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Hole-conductor-free perovskite solar cells

  • Halide Perovskite Opto- and Nanoelectronic Materials and Devices
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Abstract

Metal-halide perovskite solar cells (PSCs) have become a promising candidate for photovoltaic applications. Current popular organic hole conductors for highly efficient PSCs bring cost and stability issues, which hinder the commercialization of the PSCs. Hole-conductor-free PSCs are attracting great interest because they eliminate the adverse effects of organic hole conductors by transporting holes in the perovskite itself. In this article, we summarize recent progress in conventional, inverted, and printable mesoscopic hole-conductor-free PSCs. Specifically, we emphasize the stunning stability and scale-up manufacturing of printable hole-conductor-free PSCs, discussing their potential from laboratory to market. The causes for hole-conductor-free PSCs’ current low efficiency are also discussed, and are primarily ascribed to energy-level alignment and interface recombination. We believe that the efficiencies of hole-conductor-free PSCs can be enhanced to be comparable with hole-conductor-containing PSCs by interface modification and material design.

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Acknowledgments

The authors acknowledge financial support from the National Natural Science Foundation of China (Grant Nos. 21702069, 91733301, and 51902117), the Fundamental Research Funds for the Central Universities, the Science and Technology Department of Hubei Province (No. 2017AAA190), the 111 Project (No. B07038), the Program for HUST Academic Frontier Youth Team (2016QYTD06), and the Fundamental Research Funds for the Central Universities (No. 2019kfyXJJS051).

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Authors and Affiliations

  1. Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, China

    Deyi Zhang, Yaoguang Rong, Yue Hu, Anyi Mei & Hongwei Han

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  1. Deyi Zhang
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  2. Yaoguang Rong
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  3. Yue Hu
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  5. Hongwei Han
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Zhang, D., Rong, Y., Hu, Y. et al. Hole-conductor-free perovskite solar cells. MRS Bulletin 45, 449–457 (2020). https://doi.org/10.1557/mrs.2020.144

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  • DOI: https://doi.org/10.1557/mrs.2020.144

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