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Structural and morphological characteristics of yttrium and lutetium orthoborates synthesized in thin layers of borate oxide glasses

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Abstract

We propose a new method of synthesis of crystalline yttrium and lutetium orthoborates in thin (2.5–20.0 μm thick) layers of molten borate oxide glasses. The method is based on interaction of nanosized lutetium and yttrium oxide powders with boron anhydride in the melt. X-ray diffractometry and electron microscopy investigations have revealed that in the case of lead-content glasses, the method shows a very strong orienting effect in the texture of the resulting orthoborate particles. This highly oriented texture results in good transparency of the obtained glass–ceramic films. Studies of the luminescence and scintillation spectra of the glass–ceramic composites show that they can be used as highly effective phosphors with a light yield comparable to that of single crystalline scintillators.

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References

  1. A.C. Vaz de Araujo, I.T. Weber, B.S. Santos, B.J.P. de Silva, R.P. de Mello Jr., S. Alves Jr., G.F. de Sa, and C. de Mello Donega: Spectroscopy and crystallization behavior of Eu 33+-doped La2O3:B2O3 binary glasses. J. Non-Cryst. Solids 219, 160 (1997).

    Article  CAS  Google Scholar 

  2. V. MacFarlane, J. Javorniczky, P.J. Newman, and D.J. Booth: Enhanced fluorescence from nano-crystallized erbium-doped fluoroaluminate glasses. J. Non-Cryst. Solids 256, 366 (1999).

    Article  Google Scholar 

  3. P.A. Tick, N.F. Borrelli, and I.M. Reaney: The relationship between structure and transparency in glass-ceramic materials. Opt. Mater. 15, 81 (2000).

    Article  CAS  Google Scholar 

  4. I.V. Bondar’, V.S. Gurin, A.P. Molochko, N.P. Solovey, P.V. Prokoshin, and K.V. Yumashev: Optical properties of ultra dispersed crystallites CdSexTe1–x (0 ≤ x ≤ 1) in silicate glass matrix. Semiconductors 36, 317 (2002).

    Google Scholar 

  5. O.P. Thakur, D. Kumar, O. Parkash, and L. Pandey: Crystallization, microstructure development and dielectric behavior of glass ceramics in the system [SrO·TiO2]–[2SiO2·B2O3]–La2O3. J. Mater. Sci. 37, 2597 (2002).

    Article  CAS  Google Scholar 

  6. B.I. Zadneprovskiy, V.V. Sosnovtsev, D.G. Permenov, A.A. Meotishvili, and G.I. Voronova: Luminescent and scintillation characteristics submicron powders of LuBO3:Ce3+ and the films on their base. JTPh Letters 35, 64 (2009).

    Google Scholar 

  7. V.P. Danilov: Rare Earth Compounds. Systems with Elements of I-III Groups (NAUKA Press, Moscow, Russia, 1983) p. 296.

    Google Scholar 

  8. M.V. Korzhik: Physic of Scintillator’s Physics of Oxygen Base Single Crystals (BGU press, Minsk, Belarus, 2003) p. 263.

    Google Scholar 

  9. C. Mansuy, J.M. Nedelec, and R. Mahiou: Molecular design of inorganic scintillators: From alkoxides to scintillating materials. J. Mater. Chem. 14, 3274 (2004).

    Article  CAS  Google Scholar 

  10. K.I. Portnoy and N.I. Timofeeva: Oxygen-Containing Rare Earth Compounds (Metallurgiya Press, Moscow, Russia, 1986) p. 480.

    Google Scholar 

  11. B.F. Dzhurinskiy, I.M. Belyakov, and I.V. Tananaev: Interaction of rare earth oxides with sodium-borate melts. Bull. Acad. Sci. USSR, Phys. Ser. 3, 1876 (1967).

    Google Scholar 

  12. N.N. Vinogradova, L.N. Dmitruk, and O.B. Petrova: Vitrification and crystallization of rare earth borate glass. Glass Phys. Chem. 30, 3 (2004).

    Article  Google Scholar 

  13. Y.K. Voron’ko, S.S. Galaktionov, L.N. Dmitruk, O.B. Petrova, A.V. Popov, S.N. Ushakov, and V.E. Shukshin: Spectroscopic investigation of rare earth borate glasses. Glass Phys. Chem. 32, 1 (2006).

    Article  Google Scholar 

  14. L.N. Dmitruk, O.B. Petrova, A.V. Popov, and V.E. Shukshin: Synthesis and investigation of transparent rare earth borate glass-ceramics. In Bulletin of RAS, Proceedings of the Institute of General Physics, A.M. Prokhorov, ed. (NAUKA Press, Moscow, Russia, 64, 2008) p. 49.

    CAS  Google Scholar 

  15. E.M. Levin, C.R. Robbins, and J.L. Waring: Immiscibility and the system lanthanum oxide-boric oxide. J. Am. Ceram. Soc. 44, 87 (1961).

    Article  Google Scholar 

  16. E.M. Levin, R.S. Roth, and J.B. Martin: Polymorphism of ABO3 type rare earth borates. Am. Mineral. 46, 1030 (1961).

    CAS  Google Scholar 

  17. N. Seljakov: The x-ray method for measurement of the absolute dimensions of the individual crystallites in body from finely-granulated build (Eine roentgenographische Methode zur Messung der absoluten Dimension einzelner Kristalle in Korper von fein-kristallischem Bau). Z. Angew. Phys. 31, 439 (1925) [in German].

    Google Scholar 

  18. N.V. Klassen, S.Z. Shmurak, I.M. Shmytko, G.K. Strukova, S.E. Derenzo, and M.J. Weber: Structure and luminescence spectra of lutetium and yttrium borates synthesized from ammonium nitrate melt. Nucl. Instrum. Methods Phys. Res., Sect. A 537, 144 (2005).

    Article  CAS  Google Scholar 

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Acknowledgments

The work was supported by the Quantum Physics of Condensed Matter Research Program of the Russian Academy of Sciences (Grant No. 10.32) and RFBR Project No. 12-03-00454-a.

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Authors and Affiliations

  1. Laboratory of Spectroscopy of Defect Structures and Laboratory of Structure Analysis, Institute of Solid State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow District, Russia

    Viktor V. Kedrov, Ivan M. Shmytko, Semeon Z. Shmurak, Elena A. Kudrenko & Nikolay V. Klassen

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  1. Viktor V. Kedrov
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  2. Ivan M. Shmytko
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  3. Semeon Z. Shmurak
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  4. Elena A. Kudrenko
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Correspondence to Ivan M. Shmytko.

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Kedrov, V.V., Shmytko, I.M., Shmurak, S.Z. et al. Structural and morphological characteristics of yttrium and lutetium orthoborates synthesized in thin layers of borate oxide glasses. Journal of Materials Research 27, 2116–2121 (2012). https://doi.org/10.1557/jmr.2012.215

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  • DOI: https://doi.org/10.1557/jmr.2012.215

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