Skip to main content
Log in

Effects of aging on shape memory and wear resistance of a Fe–Mn–Si-based alloy

  • Article
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

The influence of aging treatment on shape memory effect (SME) and wear resistance of Fe–20Mn–5Si–10Cr–5Ni–0.7V–0.2N (mass%) alloy was investigated. Results showed that vanadium nitride (VN) particles precipitated during aging treatment, and the amount and size of the particles increased with increasing aging time. The sample aged for 8 h exhibited the maximal shape recovery ratio of 74% (compared with that of 16% for unaged) and favorable wear resistance in both dry wear and oil-lubricant wear conditions. The fine VN particles are the key factor to improve the SME by strengthening the alloy and acting as preferential nucleation sites for martensite. However, more and larger particles due to further aging treatment appeared to have negative effects on the SME and wear resistance. After oil-lubricant friction, there existed large amounts of friction-stress-induced ε martensite in the worn surface of the sample. As a result, the wear resistance of samples in oil-lubricant wear condition was remarkably higher than that in dry wear condition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

FIG. 1
FIG. 2
FIG. 3
FIG. 4
FIG. 5
FIG. 6
FIG. 7
FIG. 8
FIG. 9

Similar content being viewed by others

References

  1. A. Sato, K. Soma, and T. Mori: Shape memory effect in γ⇄ϵ transformation in Fe-30Mn-1Si alloy single crystals. Acta Metall. 30(6), 1171 (1982).

    Article  Google Scholar 

  2. A. Sato and T. Mori: Development of a shape memory alloy Fe–Mn–Si. Mater. Sci. Eng., A 146(1–2), 197 (1991).

    Article  Google Scholar 

  3. H. Inagaki: Shape memory effect of Fe-14 % Mn-6 % Si-9 % Cr-6 % Ni alloy polycrystals. Z. Metallkd. 83, 90 (1992).

    CAS  Google Scholar 

  4. Z.D. Liu, S. Kajiwara, T. Kikuchi, N. Shinya, D.F. Wang, and W.X. Liu: Mechanism of the improvement of the shape memory effect by “Training” and ausforming in Fe-Mn-Si based shape memory alloys. Mater. Trans. 41(5), 593 (2000).

    Article  CAS  Google Scholar 

  5. T. Kırındıa, U. Sarı, and M. Dikici: The effects of pre-strain, recovery temperature, and bending deformation on shape memory effect in an Fe–Mn–Si–Cr–Ni alloy. J. Alloys Compd. 475(1–2), 145 (2009).

    Article  Google Scholar 

  6. A. Baruj, T. Kikuchi, S. Kajiwara, and N. Shinya: Improvement of shape memory properties of NbC containing Fe–Mn–Si based shape memory alloys by simple thermomechanical treatments. Mater. Sci. Eng., A 378(1–2), 333 (2004).

    Article  Google Scholar 

  7. Z.Z. Dong, S. Kajiwara, T. Kikuchi, and T. Sawaguchi: Effect of pre-deformation at room temperature on shape memory properties of stainless type Fe–15Mn–5Si–9Cr–5Ni–(0.5–1.5)NbC alloys. Acta Metall. 53(15), 4009 (2005).

    CAS  Google Scholar 

  8. W.B. Liu, Y.H. Wen, N. Li, and S.Z. Yang: Further improvement of shape memory effect in a pre-deformed Fe–Mn–Si–Cr–Ni–Nb–C alloy by smaller NbC precipitated through electropulsing treatment. J. Alloys Compd. 472(1–2), 591 (2009).

    Article  CAS  Google Scholar 

  9. S. Farjami, K. Hiraga, and H. Kubo: Crystallography and elastic energy analysis of VN precipitates in Fe–Mn–Si–Cr shape memory alloys. Acta Mater. 53(2), 419 (2005).

    Article  CAS  Google Scholar 

  10. H. Kubo, K. Nakamura, S. Farjami, and T. Maruyama: Characterization of Fe–Mn–Si–Cr shape memory alloys containing VN precipitates. Mater. Sci. Eng., A 378(1–2), 343 (2004).

    Article  Google Scholar 

  11. Z.Z. Dong, U.E. Klotz, and C. Leinenbach: A novel Fe-Mn-Si shape memory alloy with improved shape recovery properties by VC precipitation. Adv. Eng. Mater. 11(1–2), 40 (2009).

    Article  CAS  Google Scholar 

  12. Y.H. Wen, L.R. Xiong, N. Li, and W. Zhang: Remarkable improvement of shape memory effect in an Fe–Mn–Si–Cr–Ni–C alloy through controlling precipitation direction of Cr23C6. Mater. Sci. Eng., A 474(1–2), 60 (2008).

    Article  Google Scholar 

  13. H.B. Peng, Y.H. Wen, B.B. Ye, and N. Li: Influence of ageing after pre-deformation on shape memory effect in a FeMnSiCrNiC alloy with 13 wt.% Cr content. Mater. Sci. Eng., A 504(1–2), 36 (2009).

    Article  Google Scholar 

  14. D.X. Bu, H.B. Peng, Y.H. Wen, and N. Li: Influence of ageing on wear resistance of an Fe–Mn–Si–Cr–Ni–Ti–C shape memory alloy. Mater. Des. 32(5), 2969 (2011).

    Article  CAS  Google Scholar 

  15. C.X. Lin, G.X. Wang, Y.D. Wu, J.G. Wang, and J.J. Zhang: Analysis of wear resistance and its mechanism in an Fe–Mn–Si–Cr–Ni shape memory alloy. Mater. Sci. Eng., A 438, 804 (2006).

    Google Scholar 

  16. S. Kajiwara: Characteristic features of shape memory effect and related transformation behavior in Fe-based alloys. Mater. Sci. Eng., A 273, 67 (1999).

    Article  Google Scholar 

  17. J.J. Ye, Z.W. Lai, Y.H. Wen, and N. Li: Wear characteristics of a new type austenitic stainless steel. J. Mater. Sci. 45(3), 701 (2010).

    Article  CAS  Google Scholar 

  18. Z.F. Ni, Y.S. Sun, F. Xue, J. Zhou, and J. Bai: Evaluation of electroslag remelting in TiC particle reinforced 304 stainless steel. Mater. Sci. Eng., A 528(18), 5664 (2011).

    Article  CAS  Google Scholar 

  19. K. Yang, S.F. Yu, Y.B. Li, and C.L. Li: Effect of carbonitride precipitates on the abrasive wear behaviour of hardfacing alloy. Appl. Surf. Sci. 254(16), 5023 (2008).

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors are grateful to the Natural Science Foundation of Tianjin City (No. 13JCZDJC31900), the China National Funds for Distinguished Young Scientists (No. 51325401), the International Thermonuclear Experimental Reactor (ITER) Program Special Project (No. 2014GB125006), and the Major State Basic Research Development Program (973 Program No. 2014CB046805) for grant and financial support.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Zhizhong Dong or Liming Yu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, Y., Dong, Z., Yu, L. et al. Effects of aging on shape memory and wear resistance of a Fe–Mn–Si-based alloy. Journal of Materials Research 29, 2809–2816 (2014). https://doi.org/10.1557/jmr.2014.344

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/jmr.2014.344

Navigation