Abstract
Carbon-bonded alumina filters for steel melt filtration are increasingly used by industries. Their potential regarding the material characteristics and the filtration efficiency appears, however, not used in full measure up to now. In the course of the present work, a new approach, due to the application of active oxide coatings, whose chemical phase equates to that of the nonmetallic oxidic inclusions in the steel melt, was created. The main emphasis consists of the generation of cold-applied, active alumina, spinel, and mullite coatings. Coatings have been developed due to the variation of sintering temperatures and a thermal pretreatment, which lead to increasing cold crushing strength. A basic understanding regarding the adhesion and the interface between the oxide coating and the carbon-bonded filter substrate has been created. Therefore, the essential factor is traceable back to thermal-related mechanisms.
Similar content being viewed by others
References
D. Janke and K. Raiber: Grundlegende Untersuchungen zur Optimierung der Filtration von Stahlschmelzen. Technische Forschung Stahl (Europäische Kommission, Luxembourg, 1996) ISBN 92-827-6458-3.
H-J. Bargel; G. Schulze: Eisenwerkstoffe. Werkstoffkunde (Springer-Verlag, Berlin Heidelberg New York, 2005) ISBN 3-540-26107-9.
H. Jacobi: The process metallurgy and materials engineering of steel with high purity and cleanness. In Feuerfeste Werkstoffe und Systeme für die Erzeugung hochreiner Stähle, Pro-ceedings of XXXVII. Internationales Feuerfest-Kolloquium, Stahl und Eisen Special 1994, 1994; pp. 5–16.
S. Ovtchinnikov: Kontrollierte Erstarrung und Einschlussbildung bei der Desoxidation von hochreinen Stahlschmelzen (TU Bergakademie Freiberg, Germany Diss., 2002).
K. Wasai, K. Mukai, and A. Miyanaga: Observation of inclusion in aluminum deoxidized iron. ISIJ Int. 42(5), 459–466 (2002).
A. Adams and T. Tackaberry: Ceramic filters for ductile iron filtration - your last chance to trap inclusions. Ductile Iron News 3, 1994, pp. 3–8.
E.I. Mogilevskii and V.I. Burtsev: Production technology and tests of ceramic filters for refining precision alloys. Refract. Ind. Ceram. 41, 28–30 (2000).
C.G. Aneziris, A. Ansorge, and H. Jaunich: New approaches of carbon bonded foam filters for filtration of large castings. Ceramic Forum International Special Refractories for Clean Steel Technology 85(10), E100–E103 (2008).
M. Hasterok, C. Wenzel, C.G. Aneziris, U. Ballaschk, and H. Berek: Processing of ceramic preforms for TRIP-matrix-composites. Steel Res. Int. 82(9), 1032–1039 (2011).
R.A. Olson III and L.C.B. Martins: Cellular ceramics in metal filtration. Adv. Eng. Mat. 7(4), 187–192 (2005).
P. Hammerschmid and D. Janke: Kenntnisstand zur Abscheidung von Einschlüssen beim Filtrieren von Stahlschmelzen. Stahl und Eisen 108(5), 211–219 (1988).
P. Hammerschmid, K. Raiber, and D. Janke: Abscheidung von Tonerdeeinschlüssen aus Stahl- und Nickel-Basis-Schmelzen mit keramischen Filtern. Konferenz-Einzelbericht: Stahl und Eisen, Special 1994 (1994); pp. 58–64.
R.D. Morales, O. Davila-Maldonado, A. Adams, L. Oliveira, and B. Alquist: Computer and fluid flow modeling of filtration mechanisms in foam filters. AFS Trans. 116, 715–731 (2008).
K. Uemura, M. Takahashi, S. Koyama, and M. Nitta: Filtration mechanism of non-metallic inclusions in steel by ceramic loop filter. ISIJ Int. 32, 150–156 (1992).
K. Janiszewski and Z. Kudlinski: Removal of liquid non-metallic inclusion from molten steel using the method filtration. Metal 1–9 (2006)
C.G. Aneziris, S. Dudczig, J. Hubálková, M. Emmel, and G. Schmidt: Alumina coatings on carbon bonded alumina nozzles for active filtration of steel melts. Ceram. Int. 39(3), 2835–2843 (2013).
O. Davila-Maldonaldo, A. Adams, L. Oliveira, B. Alquist, and R.D. Morales: Simulation of fluid and inclusions dynamics during filtration operations of ductile iron melts using foam filters. Metall. Mater. Trans. B 39(6), 818–839 (2008).
M. Emmel and C.G. Aneziris: Development of novel carbon bonded filter compositions for steel filtration. Ceram. Int. 38(6), 5165–5172 (2012).
U. Fischer: Optimierte Auftragsverfahren in der Spritzglasiertechnologie. Freiberger Forschungshefte A897 (Freiberg, 2009) ISBN 978-3-86012-368-3.
Acknowledgments
The authors would like to thank the German Research Foundation (DFG) for supporting these investigations through the Collaborative Research Centre 920 “Multi-Functional Filters for Metal Melt Filtration—A Contribution towards Zero Defect Materials”, Subproject A01, Mrs. Jana Hubálková for the CT measurements, and Mr. Gert Schmidt for the SEM images.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Emmel, M., Aneziris, C.G. Functionalization of carbon-bonded alumina filters through the application of active oxide coatings for steel melt filtration. Journal of Materials Research 28, 2234–2242 (2013). https://doi.org/10.1557/jmr.2013.56
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/jmr.2013.56