Skip to main content
SpringerLink
Log in

The corrosion and oxidation behavior of Zr-based metallic glasses

  • Article
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Zr-based bulk metallic glasses are promising engineering materials due to their good glass-forming abilities and unique combination of good strength (∼1.9 GPa) and medium stiffness. In this study, the corrosion behaviors of Zr-Co-Al-Ag BMGs, with silver content from 0 to 11 at.%, in NaCl and H2SO4 solutions were investigated. The corrosion resistance increased when the silver content increased. The oxidation behaviors of Zr-Co-Al-Ag BMGs were also studied. The oxidation kinetics of all the samples obeyed a two-stage parabolic rate law, which consisted of an initial transient oxidation followed by a steady-state oxidation stage. The addition of Ag was found to reduce the oxidation resistance of Zr-Co-Al-Ag BMGs. Some white nodules, possibly cobalt oxide, were observed when the Zr-Co-Al-Ag BMG with 8 at.% Ag was oxidized at high temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

FIG. 1
FIG. 2
FIG. 3
FIG. 4
FIG. 5
FIG. 6
FIG. 7

Similar content being viewed by others

Explore related subjects

Discover the latest articles, news and stories from top researchers in related subjects.

References

  1. C. Suryanarayana and A. Inoue: Bulk Metallic Glasses (CRC Press Inc, Boca Raton, 2010), pp. 307, 353, 383.

    Book  Google Scholar 

  2. C. Zhang, N. Li, J. Pan, S.F. Guo, M. Zhang, and L. Liu: Enhancement of glasses-forming ability and bio-corrosion resistance of Zr-Co-Al bulk metallic glasses by the addition of Ag. J. Alloys Compd. 504S, 163 (2010).

    Article  Google Scholar 

  3. K.F. Jin and J.F. Löffler: Bulk metallic glass formation in Zr–Cu–Fe–Al alloys. Appl. Phys. Lett. 86, 241909 (2005).

    Article  Google Scholar 

  4. L. Liu, C.L. Qiu, M. Suna, Q. Chen, K.C. Chan, and G.K.H. Pang: Improvements in the plasticity and biocompatibility of Zr–Cu–Ni–Al bulk metallic glass by the microalloying of Nb. Mater. Sci. Eng., A 449–451, 193 (2007).

    Article  Google Scholar 

  5. J.G. Wang, B.W. Choi, T.G. Nieh, and C.T. Liu: Nano-scratch behavior of a bulk Zr–10Al–5Ti–17.9Cu–14.6Ni amorphous alloy. J. Mater. Res. 15, 913 (2000).

    Article  CAS  Google Scholar 

  6. Q.K. Jiang, X.P. Nie, Y.G. Li, Y. Jin, Z.Y. Chang, X.M. Huang, and J.Z. Jiang: Ni-free Zr-based bulk metallic glasses with critical diameter above 20 mm. J. Alloys Compd. 443, 191 (2007).

    Article  CAS  Google Scholar 

  7. X.F. Zhang, Y.M. Wang, J.B. Qiang, Q. Wang, D.H. Wang, D.J. Li, C.H. Shek, and C. Dong: Optimum Zr–Al–Co bulk metallic glass composition Zr53Al23.5Co23.5. Intermetallics 12, 1275 (2004).

    Article  CAS  Google Scholar 

  8. T. Zhang and A. Inoue: Formation, thermal and mechanical properties of bulk glassy alloys in Zr–Al–Co and Zr–Al–Co–Cu systems. Mater. Sci. Eng., A 375, 432 (2004).

    Article  Google Scholar 

  9. T. Zhang and A. Inoue: New glassy Zr-Al-Fe and Zr-Al-Co alloys with a large supercooled liquid region. Mater. Trans. 43, 267 (2002).

    Article  CAS  Google Scholar 

  10. T. Wada, T. Zhang, and A. Inoue: Formation, thermal stability and mechanical properties in Zr-Al-Co bulk glassy alloys. Mater. Trans. 43, 2843 (2002).

    Article  CAS  Google Scholar 

  11. S.J. Pang, T. Zhang, K. Asami, and A. Inoue: Formation, corrosion behavior, and mechanical properties of bulk glassy Zr-Al-Co-Nb alloys. J. Mater. Res. 18, 1652 (2003).

    Article  CAS  Google Scholar 

  12. T. Wada, F.X. Qin, X.M. Wang, M. Yoshimura, A. Inoue, N. Sugiyama, R. Ito, and N. Matsushita: Formation and bioactivation of Zr-Al-Co bulk metallic glasses. J. Mater. Res. 24, 2941 (2009).

    Article  CAS  Google Scholar 

  13. N. Hua, S. Pang, Y. Li, J. Wang, R. Li, K. Georgarakis, A.R. Yavari, G. Vaughan, and T. Zhang: Ni-and Cu-free Zr–Al–Co–Ag bulk metallic glasses with superior glass-forming ability. J. Mater. Res. 26, 539 (2011).

    Article  CAS  Google Scholar 

  14. W.H. Cao, J.L. Zhang, and C.H. Shek: Oxidation behavior of Zr56Co28Al16 bulk metallic glasses. Corros. Sci. 65, 528 (2012).

    Article  CAS  Google Scholar 

  15. F.L.S. Carvalho, C.S. Borges, J.R.T Branco, and M.M. Pereira: Structure analysis of hydroxyapatite/bioactive glass composite coatings obtained by plasma spray processing. J. Non-Cryst. Solids 247, 64 (1999).

