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Synthesis of submicrometer-sized TiC particles in aluminum melt at low melting temperature

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Abstract

This research discussed how to synthesize submicrometer-sized TiC particulate reinforcement in the molten aluminum melt at low temperature via combustion synthesis by using in situ casting technique. A high temperature preheating treatment of Al–Ti–C pellets was carried out, by which the thermal explosion reaction of the pellets could take place in the pure aluminum melt at 750 °C. The synthesizing temperature of TiC particles was reduced by at least 150 °C compared with the conventional methods. In situ formed TiC particles were spherical in shape and were smaller than 1 µm in size due to the low melting temperature. The emergence of liquid aluminum phase led to the generation and accumulation of plenty of heat in the pellet in a short time due to the reactive diffusion of Al(l)–Ti(s). The formation mechanism of the submicrometer-sized TiC particles in the molten aluminum at low temperature was discussed in this research.

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References

  1. Y.F. Sun, Y.Z. Lyu, A.R. Jiang, and J.Y. Zhao: Fabrication and characterization of aluminum matrix fly ash cenosphere composites using different stir casting routes. J. Mater. Res. 29, 260–266 (2014).

    Article  CAS  Google Scholar 

  2. S. Sheibani and F.M. Najafabadi: In situ fabrication of Al–TiC metal matrix composites by reactive slag process. Mater. Des. 28, 2373–2378 (2007).

    Article  CAS  Google Scholar 

  3. H. Kaftelen, N. Ünlü, G. Göller, M.L. Öveçoğlu, and H. Henein: Comparative processing-structure–property studies of Al–Cu matrix composites reinforced with TiC particulates. Composites, Part A 42, 812–824 (2011).

    Article  Google Scholar 

  4. P.J. Li, E.G. Kandalova, and V.I. Nikitin: Preparation of Al-TiC composites by self-propagating high-temperature synthesis. Scr. Mater. 49, 699–703 (2003).

    Article  CAS  Google Scholar 

  5. Z.Y. Yu, N.Q. Zhao, E.Z. Liu, C.S. Shi, X.W. Du, and J. Wang: Fabrication of aluminum matrix composites with enhanced mechanical properties reinforced by in situ generated MgAl2O4 whiskers. Composites Part A 43, 631–634 (2012).

    Article  CAS  Google Scholar 

  6. P.J. Li, E.G. Kandalova, and V.I. Nikitin: In situ synthesis of Al–TiC in aluminum melt. Mater. Lett. 59, 2545–2548 (2005).

    Article  CAS  Google Scholar 

  7. Y.F. Liang, J.E. Zhou, and S.Q. Dong: Microstructure and tensile properties of in situ TiCp/Al–4.5 wt.% Cu composites obtained by direct reaction synthesis. Mater. Sci. Eng. A 527, 7955–7960 (2010).

    Article  Google Scholar 

  8. V. Anandakrishnan, S. Baskaran, and S. Sathish: Synthesis and forming behavior of in-situ AA 7075-TiC composites. Adv. Mater. Res. 651, 251–256 (2013).

    Article  Google Scholar 

  9. Y.F. Hou, T.D. Xia, and W.J. Zhao: Effect of molten aluminum temperature on microstructure of Al-Ti-C master alloys prepared by thermal explosion synthesis. J. Mater. Eng. 6, 44–47 (2008).

    Google Scholar 

  10. Z.W. Liu, X.M. Wang, Q.Y. Han, and J.G. Li: Effects of the addition of Ti powders on the microstructure and mechanical properties of A356 alloy. Powder Technol. 253, 751–756 (2014).

    Article  CAS  Google Scholar 

  11. D.L. Ye and J.H. Hu: Handbook of Thermodynamic Data of Inorganic Compounds, 2nd ed. (Metallurgical Industry Press, Beijing, 2002).

    Google Scholar 

  12. H.Y. Wang, Q.C. Jiang, X.L. Li, and J.G. Wang. In situ synthesis of TiC/Mg composites in molten magnesium. Scr. Mater. 48, 1349–1354 (2003).

    Article  CAS  Google Scholar 

  13. L. Xu, Y.Y. Cui, L.Y. Hao, and R. Yang: Growth of intermetallic layer in multi-laminated Ti/Al diffusion couples. Mater. Sci. Eng. A 435–436, 638–647 (2006).

    Article  Google Scholar 

  14. Z.W. Liu, M. Rakita, Q.Y. Han, and J.G. Li: A developed method for fabricating in-situ TiCp/Mg composites by using quick preheating treatment and ultrasonic vibration. Metall. Mater. Trans. A 43, 2116–2124 (2012).

    Article  CAS  Google Scholar 

  15. I. Krafcsik, J. Gyulai, C.J. Palmstrom, and J.W. Mayer: Influence of Cu as an impurity in Al/Ti and Al/W thin-film reactions. Appl. Phys. Lett. 43, 1015–1017 (1983).

    Article  CAS  Google Scholar 

  16. J. Kral, M. Ferdinandy, and D. Liska: Formation of TiAl3 layer on titanium alloys. Mater. Sci. Eng. A 140, 479–485 (1991).

    Article  Google Scholar 

  17. Y. Du, Y.A. Chang, B.Y. Huang, W.P. Gong, Z.P. Jin, H.H. Xu, Z.H. Yuan, Y. Liu, Y.H. He, and F.Y. Xie: Diffusion coefficients of some solutes in fcc and liquid Al: Critical evaluation and correlation. Mater. Sci. Eng. A 363, 140–151 (2003).

    Article  Google Scholar 

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ACKNOWLEDGMENTS

This research was supported by the US Department of Energy under Award Number DE-EE0001100, the North American Die Casting Association, and the China Scholarship Council of the Chinese Ministry of Education.

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Authors and Affiliations

  1. Purdue University, West Lafayette, Indiana, 47906, USA

    Zhiwei Liu, Xiaoming Wang & Qingyou Han

  2. School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China

    Jianguo Li

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  1. Zhiwei Liu
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  2. Xiaoming Wang
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  3. Qingyou Han
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  4. Jianguo Li
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Correspondence to Zhiwei Liu or Qingyou Han.

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Liu, Z., Wang, X., Han, Q. et al. Synthesis of submicrometer-sized TiC particles in aluminum melt at low melting temperature. Journal of Materials Research 29, 896–901 (2014). https://doi.org/10.1557/jmr.2014.56

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