Abstract
Laser metal deposition (LMD) additive manufacturing was used to deposit Inconel 625 matrix composites reinforced with nano-TiC particles. The effects of laser energy input per unit length (E) on the densification level, microstructural features, mircohardness, and wear property were investigated. The relatively low E induced insufficient liquid with higher viscosity, thus inhibiting the melted liquid from spreading out smoothly. As a result, a large number of micropores and reduced densification level of LMD-processed parts were obtained. When the E of 100 kJ/m was properly settled, the obtainable densification level generally approached 98.8%. The TiC reinforcements experienced successive microstructural changes from agglomeration to uniform distribution with coarsening grain, as the applied E increased. The nearly fully dense parts using optimal experimental parameters achieved an increased average microhardness of 330 HV0.2, resultant considerably low coefficient of friction of 0.41 and reduced wear rate of 5.4 × 10−4 mm3/(N m) in dry sliding wear tests.
Similar content being viewed by others
References
V. Shankar, K.B.S. Rao, and S.L. Mannan: Microstructure and mechanical properties of Inconel 625 superalloy. J. Nucl. Mater. 288, 222 (2001).
T.E. Abioye, J. Folkes, and A.T. Clare: A parametric study of Inconel 625 wire laser deposition. J. Mater. Process. Technol. 213, 2145 (2013).
K.P. Cooper, P. Slebodnick, and E.D. Thomas: Seawater corrosion behavior of laser surface modified Inconel 625 alloy. Mater. Sci. Eng., A 206, 138 (1996).
Z.N. Bi, J.X. Dong, L. Zheng, and X.S. Xie: Phenomenon and mechanism of high temperature low plasticity in high-Cr nickel-based superalloy. J. Mater. Sci. Technol. 29, 187 (2013).
J.H. He and E.J. Lavernia: Development of nanocrystalline structure during cryomilling of Inconel 625. J. Mater. Res. 16, 2724 (2001).
D.E. Cooper, N. Blundell, S. Maggs, and G.J. Gibbons: Additive layer manufacture of Inconel 625 metal matrix composites, reinforcement material evaluation. J. Mater. Process. Technol. 213, 2191 (2013).
I.A. Ibrahim, F.A. Mohamed, and E.J. Lavernia: Particulate reinforced metal matrix composites—A review. J. Mater. Sci. 26, 1137 (1991).
X.Y. Li and K.N. Tandon: Effect of ion implantation on the dry sliding wear behavior of SiC reinforced Al-Si composite. Surf. Coat. Technol. 90, 136 (1997).
T.C. Lei, J.H. Ouyang, Y.T. Pei, and Y. Zhou: Microstructure and wear resistance of laser clad TiC particle reinforced coating. Mater. Sci. Technol. 11, 520 (1995).
B.C. Mei, R.Z. Yuan, and X.L. Duan: Investigation of Ni3Al-matrix composites strengthened by TiC. J. Mater. Res. 8, 2830 (2001).
D.F. Jiang, C. Hong, M.L. Zhong, M. Alkhayat, A. Weisheit, A. Gasser, H.J. Zhang, I. Kelbassa, and R. Poprawe: Fabrication of nano-TiCp reinforced Inconel 625 composite coatings by partial dissolution of micro-TiCp through laser cladding energy input control. Surf. Coat. Technol. 249, 125 (2014).
B.L. Zheng, T. Topping, J.E. Smugeresky, Y.Z. Zhou, A. Biswas, D. Baker, and E.J. Lavernia: The influence of Ni-coated TiC on laser-deposited IN625 metal matrix composites. Metall. Mater. Trans. A 42, 568 (2010).
X.D. Hui, Y.S. Yang, Z.F. Wang, G.Q. Yuan, and X.C. Chen: High temperature creep behavior of in-situ TiC particulate reinforced Fe–Cr–Ni matrix composite. Mater. Sci. Eng., A 282, 187 (2000).
R. Casati and M. Vedani: Metal matrix composites reinforced by nano-particles-a review. Metals 4, 65–68 (2014).
F. He, Q. Han, and M.J. Jackson: Nanoparticulate reinforced metal matrix nanocomposites a review. Int. J. Nanopart. 1, 301 (2009).
D.D. Gu, Y.C. Hagedorn, W. Meiners, K. Wissenbach, and R. Poprawe: Selective laser melting of in-situ TiC/Ti5Si3 composites with novel reinforcement architecture and elevated performance. Surf. Coat. Technol. 205, 3285 (2011).
K. Shah, A.J. Pinkerton, A. Salman, and L. Li: Effects Of melt pool variables and process parameters in laser direct metal deposition of aerospace alloys. Mater. Manuf. Process. 25, 1372 (2010).
H.P. Qua, P. Li, S.Q. Zhang, A. Li, and H.M. Wang: Microstructure and mechanical property of laser melting deposition (LMD) Ti/TiAl structural gradient material. Mater. Des. 31, 574 (2010).
G.P. Dindaa, A.K. Dasgupta, and J. Mazumderb: Laser aided direct metal deposition of Inconel 625 superalloy: Microstructural evolution and thermal stability. Mat. Sci. Eng., A 509, 98 (2009).
H. Sun and K.M. Flores: Laser deposition of a Cu-based metallic glass powder on a Zr-based glass substrate. J. Mater. Res. 23, 2692 (2008).
