Abstract
Among the experimental techniques used to characterize complex fluids, neutron scattering has played a unique and successful role, primarily for two reasons: (1) neutrons access the proper length and time scales, especially small-angle neutron scattering and reflectometry for structural and kinetic studies and neutron spin echo for dynamic investigations; and (2) for hydrogen-containing substances, the exchange of hydrogen by deuterium facilitates labeling on a molecular scale, an extremely important method for deciphering complex structures in multicomponent materials. In this short review, we give a number of examples for successful neutron studies of dense particle suspensions, including aggregation phenomena, in situ kinetic studies on shape transformations, shear-induced surfactant self-assembly phenomena near surfaces, and dynamics of complex fluids. Finally, we give an outlook on future developments.
Similar content being viewed by others
References
D.F. Evans and H. Wennerström, The Colloidal Domain: Where Physics, Chemistry, Biology and Technology Meet (VCH Publishers, New York, 1994).
P. Lindner and Th. Zemb, eds., Neutron, X-Rays and Light Scattering Methods Applied to Soft Condensed Matter (Elsevier Science, New York, 2002).
D. Frenkel, Science 296 (2002) p. 65.
D. Frenkel, Physica A 313 (2002) p. 1.
V. Castellotto, I.W. Hamley, and J.S. Pedersen, J. Chem. Phys. 117 (2002) p. 8124.
K. Suamru, H. Matsuoka, H. Yamaoka, and G.D. Wignall, Phys. Rev. E 53 (1996) p. 1744.
W. Groenewegen, A. Lapp, S.U. Egelhaaf, and J.R.C. van der Maarel, Macromolecules 33 (2000) p. 4080.
F. Muller, P. Fontaine, M. Delsanti, L. Belloni, J. Yang, Y.J. Chen, J.W. Mays, P. Lesieur, M. Tirrell, and P. Guenoun, Eur. Phys. J. E 6 (2001) p. 109
M. Roger, P. Guenoun, F. Muller, L. Belloni, and M. Delsanti, Eur. Phys. J. E 9 (2002) p. 313.
L.F. Rojas-Ochoa, S. Romer, F. Scheffold, and P. Schurtenberger, Phys. Rev. E 65051403 (2002).
C.N. Likos, M. Schmidt, H. Löwen, M. Ballauff, D. Pötschke, and P. Lindner, Macromolecules 34 (2001) p. 34.
J. Stellbrink, J. Allgaier, D. Richter, A. Moussaid, A.B. Schofield, W.C.K Poon, P.N. Pusey, P. Lindner, J. Dzubiella, C.N. Likos, and H. Löwen, Appl. Phys. A Mater. Sci. Proc. 74 (2002) (Suppl. 1) p. S355.
J. Stellbrink, J. Allgaier, and D. Richter, Phys. Rev. E 56 (1997) p. R3772.
J. Dzubiella, A. Jusufi, C.N. Likos, C. von Ferber, H. Löwen, J. Stellbrink, J. Allgaier, D. Richter, A.B. Schofield, P.A. Smith, W.C.K Poon, and P.N. Pusey, Phys. Rev. E 64010401 (2001).
T. Eckert and E. Bartsch, Phys. Rev. Lett. 89125701 (2002).
K. Dawson, Curr. Opin. Colloid Interface Sci. 7 (2002) p. 218.
K.N. Pham, A.M. Puertas, J. Bergenholtz, S.U. Egelhaaf, A. Moussaid, P.N. Pusey, A.B. Schofield, M.E. Cates, M. Fuchs, and W.C.K Poon, Science 296 (2002) p. 104.
W.R. Chen, S.H. Chen, and F. Mallamace, Phys. Rev. E 66021403 (2002).
S.H. Chen, F. Mallamace, A. Faraone, P. Gambadauro, D. Lombardo, and W.R. Chen, Eur. Phys. J. E 9 (2002) p. 283.
A.M. Kulkarni, N.M. Dixit, and C.F. Zukoski, Faraday Discuss. 123 (2003) p. 37.
C.J. Brinker and G.W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, San Diego, 1990).
C.M. Sorensen, Aerosol Sci. Technol. 35 (2001) p. 648.
S. Romer, C. Urban, V. Lobaskin, F. Scheffold, A. Stradner, J. Kohlbrecher, and P. Schurtenberger, J. Appl. Crystallogr. 36 (2003) p. 1.
