Abstract
Condensation is a phase change phenomenon often encountered in nature, as well as used in industry for applications including power generation, thermal management, desalination, and environmental control. For the past eight decades, researchers have focused on creating surfaces allowing condensed droplets to be easily removed by gravity for enhanced heat transfer performance. Recent advancements in nanofabrication have enabled increased control of surface structuring for the development of superhydrophobic surfaces with even higher droplet mobility and, in some cases, coalescence-induced droplet jumping. Here, we provide a review of new insights gained to tailor superhydrophobic surfaces for enhanced condensation heat transfer considering the role of surface structure, nucleation density, droplet morphology, and droplet dynamics. Furthermore, we identify challenges and new opportunities to advance these surfaces for broad implementation in thermofluidic systems.
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References
A.R. Parker, C.R. Lawrence, Nature 414, 33 (2001).
Y.M. Zheng, H. Bai, Z.B. Huang, X.L. Tian, F.Q. Nie, Y. Zhao, J. Zhai, L. Jiang, Nature 463, 640 (2010).
B. Bhushan, Philos. Trans. R. Soc. London, Ser. A 367, 1445 (2009).
Y.T. Cheng, D.E. Rodak, Appl. Phys. Lett. 86 (2005).
B. Mockenhaupt, H.J. Ensikat, M. Spaeth, W. Barthlott, Langmuir 24, 13591 (2008).
J.M. Beer, Prog. Energy Combust. Sci. 33, 107 (2007).
T.B. Peters, M. McCarthy, J. Allison, F.A. Dominguez-Espinosa, D. Jenicek, H.A. Kariya, W.L. Staats, J.G. Brisson, J.H. Lang, E.N. Wang, IEEE Trans. Compon. Packag. Manuf. Technol. 2, 1637 (2012).
A.D. Khawaji, I.K. Kutubkhanah, J.M. Wie, Desalination 221, 47 (2008).
T. Humplik, J. Lee, S.C. O’Hern, B.A. Fellman, M.A. Baig, S.F. Hassan, M.A. Atieh, F. Rahman, T. Laoui, R. Karnik, E.N. Wang, Nanotechnology 22, 292001 (2011).
L. Perez-Lombard, J. Ortiz, C. Pout, Energy Build 40, 394 (2008).
B.Z. Li, R.M. Yao, Renewable Energy 34, 1994 (2009).
B. von Elsner, D. Briassoulis, D. Waaijenberg, A. Mistriotis, C. von Zabeltitz, J. Gratraud, G. Russo, R. Suay-Cortes, J. Agric. Eng. Res. 75, 1 (2000).
D. Kaschiev, Nucleation: Basic Theory With Applications (Butterworth-Heinemann, Oxford, 2000).
W.Z. Nusselt, Z. Ver. Dtsch. Ing. 60, 541 (1916).
P.J. Marto, D.J. Looney, J.W. Rose, A.S. Wanniarachchi, Int. J. Heat Mass Trans. 29, 1109 (1986).
R.W.I. Bonner, in Proceedings of the International Heat Transfer Conference (ASME, Washington, DC, 2010).
S. Vemuri, K.J. Kim, B.D. Wood, S. Govindaraju, T.W. Bell, Appl. Therm. Eng. 26, 421 (2006).
S. Vemuri, K.J. Kim, Int. J. Heat Mass Trans. 49, 649 (2006).
A.K. Das, H.P. Kilty, P.J. Marto, G.B. Andeen, A. Kumar, J. Heat Trans. 122, 278 (2000).
R.A. Erb, E. Thelen, Ind. Eng. Chem. 57, 49 (1965).
D.G. Wilkins, L.A. Bromley, S.M. Read, AlChE J. 19, 119 (1973).
D.W. Woodruff, J.W. Westwater, Int. J. Heat Mass Trans. 22, 629 (1979).
D. Beysens, C.R. Phys. 7, 1082 (2006).
D. Beysens, A. Steyer, P. Guenoun, D. Fritter, C.M. Knobler, Phase Transitions 31, 219 (1991).
D. Fritter, C.M. Knobler, D.A. Beysens, Phys. Rev. A 43, 2858 (1991).
E. Schmidt, W. Schurig, W. Sellschopp, Forsch. Ingenieurwes. 1, 53 (1930).
H.Y. Kim, H.J. Lee, B.H. Kang, J. Colloid Interface Sci. 247, 372 (2002).
P. Dimitrakopoulos, J.J.L. Higdon, J. Fluid Mech. 395, 181 (1999).
J.B. Boreyko, C.H. Chen, Phys. Rev. Lett. 103, 184501 (2009).
