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Ultrafiltration performance and fouling resistance of PVB/SPES blend membranes with different degree of sulfonation

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Abstract

In the present study, we investigated the effects of different degree of sulfonation (DS) on the performance of the poly (vinyl butyral)/sulfonated polyethersulfone (PVB/SPES) blend membranes. The compatibility of the PVB/SPES blending system was characterized by shear viscosity and Fourier transform infrared attenuated total reflection, respectively. Results stated that all PVB/SPES blending systems were partially compatible. Contact angle, equilibrium water content, and x-ray photoelectron spectroscopy measurements were carried out to investigate the hydrophilicity of the PVB/SPES blend membranes. With increasing DS, the blend membranes became more hydrophilic. The pure water flux of the blend membranes increased with DS, while the rejection decreased due to microstructures of the PVB/SPES membranes. The mechanical properties of the PVB/SPES blend membranes increased slightly with DS. Fouling resistances of blend membranes evaluated by bovine serum albumin solution filtration revealed the PVB/SPES blend membranes with DS = 27% exhibited the superior antifouling properties.

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References

  1. P. Le-Clech, V. Chen, and T.A.G. Fane: Fouling in membrane bioreactors used in wastewater treatment. J. Membr. Sci. 284, 17 (2006).

    Article  CAS  Google Scholar 

  2. R. Lewis, S. Nothrop, C.W.K. Chow, A. Everson, and J.A. van Leeuwen: Colour formation from pre and post-coagulation treatment of Pinus radiata sulfite pulp mill wastewater using nutrient limited aerated stabilisation basins. Sep. Purif. Technol. 114, 1 (2013).

    Article  CAS  Google Scholar 

  3. M. Taniguchi and G. Belfort: Low protein fouling synthetic membranes by UV-assisted surface grafting modification: Varying monomer type. J. Membr. Sci. 231, 147 (2004).

    Article  CAS  Google Scholar 

  4. C. Aydiner: A novel approach based on distinction of actual and pseudo resistances in membrane fouling: “Pseudo resistance” concept and its implementation in nanofiltration of single solutions. J. Membr. Sci. 361, 96 (2010).

    Article  CAS  Google Scholar 

  5. B. Van der Bruggen, M. Mänttäri, and M. Nyström: Drawbacks of applying nanofiltration and how to avoid them: A review. Sep. Purif. Technol. 63, 251 (2008).

    Article  CAS  Google Scholar 

  6. Y. Qiu, J. Qi, and Y. Wei: Synergistic action of non-solvent induced phase separation in preparation of poly (vinyl butyral) hollow fiber membrane via thermally induced phase separation. J. Cent. South. Univ. 21, 2184 (2014).

    Article  CAS  Google Scholar 

  7. H.K. Lonsdale: The growth of membrane technology. J. Membr. Sci. 10, 81 (1982).

    Article  CAS  Google Scholar 

  8. R.S. Tutunjian: Ultrafiltration processes in biotechnology. Ann. N. Y. Acad. Sci. 413, 238 (1983).

    Article  CAS  Google Scholar 

  9. Y. Qiu, M. Hideto, H. Zhong, H. Ye, and K. Huang: Effects of F127 on properties of PVB/F127 blend hollow fiber membrane via thermally induced phase separation. Chin. J. Chem. Eng. 18, 207 (2010).

    Article  CAS  Google Scholar 

  10. Y.R. Qiu and H. Matsuyama: Preparation and characterization of poly (vinyl butyral) hollow fiber membrane via thermally induced phase separation with diluent polyethylene glycol 200. Desalination 257, 117 (2010).

    Article  CAS  Google Scholar 

  11. A.K. Dhaliwal and J.N. Hay: The characterization of polyvinyl butyral by thermal analysis. Thermochim. Acta. 391, 245 (2002).

    Article  CAS  Google Scholar 

  12. X. Fu, H. Matsuyama, M. Teramoto, and H. Nagai: Preparation of polymer blend hollow fiber membrane via thermally induced phase separation. Sep. Purif. Technol. 52, 363 (2006).

    Article  CAS  Google Scholar 

  13. L. Yan and J. Wang: Development of a new polymer membrane—PVB/PVDF blended membrane. Desalination 281, 455 (2011).

    Article  CAS  Google Scholar 

  14. J.H. Kim and C.K. Kim: Ultrafiltration membranes prepared from blends of polyethersulfone and poly (1-vinylpyrrolidone-co-styrene) copolymers. J. Membr. Sci. 262, 60 (2005).