    Article  CAS  Google Scholar 

  16. E. Verne, M. Ferraris, A. Ventrella, L. Paracchini, A. Krajewski, and A. Ravaglioli: Sintering and plasma spray deposition of bioactive glass-matrix composites for medical applications. J. Eur. Ceram. Soc. 18, 363 (1998).

    Article  CAS  Google Scholar 

  17. X.P. Nie, X.H. Yang, L.Y. Chen, K.B. Yeap, K.Y. Zeng, D. Li, J.S. Pan, X.D. Wang, Q.P. Cao, S.Q. Ding, and J.Z. Jiang: The effect of oxidation on the corrosion resistance and mechanical properties of a Zr-based metallic glass. Corros. Sci. 53, 3557 (2011).

    Article  CAS  Google Scholar 

  18. X.P. Nie, X.H. Yang, Y. Ma, L.Y. Chen, K.B. Yeap, K.Y. Zeng, D. Li, J.S. Pan, X.D. Wang, Q.P. Cao, S.Q. Ding, and J.Z. Jiang: Thermal oxidation effect on corrosion behavior of Zr46Cu37.5Ag8.4Al8 bulk metallic glass. Intermetallics 22, 84 (2012).

    Article  CAS  Google Scholar 

  19. P.J. Tao, Y.Z. Yang, X.J. Bai, Z.X. Mu, G.Q. Li, Z.W. Xie, and X.C. Chen: Study on implantation of Co ions in ZrCuNiAl bulk metallic glasses. Surf. Coat. Technol. 203, 1656 (2009).

    Article  CAS  Google Scholar 

  20. P.J. Tao, Y.Z. Yang, Z.X. Mu, X.C. Chen, and Z.W. Xie: Influences of ion implantation on non-isothermal crystallization behaviors of bulk metallic glasses. J. Alloys Compd. 479, 736 (2009).

    Article  CAS  Google Scholar 

  21. A. Basu, A.N. Samant, S.P. Harimkar, J. Dutta Majumdar, I. Manna, and B. Narendra Dahotre: Laser surface coating of Fe-Cr-Mo-Y-B-C bulk metallic glass composition on AISI 4140 steel. Surf. Coat. Technol. 202, 2623 (2008).

    Article  CAS  Google Scholar 

  22. M. Riahi: Surface treatment of cast iron by adding different alloying elements to form a metallic glass structure layer using an industrial carbon dioxide laser. J. Mater. Process. Technol. 58, 3 (1996).

    Article  Google Scholar 

  23. P. Vanysek: Handbook of Chemistry and Physics, 88th ed. (CRC Press Inc, Boca Raton, 2007).

    Google Scholar 

  24. U. Kamachi Mudali, S. Baunack, J. Eckert, L. Schultz, and A. Gebert: Pitting corrosion of bulk glass-forming zirconium-based alloys. J. Alloys Compd. 377, 290 (2004).

    Article  CAS  Google Scholar 

  25. C.L. Qin, J.J. Oak, N. Ohtsu, K. Asami, and A. Inoue: XPS study on the surface films of a newly designed Ni-free Ti-based bulk metallic glass. Acta Mater. 55, 2057 (2007).

    Article  CAS  Google Scholar 

  26. C.L. Qin, Y.Q. Zeng, D.V. Louzguine, N. Nishiyama, and A. Inoue: Corrosion resistance and XPS studies of Ni-rich Ni–Pd–P–B bulk glassy alloys. J. Alloys Compd. 504S, S172–S175 (2010).

    Article  Google Scholar 

  27. G.C. Palit and K. Elayaperumal: Passivity and pitting of corrosion resistant pure metals Ta, Nb, Ti, Zr, Cr and Al in chloride solutions. Corros. Sci. 18, 169 (1978).

    Article  CAS  Google Scholar 

  28. N. Hua, L. Huang, J. Wang, Y. Cao, W. He, S. Pang, and T. Zhang: Corrosion behavior and in vitro biocompatibility of Zr–Al–Co–Ag bulk metallic glasses: An experimental case study. J. Non-Cryst. Solids 358, 1599 (2012).

    Article  CAS  Google Scholar 

  29. D.R. Gaskell: Introduction to the Thermodynamics of Materials, 4th ed. (Taylor and Francis, New York, 2003), p. 584.

    Google Scholar 

  30. W. Kai, I.F. Ren, P.C. Kao, R.F. Wang, C.P. Chuang, M.W. Freels, and P.K. Liaw: Air-Oxidation of a Cu45Zr45Al5Ag5 bulk metallic glass. Adv. Eng. Mater. 11, 380 (2009).

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENT

The work presented in this paper was supported by a General Research Fund (Project number: CityU 120813) from Research Grants Council, Hong Kong SAR Government.

Author information

Authors and Affiliations

  1. Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong, Hong Kong, 999077, China

    Yonglong Hu, Wenhuan Cao & Chanhung Shek

Authors
  1. Yonglong Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wenhuan Cao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chanhung Shek
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yonglong Hu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hu, Y., Cao, W. & Shek, C. The corrosion and oxidation behavior of Zr-based metallic glasses. Journal of Materials Research 29, 1248–1255 (2014). https://doi.org/10.1557/jmr.2014.107

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/jmr.2014.107

Search

Navigation