Abstract
Isothermal compression testing of Ti–5.8Al–3Sn–5Zr–0.5Mo–1.0Nb–1.0Ta–0.4Si–0.2Er titanium alloy is performed on a Gleeble-3500 thermal simulator, and the corresponding microstructures are analyzed to clarify the softening mechanism and participates evolution. A constitutive equation compensated by strain has been established to describe the hot deformation behavior of the alloy. The deformation activation energies are calculated to be 369760.93–699310.86 J/mol in α + β two-phase region and 268030.03–325800.41 J/mol in β single-phase region. At a temperature of 880 °C, the main softening mechanism is the continuous dynamic recrystallization of lamellar α colony, controlled by the mechanical rotation of the sub-grain followed by dislocation climbing and annihilation by diffusion. Meanwhile, the dominant softening mechanism is the discontinuous dynamic recrystallization of β phase during the deformation at temperatures of 920 °C–1080 °C. Silicide containing Er with an average diameter of 20 nm is formed during the water quenching.
Similar content being viewed by others
References
R.R. Boyer: An overview on the use of titanium in the aerospace industry. Mater. Sci. Eng., A 213, 103 (1996).
D. Banerjee and J.C. Williams: Perspectives on titanium science and technology. Acta Mater. 61, 844 (2013).
Z.X. Guo and T.N. Baker: On the microstructure and thermo mechanical processing of titanium alloy IMI685. Mater. Sci. Eng., A 156, 63 (1992).
N. Singh and V. Singh: Effect of temperature on tensile properties of near-α alloy Timetal 834. Mater. Sci. Eng., A 485, 130 (2008).
D.H. Lee, S.W. Nam, and S.J. Choe: Effect of microstructure and relaxation behavior on the high temperature low cycle fatigue of near-α-Ti-1100. Mater. Sci. Eng., A 291, 60 (2000).
W.J. Jia, W.D. Zeng, J.R. Liu, Y.G. Zhou, and Q.J. Wang: Influence of thermal exposure on the tensile properties and microstructures of Ti60 titanium alloy. Mater. Sci. Eng., A 530, 511 (2011).
Q. Hong, Y.L. Qi, Y.Q. Zhao, and G.J. Yang: Effect of rolling process on microstructure and properties of Ti600 alloy plates. Rare Met. Mater. Eng. 34(8), 1334 (2015).
M.Y. Hao, J.M. Cai, and J. Du: The effect of heat treatment on microstructure and properties of BT36 high temperature alloy. J. Aeronaut. Mater. 23(02), 14 (2012).
Q.J. Wang, J.R. Liu, and R. Yang: High temperature titanium alloys: Status and perspective. J. Aeronaut. Mater. 34(04), 1 (2014).
S.Z. Zhang, M.M. Li, and R. Yang: Mechanism and kinetics of carbide dissolution in near alpha Ti–5.6Al–4.8Sn–2Zr–1Mo–0.35Si–0.7Nd titanium alloy. Mater. Charact. 62, 1151 (2011).
L. Xiao, W.J. Lu, and Z.F. Yang: Effect of reinforcements on high temperature mechanical properties of in situ synthesized titanium matrix composites. Mater. Sci. Eng., A 491, 192 (2008).
S.M.L. Sastry, P.J. Meschter, and J.E. O’Neal: Structure and properties of rapidly solidified dispersion-strengthened titanium alloys Part I. Characterization of dispersoid distribution, structure, and chemistry. Metall. Trans. A 15, 1451 (1984).
K.K. Sankaran, S.M.L. Sastry, and P.S. Pao: The effects of second-phase dispersoids on the deformation behavior of titanium. Metall. Trans. A 11, 196 (1980).
P. Han, B.L. Li, J.M. Yin, T. Liu, and Z.R. Nie: Effect of Er on creep properties of a near-α high temperature titanium alloy. Sci. Tech. Engrg. 12(17), 4124 (2012).
H.R. Jiang, M. Hirohasi, Y. Lu, and H. Imanari: Effect of Nb on the high temperature oxidation of Ti–(0–50 at.%)Al. Scr. Mater. 46, 639 (2002).
B.G. Fu, H.W. Wang, C.M. Zou, and Z.J. Wei: The effects of Nb content on microstructure and fracture behavior of near α titanium alloys. Mater. Des. 66, 267 (2015).
S.X. Zhu, Q.J. Wang, J.R. Liu, Y.Y. Liu, and R. Yang: Effect of Ta on oxidation resistance behavior of Ti-60A titanium alloys. Trans. Nonferrous Met. Soc. China 20(1), 138 (2010).
W.J. Jia, W.D. Zeng, and H.Q. Yu: Effect of aging on the tensile properties and microstructures of a near-alpha titanium alloy. Mater. Des. 58, 108 (2014).
T. Wang, H.Z. Guo, Y.W. Wang, X.N. Peng, Y. Zhao, and Z.K. Yao: The effect of microstructure on tensile properties, deformation mechanisms and fracture models of TG6 high temperature titanium alloy. Mater. Sci. Eng., A 528, 2370 (2011).
I. Cvijović-Alagić, N. Gubeljak, M. Rakin, Z. Cvijović, and K. Gerić: Microstructural morphology effects on fracture resistance and crack tip strain distribution in Ti–6Al–4V alloy for orthopedic implants. Mater. Des. 53, 870 (2014).
