Abstract
A bismuth telluride alloy-based thermoelectric generator with high-aspect ratio, free-standing legs was fabricated. Such legs are desirable for efficient generator performance from low-grade heat sources but are difficult to assemble because they are fragile and difficult to handle and position. Plunge and wire electro-discharge machining (EDM) were used to produce 150 μm × 300 μm legs, approximately 6-mm long, with high fidelity. Removal of recast material from EDM was necessary for good adhesion of metallization, but sputter etching was found to deteriorate the mechanical strength of the contacts. A wet chemical cleaning process was developed instead that resulted in good adhesion under test conditions. Au was preferred for designs where interconnects could be patterned directly on the module. Module figure of merit (ZT) was 0.72, close to the 0.85 value expected from bulk material property measurements. Impedance spectroscopy and the Harman technique were shown to significantly underestimate module ZT in the present test configuration. Shear and fatigue testing were performed on arrays of high-aspect ratio legs. Legs survived over 104 cycles of shear loading at 90% of the load to failure.
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Sandia National Laboratories is a multiprogram laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy’s National Nuclear Security Administration under Contract DE-AC04-94AL85000.
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Wesolowski, D.E., Goeke, R.S., Morales, A.M. et al. Development of a Bi2Te3-based thermoelectric generator with high-aspect ratio, free-standing legs. Journal of Materials Research 27, 1149–1156 (2012). https://doi.org/10.1557/jmr.2012.27
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DOI: https://doi.org/10.1557/jmr.2012.27