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Preparation and photocatalytic application of AgBr modified Bi2WO6 nanosheets with high adsorption capacity

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Abstract

AgBr-modified Bi2WO6 nanosheets were successfully synthesized using a CTAB-assisted hydrothermal method followed by a facile deposition–precipitation procedure. The as-prepared photocatalysts were characterized using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), UV-vis diffuse reflectance spectroscopy (DRS), Brunauer–Emmett–Teller (BET), and photoluminescence emission spectroscopy (PL). AgBr nanoparticles were found evenly distributed on the surface of the Bi2WO6 nanosheets. The AgBr/Bi2WO6 nanocomposite demonstrated enhanced pollutant decolorization efficiency in eliminating Rhodamine B (RhB), methyl orange (MO), and phenol aqueous solutions under simulated solar light irradiation. It has been noticed that the adsorption performance of both Bi2WO6 nanosheets and AgBr-modified Bi2WO6 nanosheets played a more important role in the decolorization of pollutants, such as RhB and MO, than their photocatalytic ability. The high adsorption efficiency of the photocatalysts was mainly attributed to the increased surface area and the exposed reactive facets of the materials.

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References

  1. C. Zhang and Y.F. Zhu: Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts. Chem. Mater. 17, 3537 (2005).

    Article  CAS  Google Scholar 

  2. H.B. Fu, C.S. Pan, W.Q. Yao, and Y.F. Zhu: Visible-light-induced degradation of rhodamine B by nanosized Bi2WO6. J. Phys. Chem. B 109, 22432 (2005).

    Article  CAS  Google Scholar 

  3. S.X. Yu, Y.H. Zhang, M. Li, X. Du, and H.W. Huang: Non-noble metal Bi deposition by utilizing Bi2WO6 as the self-sacrificing template for enhancing visible light photocatalytic activity. Appl. Surf. Sci. 391, 491 (2017).

    Article  CAS  Google Scholar 

  4. L.S. Zhang, W.Z. Wang, L. Zhou, and H.L. Xu: Bi2WO6 nano-and microstructures: Shape control and associated visible-light-driven photocatalytic activities. Small 3, 1618 (2007).

    Article  CAS  Google Scholar 

  5. Y.M. Liu, H.B. Tang, H. Lv, Z.J. Li, Z.W. Ding, and S. Li: Self-assembled three-dimensional hierarchical Bi2WO6 microspheres by sol–gel-hydrothermal route. Ceram. Int. 40, 6203 (2014).

    Article  CAS  Google Scholar 

  6. Z. Lou, J.N. Deng, L.L. Wang, L.J. Wang, and T. Zhang: Curling-like Bi2WO6 microdiscs with lamellar structure for enhanced gas-sensing properties. Sens. Actuators, B 182, 217 (2013).

    Article  CAS  Google Scholar 

  7. S.M. Sun, W.Z. Wang, L. Zhang, E.P. Gao, D. Jiang, Y.F. Sun, and L. Xie: Ultrathin {001}-oriented bismuth tungsten oxide nanosheets as highly efficient photocatalysts. ChemSusChem 6, 1873 (2013).

    Article  CAS  Google Scholar 

  8. Y.G. Zhou, Y.F. Zhang, M.S. Lin, J.L. Long, Z.Z. Zhang, H.X. Lin, J.C.S. Wu, and X.X. Wang: Monolayered Bi2WO6 nanosheets mimicking heterojunction interface with open surfaces for photocatalysis. Nat. Commun. 6, 8340 (2015).

    Article  Google Scholar 

  9. P. Zhang, X. Hua, X.X. Teng, D.S. Liu, Z.H. Qin, and S.M. Ding: CTAB assisted hydrothermal synthesis of lamellar Bi2WO6 with superior photocatalytic activity for rhodamine b degradation. Mater. Lett. 185, 275 (2016).

    Article  CAS  Google Scholar 

  10. D. Sun, Y. Le, C.J. Jiang, and B. Cheng: Ultrathin Bi2WO6 nanosheet decorated with Pt nanoparticles for efficient formaldehyde removal at room temperature. Appl. Surf. Sci. 441, 429 (2018).

    Article  CAS  Google Scholar 

  11. K. Dai, L.H. Lu, J. Dong, Z.Y. Ji, Z.G. Ping, Q.Z. Liu, Y.X. Zhang, D.P. LI, and C.H. Liang: Facile synthesis of a surface plasmon resonance-enhanced Ag/AgBr heterostructure and its photocatalytic performance with 450 nm LED illumination. Dalton Trans. 42, 4657 (2013).