P. Schurtenberger, H. Bissig, L. Rojas, R. Vavrin, A. Stradner, S. Romer, F. Scheffold, and V. Trappe, in Mesoscale Phenomena in Fluid Systems, edited by F. Case and P. Alexandridis, ACS Symposium Series 861 (American Chemical Society, Washington, DC, 2003) p. 143.
D.A. Weitz, J.X. Zhu, D.J. Durian, and D.J. Pine, in Structure and Dynamics of Strongly Interacting Colloids and Supramolecular Aggregates in Solution, edited by S.-H. Chen, J.S. Huang, and P. Tartaglia (Kluwer Academic Publishers, Dordrecht, 1992) p. 731.
S.U. Egelhaaf and P. Schurtenberger, Phys. Rev. Lett. 82 (1999) p. 2804.
S.U. Egelhaaf, J. Leng, A. Salonen, P. Schurtenberger, and M. Cates, in Proc. of Self Assembly: the Future, edited by B. Robinson, J. Eastoe, and A. Hatton (CRC Press, Boca Raton, FL, 2003) in press.
P. Butler, Curr. Opin. Colloid Interface Sci. 4 (1999) p. 214.
O. Diat, D. Roux, and F. Nallet, J. Phys. II 3 (1993) p. 1427.
P.D. Butler, L.J. Magid, W.A. Hamilton, J.B. Hayter, B. Hammouda, and P.J. Kreke, J. Phys. Chem. 100 (1996) p. 442.
L. Porcar, W.A. Hamilton, P.D. Butler, and G.G. Warr, Phys. Rev. Lett. 89168301 (2002).
W.A. Hamilton, P.D. Butler, S.M. Baker, G.S. Smith, J.B. Hayter, L.J. Magid, and R. Pynn, Phys. Rev. Lett. 72 (1994) p. 2219.
W.A. Hamilton, P.D. Butler, L.J. Magid, Z. Han, and T.M. Slawecki, Phys. Rev. E 60 (1999) p. R1146.
J.S. Higgins and H.C. Benoit, Polymers and Neutron Scattering, Chapter 3, Oxford Series on Neutron Scattering in Condensed Matter, No. 8 (Clarendon Press, Oxford, 1994).
C.L. Soles, J.F. Douglas, W.-I. Wu, and R.M. Dimeo, Phys. Rev. Lett. 88037401 (2002).
G.M. Mao, M.-L. Saboungi, D.L. Price, M.B. Armand, and W.S. Howells, Phys. Rev. Lett. 84 (2000) p. 5536.
G.M. Mao, M.-L. Saboungi, D.L. Price, M. Armand, F. Mezei, and S. Pouget, Macromole-cules 35 (2002) p. 415.
G. Mao, R.F. Perea, W.S. Howells, D.L. Price, and M.-L. Saboungi, Nature 405 (2000) p. 163.
C. Karlsson, A.S. Best, J. Swenson, W.S. Howells, and L. Børjesson, J. Chem. Phys. 118 (2003) p. 4206.
T. Hellweg, K. Kratz, S. Pouget, and W. Eimer, Colloids Surf., A Physicochem. Eng. Aspects202 (2002) p. 223.
A.G. Zilman and R. Granek, Phys. Rev. Lett. 77 (1996) p. 4788.
B.-S. Yang, J. Lal, M. Mihailescu, M. Monkenbusch, D. Richter, J.S. Huang, J. Kohn, W.B. Russel, and R.K. Prud’homme, Langmuir 18 (2002) p. 6.
M. Mihailescu, M. Monkenbusch, H. Endo, J. Allgaier, G. Gompper, J. Stellbrink, D. Richter, B. Jakobs, T. Sottmann, and B. Farago, J. Chem. Phys. 115 (2001) p. 9563.
H. Seto, T. Kato, M. Monkenbusch, T. Takeda, Y. Kawabata, M. Nagao, D. Okuhara, M. Imai, and S. Komura, J. Phys. Chem. Solids 60 (1999) p. 1371.
L. Magid, B. Veith, P. Butler, N. Rosov, and D. Bossev (unpublished).
A. Wischnewski, M. Monkenbusch, L. Willner, D. Richter, and G. Kali, Phys. Rev. Lett. 90 058302 (2003).
Rights and permissions
About this article
Cite this article
Magid, L.J., Schurtenberger, P. Characterizing Complex Fluids. MRS Bulletin 28, 907–912 (2003). https://doi.org/10.1557/mrs2003.253
Published:
Issue Date:
DOI: https://doi.org/10.1557/mrs2003.253