.M. Leger, and G. Bocquillon, Annu. Rev. Mater. Res. 31 (2001) p. 1.
B. Affatato, M. Goldoni, M. Testoni, and A. Toni, Biomaterials 22 (2001) p. 717.
D.M. Teter, MRS Bull. 23 (1) (1998) p. 22.
V.V. Murashov and I.M. Svishchev, Phys. Rev. B 57 (1998) p. 5639.
R.W.G. Wyckoff, Crystal Structures (John Wiley & Sons, New York, 1963).
N.R. Keskar and J.R. Chelikowsky, Phys. Rev. B 46 (1992) p. 1.
P.J. Heaney, G.V. Gibb, and C.T. Prewitt, eds., Silica-Physical Behavior: Geochemistry and Materials Applications, Vol. 29, Reviews of Mineralogy (Mineralogical Society of America, Washington, DC, 1994).
J.E. Fleming and H. Lynton, Phys. Chem. Glasses 1 (1960) p. 148.
Y. Tsuchida and T. Yagi, Nature 340 (1989) p. 217.
L.G. Liu, W.A. Bassett, and J. Sharry, J. Geophys. Res. 78 (1978) p. 2301.
N.A. Dubrovinskaia and L.S. Dubrovinsky, Mater. Chem. Phys. 68 (2001) p. 77.
S. Ono, K. Hirose, N. Nishiyama, and M. Isshiki, Am. Mineral. 87 (2002) p. 99.
V.P. Dmitriev, P. Tolédano, and E.K.H. Salje, Phys. Rev. B 58 (1998) p. 11911.
J.S. Tse, D.D. Klug, and M. Bernasconi, Phys. Rev. B 56 (1997) p. 10878.
R.M. Wentzcovitch, C. Da Silva, and J.R. Chelikowsky, Phys. Rev. Lett. 80 (1998) p. 2149.
M. Tjabane and J.E. Lowther, Physica B 270 (1999) p. 164.
R.J. Hemley, C.T. Prewitt, and K.J. Klima, Physical Behavior, Geochemistry and Material Applications (Mineralogical Society of America, Washington, DC, 1994).
R.J. Hemley, A.P. Jepheoat, H.K. Mao, L.C. Ming, and M.H. Manghnani, Nature 334 (1988) p. 52.
N. Binggeli and J.R. Chelikowsy, Phys. Rev. Lett. 69 (1992) p. 2220.
D.M. Teter, R.J. Hemley, G. Kresse, and J. Hafner, Phys. Rev. Lett. 80 (1998) p. 2145.
K. Liddell and D.P. Thompson, “The Future of Multicomponent SiAlON Ceramics,” presented at the International Symposium on Sialons, Chuba, Japan, 2001.
J. Haines, J.M. Leger, and B. Blanzat, J. Mater. Sci. Lett. 44 (1994) p. 1688.
J.K. Dewhurst and J.E. Lowther, Phys. Rev. B 54 (1997) p. R1234.
T. Arlt, M. Bermejo, M.A. Blanco, L. Gerward, J.Z. Jiang, J. Stan Olsen, and J.M. Recio, Phys. Rev. B 61 (2000) p. 14414.
J.T. Olsen, L. Gerward, and J. Jiang, High Pressure Res. 22 (2002) p. 385.
J.K. Dewhurst and J.E. Lowther, Phys. Rev. B 64 14104 (2001)
L.S. Dubrovinsky, N.A. Dubrovinskaia, V. Swamy, J. Muscat, N.M. Harrison, R. Ahuja, B. Holm, and B. Johansson, Nature 410 (2001) p. 653.
J. Haines and J.M. Leger, Physica B 192 (1993) p. 233.
H. Sato, S. Endo, M. Sugiyama, T. Kikegawa, O. Shimomura, and K. Kusaba, Science 251 (1991) p. 786.
Z. Wang, S.K. Saxena, V. Pischedda, H.P. Liermann, and C.S. Zha, J. Phys.: Condens. Matter 13 (2001) p. 8317.
J. Haines, J.M. Leger, and O. Schulte, J. Phys.: Condens. Matter 8 (1996) p. 1631.
K. Lagarec and S. Desgreniers, Solid State Commun. 94 (1995) p. 519.
K.M. Glassford and J.R. Chelikowsky, Phys. Rev. B 46 (1992) p. 1284.
M. Calatayud, P. Mori-Sánchez, A. Beltrán, A.M. Pendás, E. Francisco, J. Andrés, and J.M. Recio, Phys. Rev. B 64 184113 (2001)
J. Haines and J.M. Leger, Phys. Rev. B 48 (1993) p. 13344.
U. Lundin, L. Fast, L. Nordström, and B.R. Johansson, Phys. Rev. B 57 (9) (1998) p. 4979.
J.K. Dewhurst and J.E. Lowther (unpublished).
J.S. Tse, D.D. Klug, K. Uehara, Z.Q. Li, J. Haines, and J.M. Leger, Phys. Rev. B 61 (2000) p. 10029.
J. Haines, J.M. Leger, and O. Schulte, Science 271 (1996) p. 629.
J.M. Haines, J.M. Leger, S. Hull, A.S. Pereira, C.A. Perottoni, and J.A.H. da Jornada, J. Am. Ceram. Soc. 80 (1997) p. 1910.