G. Rolink, S. Vogt, L. Sencekova, A. Weisheit, R. Poprawe, and M. Palm: Laser metal deposition and selective laser melting of Fe-28 at.% Al. J. Mater. Res. 29, 2036 (2014).
Y.Z. Zhang, J.C. Sun, C. Huang, and G.W. Li: Characterization of in-situ titanium matrix composites prepared by laser melting deposition. Rare Met. Mater. Eng. 40, 33 (2011).
M. Rombouts, G. Maes, M. Mertens, and W. Hendrix: Laser metal deposition of Inconel 625: Microstructure and mechanical properties. J. Laser Appl. 24, 052007 (2012).
Y.Z. Zhang, L.K. Shi, G.W. Li, and M.Z. Xi: Characterization on laser melting deposition of metallic components. Rare Met. Mater. Eng. 40, 27 (2011).
D.D. Gu: Laser Additive Manufacturing of High-performance Materials, 1st ed. (Springer-Verlag, Berlin Heidelberg, Germany, 2015).
D.D. Gu and Y.F. Shen: Effects of processing parameters on consolidation and microstructure of W–Cu components by DMLS. J. Alloys Compd. 473, 107 (2009).
Y. Zhou and G.H. Wu: Analysis Methods in Materials Science—X-ray Diffraction and Electron Microscopy in Materials Science, 2nd ed. (Harbin Institute of Technology Press, Harbin, China, 2007).
I. Takamichi and I.L.G. Roderick: The Physical Properties of Liquid Metals, 1st ed. (Clarendon Press, Oxford, Britain, 1993).
Z.F. Yuan, J.J. Ke, and J. Li: Surface Tension of Metals and Alloys, 1st ed. (Science Press, Beijing, China, 2006).
R.D. Li, Y.S. Shi, L. Wang, J.H. Liu, and Z.G. Wang: The key metallurgical features of selective laser melting of stainless steel powder for building metallic part. Powder Metall. Met. Ceram. 50, 141 (2011).
T. Vilaro, C. Colin, J.D. Bartout, L. Naze, and M. Sennour: Microstructural and mechanical approaches of the selective laser melting process applied to a nickel-base superalloy. Mater. Sci. Eng., A 534, 446 (2012).
H. Yan, P.L. Zhang, Z.S. Yu, C.G. Li, and R.D. Li: Development and characterization of laser surface cladding (Ti,W)C reinforced Ni-30Cu alloy composite coating on copper. Opt. Laser Technol. 44, 1351 (2012).
V. Erukhimovitch and J. Baram: Crystallization kinetics. Phys. Rev. B 50, 5854 (1994).
M. Boccalini and H. Goldenstein: Solidification of high speed steels. Int. Mater. Rev. 46, 92 (2001).
A. Simchi and H. Asgharzadeh: Densification and microstructural evaluation during laser sintering of M2 high speed steel powder. Mater. Sci. Technol. 201462 (2004).
H. Qi, J. Mazumder, and H. Ki: Numerical simulation of heat transfer and fluid flow in coaxial laser cladding process for direct metal deposition. J. Appl. Phys. 100, 024903 (2006).
A. Simchi and H. Pohl: Effects of laser sintering processing parameters on the microstructure and densification of iron powder. Mater. Sci. Eng., A 359, 119 (2003).
H.J. Niu and I.T.H. Chang: Selective laser sintering of gas and water atomized high speed steel powders. Scr. Mater. 41, 25 (1999).
H.J. Niu and I.T.H. Chang: Instability of scan tracks of selective laser sintering of high speed steel powder. Scr. Mater. 41, 1229 (1999).
Y.P. Lei, H. Murakawa, Y.W. Shi, and X.Y. Li: Numerical analysis of the competitive influence of Marangoni flow and evaporation on heat surface temperature and molten pool shape in laser surface remelting. Comput. Mater. Sci. 21, 276 (2001).
K. Arafune and A. Hirata: Thermal and solutal marangoni convection in Ln-Ga-Sb system. J. Cryst. Growth 197, 811 (1999).
J.J. Bellina, Jr., J.A. Kargol, and N.F. Fiore: Surface film behavior on a Ni-base superalloy. Scr. Metall. Mater. 15, 211 (1981).
ACKNOWLEDGMENTS
The authors gratefully appreciate the financial support from the National Natural Science Foundation of China (Nos. 51322509 and 51575267), the Outstanding Youth Foundation of Jiangsu Province of China (No. BK20130035), the Program for New Century Excellent Talents in University (No. NCET-13-0854), the Science and Technology Support Program (The Industrial Part), Jiangsu Provincial Department of Science and Technology of China (No. BE2014009-2), the 333 Project (No. BRA2015368), Science and Technology Foundation for Selected Overseas Chinese Scholar, Ministry of Human Resources and Social Security of China, the Program for Distinguished Talents of Six Domains in Jiangsu Province of China (No. 2013-XCL-028), the Fundamental Research Funds for the Central Universities (Nos. NE2013103 and NP2015206), the Funding of Jiangsu Innovation Program for Graduate Education (No. SJLX15_0126), and the Priority Academic Program Development of Jiangsu Higher Education Institutions.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Cao, S., Gu, D. Laser metal deposition additive manufacturing of TiC/Inconel 625 nanocomposites: Relation of densification, microstructures and performance. Journal of Materials Research 30, 3616–3628 (2015). https://doi.org/10.1557/jmr.2015.358
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/jmr.2015.358