J.W. Rose, Proc. Inst. Mech. Eng., Part A: J. Power Eng. 216, 115 (2002).
B.S. Sikarwar, S. Khandekar, S. Agrawal, S. Kumar, K. Muralidhar, Heat Trans. Eng. 33, 301 (2012).
A. Lafuma, D. Quéré, Nat. Mater. 2, 457 (2003).
N.A. Patankar, Soft Matter 6, 1613 (2010).
L. Bocquet, E. Lauga, Nat. Mater. 10, 334 (2011).
S.H. Kang, N. Wu, A. Grinthal, J. Aizenberg, Phys. Rev. Lett. 107, 177802 (2011).
T. Young, Philos. Trans. R. Soc. London 95, 65 (1805).
R.N. Wenzel, Ind. Eng. Chem. 28, 988 (1936).
A.B.D. Cassie, S. Baxter, Trans. Faraday Soc. 40, 546 (1944).
L.C. Gao, A.Y. Fadeev, T.J. McCarthy, MRS Bull. 33, 747 (2008).
D. Quéré, Annu. Rev. Mater. Res. 38, 71 (2008).
C. Dorrer, J. Ruhe, Soft Matter 5, 51 (2009).
P. Roach, N.J. Shirtcliffe, M.I. Newton, Soft Matter 4, 224 (2008).
S. Moulinet, D. Bartolo, Eur. Phys. J. E 24, 251 (2007).
R.D. Narhe, D.A. Beysens, Europhys. Lett. 75, 98 (2006).
R.D. Narhe, D.A. Beysens, Phys. Rev. Lett. 93, 076103 (2004).
R.D. Narhe, D.A. Beysens, Langmuir 23, 6486 (2007).
N. Miljkovic, R. Enright, Y. Nam, K. Lopez, N. Dou, J. Sack, E.N. Wang, Nano Lett. 13, 179 (2013).
C. Dorrer, J. Ruhe, Langmuir 23, 3820 (2007).
K.A. Wier, T.J. McCarthy, Langmuir 22, 2433 (2006).
C.H. Chen, Q.J. Cai, C.L. Tsai, C.L. Chen, G.Y. Xiong, Y. Yu, Z. Ren, Appl. Phys. Lett. 90, 173108 (2007).
C. Dorrer, J. Ruhe, Adv. Mater. 20, 159 (2008).
X. Chen, J. Wu, R. Ma, M. Hua, N. Koratkar, S. Yao, Z. Wang, Adv. Funct. Mater. 21, 4617 (2011).
K.K.S. Lau, J. Bico, K.B.K. Teo, M. Chhowalla, G.A.J. Amaratunga, W.I. Milne, G.H. McKinley, K.K. Gleason, Nano Lett. 3, 1701 (2003).
K. Rykaczewski, W.A. Osborn, J. Chinn, M.L. Walker, J.H.J. Scott, W. Jones, C. Hao, S. Yaod, Z. Wang, Soft Matter 8, 8786 (2012).
R. Enright, N. Miljkovic, A. Al-Obeidi, C.V. Thompson, E.N. Wang, Langmuir 40, 14424 (2012).
D.M. Anderson, M.K. Gupta, A.A. Voevodin, C.N. Hunter, S.A. Putnam, V.V. Tsukruk, A.G. Fedorov, ACS Nano 6, 3262 (2012).
K.K. Varanasi, T. Deng, in 12th IEEE Intersociety Conference on Thermal and Thermomechanical Phenomena in Electronic Systems 1 – 5 (Los Vegas, NV, 2010).
K.K. Varanasi, M. Hsu, N. Bhate, W.S. Yang, T. Deng, Appl. Phys. Lett. 95, 094101 (2009).
E.K. Her, T.J. Ko, K.R. Lee, K.H. Oh, M.W. Moon, Nanoscale 4, 2900 (2012).
S.M. Ji, I.Y. Kim, E.H. Kim, J.U. Jung, W.D. Kim, H.E. Lim, J. Korean Soc. Precis. Eng. 29, 19 (2012).
A. Lee, M.W. Moon, H. Lim, W.D. Kim, H.Y. Kim, Langmuir 28, 10183 (2012).
S.C. Thickett, C. Neto, A.T. Harris, Adv. Mater. 23, 3718 (2011).
C.W. Yao, T.P. Garvin, J.L. Alvarado, A.M. Jacobi, B.G. Jones, C.P. Marsh, Appl. Phys. Lett. 101, 111605 (2012).
J.C. Love, L.A. Estroff, J.K. Kriebel, R.G. Nuzzo, G.M. Whitesides, Chem. Rev. 105, 1103 (2005).
G.P. Lopez, H.A. Biebuyck, C.D. Frisbie, G.M. Whitesides, Science 260, 647 (1993).