    Article  CAS  Google Scholar 

  12. Y.J. Zang and R. Farnood: Photocatalytic activity of AgBr/TiO2 in water under simulated sunlight irradiation. Appl. Catal., B 79, 334 (2008).

    Article  CAS  Google Scholar 

  13. L. Shi, L. Liang, J. Ma, Y.N. Meng, S.F. Zhong, F.X. Wang, and J.M. Sun: Highly efficient visible light-driven Ag/AgBr/ZnO composite photocatalyst for degrading Rhodamine B. Ceram. Int. 40, 3495 (2014).

    Article  CAS  Google Scholar 

  14. H. Xu, J. Yan, Y.G. Xu, Y.H. Song, H.M. Li, J.X. Xia, C.J. Huang, and H.L. Wan: Novel visible-light-driven AgX/graphite-like C3N4 (X = Br, I) hybrid materials with synergistic photocatalytic activity. Appl. Catal., B 129, 182 (2013).

    Article  CAS  Google Scholar 

  15. P. Amornpitoksuk and S. Suwanboon: Photocatalytic degradation of dyes by AgBr/Ag3PO4 and the ecotoxicities of their degraded products. Chin. J. Catal. 37, 711 (2016).

    Article  Google Scholar 

  16. D.J. Wang, L. Guo, Y.Z. Zhen, L.L. Yue, G.L. Xue, and F. Fu: AgBr quantum dots decorated mesoporous Bi2WO6 architectures with enhanced photocatalytic activities for methylene blue. J. Mater. Chem. A 2, 11716 (2014).

    Article  CAS  Google Scholar 

  17. S.L. Lin, L. Liu, J.S. Hu, Y.H. Liang, and W.Q. Cui: Nano Ag@AgBr surface-sensitized Bi2WO6 photocatalyst: Oil-in-water synthesis and enhanced photocatalytic degradation. Appl. Surf. Sci. 324, 20 (2015).

    Article  CAS  Google Scholar 

  18. F. Chen, Q. Yang, X.M. Li, G.M. Zeng, D.B. Wang, C.G. Niu, J.W. Zhao, H.X. An, T. Xie, and Y.C. Deng: Hierarchical assembly of graphene-bridged Ag3PO4/Ag/BiVO4 (040) Z-scheme photocatalyst: An efficient, sustainable and heterogeneous catalyst with enhanced visible-light photoactivity towards tetracycline degradation under visible light irradiation. Appl. Catal., B 200, 330 (2017).

    Article  CAS  Google Scholar 

  19. Y.X. Yang, W. Guo, Y.N. Guo, Y.H. Zhao, X. Yuan, and Y.H. Guo: Fabrication of Z-scheme plasmonic photocatalyst Ag@AgBr/g-C3N4 with enhanced visible-light photocatalytic activity. J. Hazard. Mater. 271, 150 (2014).

    Article  CAS  Google Scholar 

  20. K. Fuku, R. Hayashi, S. Takakura, T. Kamegawa, K. Mori, and H. Yamashita: The synthesis of size-and color-controlled silver nanoparticles by using microwave heating and their enhanced catalytic activity by localized surface plasmon resonance. Angew. Chem., Int. Ed. 52, 7446 (2013).

    Article  CAS  Google Scholar 

  21. J.C. Yu, J.G. Yu, W.K. Ho, Z.T. Jiang, and L.Z. Zhang: Effects of F-doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chem. Mater. 14, 3808 (2002).

    Article  CAS  Google Scholar 

  22. V. Subramanian, E.E. Wolf, and P.V. Kamat: Catalysis with TiO2/gold nanocomposites. Effect of metal particle size on the Fermi level equilibration. J. Am. Chem. Soc. 126, 4943 (2004).

    Article  CAS  Google Scholar 

  23. Z.J. Zhang, W.Z. Wang, L. Wang, and S.M. Sun: Enhancement of visible-light photocatalysis by coupling with narrow-band-gap semiconductor: A case study on Bi2S3/Bi2WO6. ACS Appl. Mater. Interfaces 4, 593 (2012).

    Article  CAS  Google Scholar 

  24. K.S.W. Sing: Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984). Pure Appl. Chem. 57, 603 (1985).

    Article  CAS  Google Scholar 

  25. Z. Feng, L. Zeng, Y.J. Chen, Y.Y. Ma, C.R. Zhao, R.S. Jin, Y. Lu, Y. Wu, and Y.M. He: In situ preparation of Z-scheme MoO3/g-C3N4 composite with high performance in photocatalytic CO2 reduction and RhB degradation. J. Mater. Res. 32, 3660 (2017).