    Article  CAS  Google Scholar 

  15. M. Ulbricht, O. Schuster, W. Ansorge, M. Ruetering, and P. Steiger: Influence of the strongly anisotropic cross-section morphology of a novel polyethersulfone microfiltration membrane on filtration performance. Sep. Purif. Technol. 57, 63 (2007).

    Article  CAS  Google Scholar 

  16. X. Ma, Y. Su, Q. Sun, Y. Wang, and Z. Jiang: Enhancing the antifouling property of polyethersulfone ultrafiltration membranes through surface adsorption-crosslinking of poly (vinyl alcohol). J. Membr. Sci. 300, 71 (2007).

    Article  CAS  Google Scholar 

  17. V. Moghimifar, A. Raisi, and A. Aroujalian: Surface modification of polyethersulfone ultrafiltration membranes by corona plasma-assisted coating TiO2 nanoparticles. J. Membr. Sci. 461, 69 (2014).

    Article  CAS  Google Scholar 

  18. J. Peng, Y. Su, Q. Shi, W. Chen, and Z. Jiang: Protein fouling resistant membrane prepared by amphiphilic pegylated polyethersulfone. Bioresour. Technol. 102, 2289 (2011).

    Article  CAS  Google Scholar 

  19. P.S. Yune, J.E. Kilduff, and G. Belfort: Using co-solvents and high throughput to maximize protein resistance for poly (ethylene glycol)-grafted poly (ether sulfone) UF membranes. J. Membr. Sci. 370, 166 (2011).

    Article  CAS  Google Scholar 

  20. R. Mahendran, R. Malaisamy, and D.R. Mohan: Cellulose acetate and polyethersulfone blend ultrafiltration membranes. Part I: Preparation and characterizations. Polym. Advan. Technol. 15, 149 (2004).

    Article  CAS  Google Scholar 

  21. Y. Wang, T. Wang, Y. Su, F. Peng, H. Wu, and Z. Jiang: Protein-adsorption-resistance and permeation property of polyethersulfone and soybean phosphatidylcholine blend ultrafiltration membranes. J. Membr. Sci. 270, 108 (2006).

    Article  CAS  Google Scholar 

  22. A. Rahimpour and S.S. Madaeni: Polyethersulfone (PES)/cellulose acetate phthalate (CAP) blend ultrafiltration membranes: Preparation, morphology, performance and antifouling properties. J. Membr. Sci. 305, 299 (2007).

    Article  CAS  Google Scholar 

  23. Y. Gao, G.P. Robertson, M.D. Guiver, X. Jian, S.D. Mikhailenko, K. Wang, and S. Kaliaguine: Sulfonation of poly (phthalazinones) with fuming sulfuric acid mixtures for proton exchange membrane materials. J. Membr. Sci. 227, 39 (2003).

    Article  CAS  Google Scholar 

  24. C. Klaysom, B.P. Ladewig, G.Q. Lu, and L. Wang: Preparation and characterization of sulfonated polyethersulfone for cation-exchange membranes. J. Membr. Sci. 368, 48 (2011).

    Article  CAS  Google Scholar 

  25. M.S. Kang, Y.J. Choi, I.J. Choi, T.H. Yoon, and S.H. Moon: Electrochemical characterization of sulfonated poly (arylene ether sulfone) (S-PES) cation-exchange membranes. J. Membr. Sci. 216, 39 (2003).

    Article  CAS  Google Scholar 

  26. R. Guan, H. Zou, D. Lu, C. Gong, and Y. Liu: Polyethersulfone sulfonated by chlorosulfonic acid and its membrane characteristics. Eur. Polym. J. 41, 1554 (2005).

    Article  CAS  Google Scholar 

  27. W. Zhao, Q. Mou, X. Zhang, J. Shi, S. Sun, and C. Zhao: Preparation and characterization of sulfonated polyethersulfone membranes by a facile approach. Eur. Polym. J. 49, 738 (2013).

    Article  CAS  Google Scholar 

  28. Y. Gao, G.P. Robertson, M.D. Guiver, and X. Jian: Synthesis and characterization of sulfonated poly (phthalazinone ether ketone) for proton exchange membrane materials. J. Polym. Sci. Pol. Chem. 41, 497 (2003).

    Article  CAS  Google Scholar 

  29. R. Nolte, K. Ledjeff, M. Bauer, and R. Mülhaupt: Partially sulfonated poly (arylene ether sulfone)-A versatile proton conducting membrane material for modern energy conversion technologies. J. Membr. Sci. 83, 211 (1993).