D. Mandler, I. Turyan, Electroanalysis 8, 207 (1996).
N. Miljkovic, R. Enright, E.N. Wang, ACS Nano 6, 1776 (2012).
K. Rykaczewski, Langmuir 28, 7720 (2012).
S. Kim, K.J. Kim, J. Heat Transfer 133, 081502 (2011).
M. AbuOrabi, Int. J. Heat Mass Trans. 41, 81 (1998).
S. Anand, S.Y. Son, Langmuir 26, 17100 (2010).
L. Cao, A.K. Jones, V.K. Sikka, J.Z. Wu, D. Gao, Langmuir 25, 12444 (2009).
J.W. Rose, L.R. Glicksman, Int. J. Heat Mass Trans. 16, 411 (1973).
R.D. Narhe, M.D. Khandkar, P.B. Shelke, A.V. Limaye, D.A. Beysens, Phys. Rev. E 80, 031604 (2009).
C. Dietz, K. Rykaczewski, A.G. Fedorov, Y. Joshi, Appl. Phys. Lett. 97, 033104 (2010).
N. Miljkovic, R. Enright, E.N. Wang, presented at the 3rd Micro/Nanoscale Heat & Mass Transfer International Conference (Atlanta, GA, 2012).
M. Nosonovsky, B. Bhushan, Ultramicroscopy 107, 969 (2007).
M. McCarthy, K. Gerasopoulos, R. Enright, J.N. Culver, R. Ghodssi, E.N. Wang, Appl. Phys. Lett. 100, 1 (2012).
B. Bhushan, M. Nosonovsky, Nano Lett. 7, 2633 (2007).
B. Bhushan, Y.C. Jung, ACS Nano 3, 4155 (2009).
B. Pokroy, S.H. Kang, L. Mahadevan, J. Aizenberg, Science 323, 237 (2009).
T.Q. Liu, W. Sun, X.Y. Sun, H.R. Ai, Langmuir 26, 14835 (2010).
T.Q. Liu, W. Sun, X.Y. Sun, H.R. Ai, Colloids Surf., A 414, 366 (2012).
N. Miljkovic, R. Enright, E.N. Wang, J. Heat Transfer (2012), in press.
J. Feng, Y. Pang, Z. Qin, R. Ma, S. Yao, ACS Appl. Mater. Interfaces 4, 6618 (2012).
R. Enright, N. Dou, N. Miljkovic, Y. Nam, E.N. Wang, presented at the 3rd Micro/Nanoscale Heat & Mass Transfer International Conference (Atlanta, GA, 2012).
C. Dietz, K. Rykaczewski, A. Fedorov, Y. Joshi, J. Heat Transfer 132, 080904 (2010).
J.B. Boreyko, P.C. Collier, ACS Nano 7, 1618 (2013)
K. Rykaczewski, J.H.J. Scott, S. Rajauria, J. Chinn, A.M. Chinn, W. Jones, Soft Matter 7, 8749 (2011).
K. Rykaczewski, A.T. Paxson, S. Anand, X. Chen, Z. Wang, K.K. Varanasi, Langmuir 29, 881 (2013).
K. Rykaczewski, J. Chinn, M.L. Walker, J.H.J. Scott, A. Chinn, W. Jones, ACS Nano 5, 9746 (2011).
R.D. Narhe, W. Gonzalez-Vinas, D.A. Beysens, Appl. Surf. Sci. 256, 4930 (2010).
D. Torresin, M.K. Tiwari, D. Del Col, D. Poulikakos, Langmuir 29, 840 (2013).
J. Feng, Z.Q. Qin, S.H. Yao, Langmuir 28, 6067 (2012).
X.T. Zhang, M. Jin, Z.Y. Liu, S. Nishimoto, H. Saito, T. Murakami, A. Fujishima, Langmuir 22, 9477 (2006).
X.T. Zhang, M. Jin, Z.Y. Liu, D.A. Tryk, S. Nishimoto, T. Murakami, A. Fujishima, J. Phys. Chem. C 111, 14521 (2007).
M. He, X. Zhou, X.P. Zeng, D.P. Cui, Q.L. Zhang, J. Chen, H.L. Li, J.J. Wang, Z.X. Cao, Y.L. Song, L. Jiang, Soft Matter, 8, 6680 (2012).
Y. Nam, S. Sharratt, C. Byon, S.J. Kim, Y.S. Ju, J. Microelectromech. Syst. 19, 581 (2010).
Y. Nam, Y. Sungtaek, J. Adhes. Sci. Technol. 1 (2012).
J.W. Rose, Int. J. Heat Mass Trans. 10, 755 (1967).