    Article  CAS  Google Scholar 

  26. S.R. Fu, Y.M. He, Q. Wu, Y. Wu, and T.H. Wu: Visible-light responsive plasmonic Ag2O/Ag/g-C3N4 nanosheets with enhanced photocatalytic degradation of Rhodamine B. J. Mater. Res. 31, 2252 (2016).

    Article  CAS  Google Scholar 

  27. F.J. Wua, X. Lia, W. Liu, and S.T. Zhang: Highly enhanced photocatalytic degradation of methylene blue over the indirect all-solid-state Z-scheme g-C3N4-RGO-TiO2 nanoheterojunctions. Appl. Surf. Sci. 405, 60 (2017).

    Article  Google Scholar 

  28. J.Q. Wen, J. Xie, X.B. Chen, and X. Li: A review on g-C3N4-based photocatalysts. Appl. Surf. Sci. 391, 72 (2017).

    Article  CAS  Google Scholar 

  29. H.N. Wang, T. Wang, L. Han, M. Tang, J. Zhong, W.Q. Huang, and R.Y. Chen: VOC adsorption and desorption behavior of hydrophobic, functionalized SBA-15. J. Mater. Res. 31, 516 (2016).

    Article  Google Scholar 

  30. M. Rames, C. Rao, S. Anandan, and H. Nagaraja: Adsorption and photocatalytic properties of NiO nanoparticles synthesized via a thermal decomposition process. J. Mater. Res. 33, 601 (2016).

    Article  Google Scholar 

  31. C. Boruban and E.N. Esenturk: Synthesis of CuO nanostructures on zeolite-Y and investigation of their CO2 adsorption properties. J. Mater. Res. 32, 3669 (2017).

    Article  CAS  Google Scholar 

  32. J. Song, K. Huang, and N. Wang: Gas-sensing properties and in situ diffuse-reflectance Fourier-transform infrared spectroscopy study of diethyl ether adsorption and reactions on SnO2/rGO film. J. Mater. Res. 31, 2035 (2016).

    Article  CAS  Google Scholar 

  33. Y.K. Liu, Q. Huang, G.H. Jiang, D.P. Liu, and W.J. Yu: Cu2O nanoparticles supported on carbon nanofibers as a cost-effective and efficient catalyst for RhB and phenol degradation. J. Mater. Res. 32, 3605 (2017).

    Article  CAS  Google Scholar 

  34. C.Y. Bai, G. Franchin, H. Elsayed, A. Zaggia, L. Conte, H.Q. Li, and P. Colombo: High-porosity geopolymer foams with tailored porosity for thermal insulation and wastewater treatment. J. Mater. Res. 32, 3251 (2017).

    Article  CAS  Google Scholar 

  35. K.J. Kim, J.H. Seo, M. Lee, J. Moon, K.C. Lee, D.K. Yi, and U. Paik: Ce3+-enriched core–shell ceria nanoparticles for silicate adsorption. J. Mater. Res. 32, 2829 (2017).

    Article  CAS  Google Scholar 

  36. P. Zhang, P.Y. Wu, S.Y. Bao, Z. Wang, B.Z. Tian, and J.L. Zhang: Synthesis of sandwich-structured AgBr@Ag@TiO2 composite photocatalyst and study of its photocatalytic performance for the oxidation of benzyl alcohols to benzaldehydes. Chem. Eng. J. 306, 1151 (2016).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The authors are grateful to the funding from the Achievement Transfer Program of Institutions of Higher Education in Chongqing (KJZH17131), the “Chunhui Project” of Ministry of Education of the People’s Republic of China (Grant No. Z2016175), the Scientific Research Project of Fuling District (Grant No. FLKW, 2017ABA1007), and the Scientific Research Foundation of Yangtze Normal University (Grant No. 2015XJXM01).

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Correspondence to Hualin Xie.

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Zhang, P., Dong, Z., Ran, Y. et al. Preparation and photocatalytic application of AgBr modified Bi2WO6 nanosheets with high adsorption capacity. Journal of Materials Research 33, 3953–3962 (2018). https://doi.org/10.1557/jmr.2018.386

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  • DOI: https://doi.org/10.1557/jmr.2018.386

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