    Article  CAS  Google Scholar 

  30. P. Daraei, S.S. Madaeni, N. Ghaemi, M.A. Khadivi, B. Astinchap, and R. Moradian: Fouling resistant mixed matrix polyethersulfone membranes blended with magnetic nanoparticles: Study of magnetic field induced casting. Sep. Purif. Technol. 109, 111 (2013).

    Article  CAS  Google Scholar 

  31. G. Arthanareeswaran, T.K. Sriyamuna Devi, and M. Raajenthiren: Effect of silica particles on cellulose acetate blend ultrafiltration membranes: Part I. Sep. Purif. Technol. 64, 38 (2008).

    Article  CAS  Google Scholar 

  32. V. Vatanpour, S.S. Madaeni, R. Moradian, S. Zinadini, and B. Astinchap: Novel antibifouling nanofiltration polyethersulfone membrane fabricated from embedding TiO2 coated multiwalled carbon nanotubes. Sep. Purif. Technol. 90, 69 (2012).

    Article  CAS  Google Scholar 

  33. J. Pieracci, J.V. Crivello, and G. Belfort: Increasing membrane permeability of UV-modified poly (ether sulfone) ultrafiltration membranes. J. Membr. Sci. 202, 1 (2002).

    Article  CAS  Google Scholar 

  34. J. Lawrence and T. Yamaguchi: The degradation mechanism of sulfonated poly (arylene ether sulfone)s in an oxidative environment. J. Membr. Sci. 325, 633 (2008).

    Article  CAS  Google Scholar 

  35. V.N. Kuleznev, O.L. Melnikova, and V.D. Klykova: Dependence of modulus and viscosity upon composition for mixtures of polymers. Effects of phase composition and properties of phases. Eur. Polym. J. 14, 455 (1978).

    Article  CAS  Google Scholar 

  36. Y.P. Singh and R.P. Singh: Compatibility studies on solutions of polymer blends by viscometric and ultrasonic techniques. Eur. Polym. J. 19, 535 (1983).

    Article  CAS  Google Scholar 

  37. Y. Li: Research of Solution Blending in Modification of PVDF Membrane (Donghua University, Shanghai, China, 2012).

    Google Scholar 

  38. C. Mu, Y. Su, M. Sun, W. Chen, and Z. Jiang: Remarkable improvement of the performance of poly (vinylidene fluoride) microfiltration membranes by the additive of cellulose acetate. J. Membr. Sci. 350, 293 (2010).

    Article  CAS  Google Scholar 

  39. Y. Su, C. Li, W. Zhao, Q. Shi, H. Wang, Z. Jiang, and S. Zhu: Modification of polyethersulfone ultrafiltration membranes with phosphorylcholine copolymer can remarkably improve the antifouling and permeation properties. J. Membr. Sci. 332, 171 (2008).

    Article  CAS  Google Scholar 

  40. V. Vatanpour, S.S. Madaeni, L. Rajabi, S. Zinadini, and A.A. Derakhshan: Boehmite nanoparticles as a new nanofiller for preparation of antifouling mixed matrix membranes. J. Membr. Sci. 401, 132 (2012).

    Article  CAS  Google Scholar 

  41. K. Ishihara: Bioinspired phospholipid polymer biomaterials for making high performance artificial organs. Sci. Technol. Adv. Mat. 1, 131 (2000).

    Article  CAS  Google Scholar 

  42. J.R. Lu, E.F. Murphy, T.J. Su, A.L. Lewis, P.W. Stratford, and S.K. Satija: Reduced protein adsorption on the surface of a chemically grafted phospholipid monolayer. Langmuir 17, 3382 (2001).

    Article  CAS  Google Scholar 

  43. V. Kochkodan and N.A. Hilal: comprehensive review on surface modified polymer membranes for biofouling mitigation. Desalination 356, 187 (2015).

    Article  CAS  Google Scholar 

  44. A. Al-Amoudi and R.W. Lovitt: Fouling strategies and the cleaning system of NF membranes and factors affecting cleaning efficiency. J. Membr. Sci. 303, 4 (2007).

    Article  CAS  Google Scholar 

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Jiang, S., Wang, J., Wu, J. et al. Ultrafiltration performance and fouling resistance of PVB/SPES blend membranes with different degree of sulfonation. Journal of Materials Research 30, 2688–2701 (2015). https://doi.org/10.1557/jmr.2015.234

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