Y.G. Zhou, W.D. Zeng, and H.Q. Yu: A new high-temperature deformation strengthening and toughening process for titanium alloys. Mater. Sci. Eng., A 221, 58 (1996).
V. Chandravanshi, R. Sarkar, S.V. Kamat, and T.K. Nandy: Effects of thermomechanical processing and heat treatment on the tensile and creep properties of boron-modified near alpha titanium alloy Ti-1100. Metall. Mater. Trans. A 44A, 201 (2013).
D.V.V. Satyanarayana, C.M. Omprakash, T. Sridhar, and V. Kumar: Effect of microstructure on creep crack growth behavior of a near-a titanium alloy IMI-834. Metall. Mater. Trans. A 40A, 128 (2009).
P. Vo, M. Jahazi, and S. Yue: Recrystallization during thermomechanical processing of IMI834. Metall. Mater. Trans. A 30A, 2965 (2008).
Y.C. Lin, Y. Ding, M.S. Chen, and J. Deng: A new phenomenological constitutive model for hot tensile deformation behaviors of a typical Al–Cu–Mg alloy. Mater. Des. 52, 118 (2013).
W.W. Peng, W.D. Zeng, Q.J. Wang, and H.Q. Yu: Characterization of high-temperature deformation behavior of as-cast Ti60 titanium alloy using processing map. Mater. Sci. Eng., A 571, 116 (2013).
H. Wu, S.P. Wen, H. Huang, X.L. Wu, K.Y. Gao, W. Wang, and Z.R. Nie: Hot deformation behavior and constitutive equation of a new type Al–Zn–Mg–Er–Zr alloy during isothermal compression. Mater. Sci. Eng., A 651, 415 (2016).
Y.L. Zhao, B.L. Li, Z.S. Zhu, and Z.R. Nie: The high temperature deformation behavior and microstructure of TC21 titanium alloy. Mater. Sci. Eng., A 527, 5360 (2010).
Z.L. Zhao, H. Li, M.W. Fu, H.Z. Guo, and Z.K. Yao: Effect of the initial microstructure on the deformation behavior of Ti60 titanium alloy at high temperature processing. J. Alloys Compd. 617, 525 (2014).
C.M. Sellars and W.J. Tegart: On the mechanism of hot deformation. Acta Metall. 14, 1136 (1966).
C. Zener and J.H. Hollomon: Effect of strain rate upon plastic flow of steel. J. Appl. Phys. 15, 22 (1944).
N. Radovi and D. Drobnjak: Effect of interpass time and cooling rate on apparent activation energy for hot working and critical recrystallization temperature of Nb-microalloyed steel. ISIJ Int. 39, 575 (1999).
W.S. Lee and M.T. Lin: The effects of strain rate and temperature on the compressive deformation behaviour of Ti–6A1–4V alloy. J. Mater. Process. Technol. 71(2), 235 (1997).
D. Drobnjak, N. Radovi, and M. Andjeli: Effect of test variables on apparent activation energy for hot working and critical recrystallization temperatures of V-microalloyed steel. Steel Res. 68(7), 306 (1997).
Y. Niu, H.L. Hou, M.Q. Li, and Z.Q. Li: High temperature deformation behavior of a near alpha Ti600 titanium alloy. Mater. Sci. Eng., A 492, 24 (2008).
M.Q. Li, H.S. Pan, Y.Y. Lin, and J. Luo: High temperature deformation behavior of near alpha Ti–5.6Al–4.8Sn–2.0Zr alloy. J. Mater. Process. Technol. 183, 71 (2007).
H.R. Rezaei Ashtiani, M.H. Parsa, and H. Bisadi: Constitutive equations for elevated temperature flow behavior of commercial purity aluminum. Mater. Sci. Eng., A 545, 61 (2012).
S. Mandal, V. Rakesh, P.V. Sivaprasad, S. Venugopal, and K.V. Kasiviswanathan: Constitutive equations to predict high temperature flow stress in a Ti-modified austenitic stainless steel. Mater. Sci. Eng., A 500, 114 (2009).
D.T. Mcdonald, F.J. Humphreys, and P.S. Bate: Nucleation and texture development during dynamic recrystallization of copper. J. Mater. Process. Technol. 263(10), 1195 (2005).
F.C. Ma, W.J. Lu, J.N. Qin, and D. Zhang: Microstructure evolution of near-α titanium alloys during thermomechanical processing. Mater. Sci. Eng., A 416, 59 (2006).
M.Y. Chu, S.X. Hui, Z. Zhang, and J.Y. Shen: Precipitation mechanism of silicide in BT25y titanium alloy in solution treatment and thermal exposure. J. Chin. Electron Microsc. Soc. 23(2), 168 (2004).
ACKNOWLEDGMENTS
This research was supported by the Beijing Natural Science Foundation (Project No. 2162004), and National Natural Science Foundation of China (Project No. 51371013).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Wang, T., Li, B., Wang, Z. et al. Hot deformation behavior and microstructure evolution of a high-temperature titanium alloy modified by erbium. Journal of Materials Research 32, 1517–1527 (2017). https://doi.org/10.1557/jmr.2017.33
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/jmr.2017.33