Abstract
Tungsten oxide (WO3−x) nanomaterials with controlled morphology and composition were fabricated by thermal evaporation of WO3 and S powders at different temperatures in a vacuum tube furnace. At 850 °C the obtained green particle is still of the same monoclinic WO3 phase as that of the starting powder. At a temperature between 900 and 1100 °C, the resultant dark-blue products are particle-like clusters composed of numerous monoclinic WO2.90 short nanorods, but the clusters became looser and the nanorods grew somewhat longer as the temperature increased. At a temperature between 1150 and 1250 °C, elongated and thoroughly separate purple-red monoclinic W18O49 nanorods were obtained. The growth of the prepared WO3−x nanomaterials was controlled by a gas–solid mechanism. Their photocatalytic degradation on organic contaminants was evaluated by decomposing methylene blue (MB) in aqueous phase under sunlight, in which WO3 particles presented higher photocatalytic activity than its oxygen-deficient counterparts, WO2.90 and W18O49. But the W18O49 nanorods had higher adsorption ability to MB in all the samples.
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ACKNOWLEDGMENTS
The authors would like to thank the financial support for this work from the National Natural Science Foundation of China (Grant Nos. 61274015, 11274052, and 51172030), Excellent Adviser Foundation in China University of Geosciences from the Fundamental Research Funds for the Central Universities, and Fund of State Key Laboratory of Information Photonics and Optical Communications (Beijing University of Posts and Telecommunications).
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Supplementary Materials: Synthesis of WO3−X nanomaterials with controlled morphology and composition for highly efficient photocatalysis (approximately 33.2 MB)
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Shen, Z., Zhao, Z., Qian, J. et al. Synthesis of WO3−x nanomaterials with controlled morphology and composition for highly efficient photocatalysis. Journal of Materials Research 31, 1065–1076 (2016). https://doi.org/10.1557/jmr.2016.106
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DOI: https://doi.org/10.1557/jmr.2016.106