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Oxygen semi-permeation properties of La1−xSrxFeO3−δ perovskite membranes under high oxygen gradient

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Abstract

This work is focused on the evaluation of oxygen semi-permeation and electrochemical performances under high oxygen gradient of free cobalt perovskite membrane materials; La1−xSrxFeO3−δ perovskite. For a better understanding of oxygen transport through La1−xSrxFeO3−δ perovskite membranes, the oxygen diffusion, oxygen incorporation, and desorption coefficients were determined under high oxygen gradient in relation to the temperature for La1−xSrxFeO3−δ (with x = 0.1, 0.3, 0.5, and 0.7) by a specific method based on oxygen semi-permeation. The best electrochemical performances were obtained for La0.3Sr0.7FeO3−δ (LSF37) and La0.5Sr0.5FeO3−δ (LSF55) perovskite membranes with oxygen fluxes of 1.7 × 10−3 and 1.2 × 10−3 mol/m2 s at 900 °C, respectively. The oxygen incorporation and desorption coefficients of LSF55 were two times lower than those of LSF37 and similar to those of La0.5Sr0.5Fe0.7Ga0.3O3−δ. The values of these coefficients are discussed and compared with the data reported in the literature by isotopic exchange for the similar material compositions.

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Authors and Affiliations

  1. IRCER, CNRS, Université de Limoges, CEC, 12 Rue Atlantis, 87068, Limoges, France

    Eva Deronzier, Thierry Chartier & Pierre-Marie Geffroy

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  1. Eva Deronzier
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  2. Thierry Chartier
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  3. Pierre-Marie Geffroy
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Correspondence to Eva Deronzier.

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Deronzier, E., Chartier, T. & Geffroy, PM. Oxygen semi-permeation properties of La1−xSrxFeO3−δ perovskite membranes under high oxygen gradient. Journal of Materials Research 35, 2506–2515 (2020). https://doi.org/10.1557/jmr.2020.230

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