J.B. Boreyko, Y.J. Zhao, C.H. Chen, Appl. Phys. Lett. 99, 234105 (2011).
J. Cheng, A. Vandadi, C.L. Chen, Appl. Phys. Lett. 101, 131909 (2012).
J.B. Boreyko, C.H. Chen, Int. J. Heat Mass Transf. 61, 409 (2013).
X.H. Ma, X.D. Zhou, Z. Lan, Y.M. Li, Y. Zhang, Int. J. Heat Mass Trans. 51, 1728 (2008).
J.W. Rose, Int. J. Heat Mass Trans. 23, 539 (1980).
G.P. Thiel, J.H. Lienhard, Int. J. Heat Mass Trans. 55, 5133 (2012).
H.C. Barshilia, A. Chaudhary, P. Kumar, N.T. Manikandanath, Nanomaterials 2, 65 (2012).
G. Azimi, R. Dhiman, H.K. Kwon, A.T. Paxson, K.K. Varanasi, Nat. Mater. (2013), doi: 10.1038/nmat3545.
A. Lafuma, D. Quéré, Europhys. Lett. 96, 56001 (2011).
T.S. Wong, S.H. Kang, S.K.Y. Tang, E.J. Smythe, B.D. Hatton, A. Grinthal, J. Aizenberg, Nature 477, 443 (2011).
S. Anand, A.T. Paxson, R. Dhiman, D.J. Smith, K.K. Varanasi, ACS Nano 6, 10122 (2012).
P. Kim, T.S. Wong, J. Alvarenga, M.J. Kreder, W.E. Adorno-Martinez, J. Aizenberg, ACS Nano 6, 6569 (2012).
P.W. Wilson, W. Lu, H. Xu, P. Kim, M.J. Kreder, J. Alvarenga, J. Aizenberg, Phys. Chem. Chem. Phys. 15, 581 (2013).
A.K. Epstein, T.S. Wong, R.A. Belisle, E.M. Boggs, J. Aizenberg, Proc. Natl. Acad. Sci. U.S.A. 109, 13182 (2012).
D.J. Smith, R. Dhiman, S. Anand, E. Reza-Garduno, R.E. Cohen, G.H. McKinley, K.K. Varanasi, Soft Matter 9, 1772 (2013).
A. Tuteja, W.J. Choi, G.H. McKinley, R.E. Cohen, M.F. Rubner, MRS Bull. 33, 752 (2008).
X. Deng, L. Mammen, H.J. Butt, D. Vollmer, Science 335, 67 (2012).
S. Nishimoto, B. Bhushan, RSC Adv. 3, 671 (2013).
X.J. Liu, Y.M. Liang, F. Zhou, W.M. Liu, Soft Matter 8, 2070 (2012).
D. Stokes, Principles and Practice of Variable Pressure/Environmental Scanning Electron Microscopy (VP-ESEM) (New York, Wiley, 2008).
N.A. Stelmashenko, J.P. Craven, A.M. Donald, E.M. Terentjev, B.L. Thiel, J. Microsc. 204, 172 (2001).
M.P. Rossi, Y. Gogotsi, K.G. Kornev, Langmuir 25, 2804 (2009).
N. Miljkovic, R. Enright, S.C. Maroo, H.J. Cho, E.N. Wang, J. Heat Transfer 133, 080903 (2011).
N. Miljkovic, R. Enright, E.N. Wang, J. Heat Transfer 134 (8), 080902 (2012).
Z. Barkay, Appl. Phys. Lett. 96, 183109 (2010).
B. Bhushan, Y.C. Jung, J. Microsc. 229, 127 (2008).
K. Rykaczewski, J.H.J. Scott, ACS Nano 5, 5962 (2011).
K. Rykaczewski, J.H.J. Scott, A.G. Fedorov, Appl. Phys. Lett. 98, 093106 (2011).
S. Wiedemann, A. Plettl, P. Walther, P. Ziemann, Langmuir 29, 913 (2013).
K. Rykaczewski, T. Landin, M.L. Walker, J.H.J. Scott, K.K. Varanasi, ACS Nano 6, 9326 (2012).
Acknowledgements
We gratefully acknowledge funding support from the MIT S3TEC Center, an Energy Frontier Research Center funded by the Department of Energy, Office of Science, Office of Basic Energy Sciences, Office of Naval Research Young Investigator Award, and Air Force Office of Scientific Research Young Investigator Award.
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Miljkovic, N., Wang, E.N. Condensation heat transfer on superhydrophobic surfaces. MRS Bulletin 38, 397–406 (2013). https://doi.org/10.1557/mrs.2013.103
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DOI: https://doi.org/10.1557/mrs.2013.103