Abstract
High pressures have a significant impact on the structure-related properties of glass and are encountered in scenarios ranging from fracture mechanics, where stresses in the gigapascal regime are easily generated by sharp-contact loading, to the manufacture of permanently densified materials with tuned physical characteristics. Here, we consider pressure-induced structural changes that occur in glass and show that, for oxide materials, the oxygen-packing fraction plays a key role in determining when these changes are likely to occur. Fivefold coordinated Si atoms appear as important intermediaries in the pressure-induced deformation of silica glass.
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Salmon, P.S., Huang, L. Impact of pressure on the structure of glass and its material properties. MRS Bulletin 42, 734–737 (2017). https://doi.org/10.1557/mrs.2017.210
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DOI: https://doi.org/10.1557/mrs.2017.210