N. Beatham and A.F. Orchard, J. Electron Spectrosc. Relat. Phenom. 16 (1979) p. 77.
L.C. Ming and M.H. Manghnani, in Proc. 2nd U.S.–Japan Seminar on High-Pressure Research: Applications in Geophysics, edited by S. Akimoto and M.H. Manghnani (Center Academic Publications, Tokyo, 1982) p. 329.
J. Haines, J.M. Leger, M.W. Schmidt, J.P. Petitet, A.S. Pereira, J.A.H. da Jornada, and S. Hull, J. Phys. Chem. Solids 59 (1998) p. 239.
J.M. Leger, P. Djemia, F. Ganot, J. Haines, A.S. Pereira, and J.A.H. da Jornada, Appl. Phys. Lett. 79 (14) (2001) p. 2169.
J.D. McCullough and K.N. Trueblood, Acta Crystallogr. 12 (1959) p. 507.
P. Aldebert and J.P. Traverse, J. Am. Ceram. Soc. 68 (1985) p. 34.
D.K. Smith and C.F. Cline, J. Am. Ceram. Soc. 45 (1962) p. 249.
B. Starbova, V. Mankov, N. Starbov, D. Popov, D. Nihtianova, K. Kolev, and L.D. Laude, Appl. Surf. Sci. 173 (2001) p. 177.
B. Aarik, A. Aidla, H. Mandar, T. Uustare, K. Kukli, and M. Schuisky, Appl. Surf. Sci. 173 (2001) p. 15.
J.K. Dewhurst and J.E. Lowther, Phys. Rev. B 57 (1998) p. 741.
S. Desgreniers and K. Lagarec, Phys. Rev. B 59 (1999) p. 8467.
J.E. Lowther, J.K. Dewhurst, J.M. Leger, and J. Haines, Phys. Rev. B 60 (1999) p. 14485.
O. Ohtaka, H. Fukui, T. Kunisada, T. Fujisawa, K. Funakoshi, W. Utsumi, T. Irifune, K. Kuroda, and T. Kikegawa, Phys. Rev. B 63 174108 (2001)
R.P. Ingel and D. Lewis, J. Am. Ceram. Soc. 71 (1988) p. 265.
O. Ohtaka, H. Fukui, T. Kunisada, T. Fujisawa, K. Funakoshi, T. Irifune, K. Kuroda, and T. Kikegawa, J. Am. Ceram. Soc. 84 (2001) p. 1369.
R.E. Cohen, M.J. Mehl, and L.L. Boyer, Physica B 150 (1988) p. 1.
E.H. Kisi, C.J. Howard, and R.J. Hill, J. Am. Ceram. Soc. 72 (1989) p. 1757.
O. Ohtaka, T. Yamanaka, S. Kume, N. Hara, H. Asano, and F. Izumi, in Proc. Japan Acad. 66 Ser. B (1990) p. 193.
J.M. Leger and R. Blanzat, J. Mater. Sci. 44 (1993) p. 1688.
R. Guinebretiere, Z. Oudjedi, and A. Dauger, Scripta. Metall. Mater. 34 (1996) p. 1039.
Y. Kudoh, H. Takeda, and H. Arashi, Phys. Chem. Miner. 13 (1986) p. 233.
A.H. Heuer, V. Lanteri, S.C. Farmer, R. Chaim, R.R. Lee, B.W. Kibbel, and R.M. Dickerson, J. Mater. Sci. 24 (1989) p. 124.
C.J. Howard, E.H. Kisi, and O. Ohtaka, J. Am. Ceram. Soc. 74 (1991) p. 2321.
L.G. Liu, Earth Planet. Sci. Lett. 44 (1979) p. 390.
S. Block, J.A.H. da Jornada, and G.J. Piermarini, J. Am. Ceram. Soc. 78 (1995) p. 497.
L.-G. Liu, J. Phys. Chem. Solids 41 (1980) p. 331.
J. Haines, J.M. Leger, and A. Atouf, J. Am. Ceram. Soc. 78 (1995) p. 445.
L.C. Ming and M.H. Manghnani, in Solid State Physics under Pressure, edited by S. Minomura (KTK Science, Tokyo, 1985) p. 135.
H. Arashi, T. Yagi, S. Akimoto, and Y. Kudoh, Phys. Rev. B 41 (1990) p. 4309.
O. Ohtaka, S. Kume, and E. Ito, J. Am. Ceram. Soc. 71 (1988) p. C448.
S.R.U. Dev, L.C. Ming, and M.H. Manghnani, J. Am. Ceram. Soc. 70 (1987) p. C218.
E.V. Stefanovich, A.L. Shluger, and C.R.A. Catlow, Phys. Rev. B 49 (1994) p. 11560.
G. Stapper, M. Bernasconi, N. Nicoloso, and M. Parrinello, Phys. Rev. B 59 (1999) p. 797.
A. Bogicevic, C. Wolverton, G.M. Crosbie, and E.B. Stechel, Phys. Rev. B 64 104106 (2001)
Rights and permissions
About this article
Cite this article
Lowther, J.E. Superhard Ceramic Oxides. MRS Bulletin 28, 189–193 (2003). https://doi.org/10.1557/mrs2003.61
Published:
Issue Date:
DOI: https://doi.org/10.1557/mrs2003.61