Abstract
A metal-supported solid oxide fuel cell (SOFC) using Ce0.8Sm0.2O2 (Sm-doped ceria, SDC) buffer layer and La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) electrolyte films showed a small degradation in the cell performance after a long-term operation because of La migration from the electrolyte to the buffer layer, resulted in a formation of a less conductive phase. Thus, various ceramic materials such as doped ceria and perovskite-related oxides were investigated for an effective buffer layer with respect to fabricating reliable metal-supported SOFCs using a LSGM electrolyte film. In particular, La-doped CeO2 (LDC) and Pr-doped LaCrO3 (LPCr) were investigated as buffer layer material since the materials showed chemical compatibility with the LSGM and anode materials. The cell using a LDC buffer layer showed a prior stability during the operation for 100 h at 973 K, while the power density of the cell was slightly low owing to the low electrical conductivity of LDC compared with that of SDC or LPCr. In contrast, the cell using a LPCr buffer layer revealed significantly low open circuit voltage (OCV) and power density, which were attributed to Pr decomposition in the LPCr caused by the reactivity with water vapor. However, the metal-supported cell with a multilayer electrolyte film including LSGM/LPCr/SDC layers showed an almost theoretical OCV and reasonably high power density with no degradation after a long-term operation for 100 h at 973 K, suggesting that the LPCr layer effectively prevented La migration and the SDC layer led to avoid the Pr decomposition. Thus, a LPCr is an effective buffer layer material for reliable metal-supported SOFCs using a LSGM electrolyte thin film.
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References
O. Yamamoto: Solid oxide fuel cells: Fundamental aspects and prospects. Electrochim. Acta 45, 2423 (2000).
S.C. Singhal: Solid oxide fuel cells for stationary, mobile, and military applications. Solid State Ionics 152-153, 405 (2002).
N.Q. Minh: Solid oxide fuel cell technology–features and applications. Solid State Ionics 174, 271 (2004).
H. Yahiro, Y. Baba, K. Eguchi, and H. Arai: High temperature fuel cell with ceria-yttria solid electrolyte. J. Electrochem. Soc. 135, 2077 (1988).
A.V. Virkar: Theoretical analysis of solid oxide fuel cells with two-layer, composite electrolytes: Electrolyte stability. J. Electrochem. Soc. 138, 1481 (1991).
M. Mogensen, N.M. Sammes, and G.A. Tompsett: Physical, chemical and electrochemical properties of pure and doped ceria. Solid State Ionics 129, 63 (2000).
T. Ishihara, H. Matsuda, and Y. Takita: Doped LaGaO3 perovskite type oxide as a new oxide ionic conductor. J. Am. Chem. Soc. 116, 3801 (1994).
T. Ishihara, H. Minami, H. Matsuda, H. Nishiguchi, and Y. Takita: Decreased operating temperature of solid oxide fuel cells (SOFCs) by the application of LaGaO3-based oxide as electrolyte. Chem. Commun. 8, 929 (1996).
T. Ishihara, M. Honda, T. Shibayama, H. Minami, H. Nishiguchi, and Y. Takita: Intermediate temperature solid oxide fuel cells using a new LaGaO3 based oxide ion conductor. J. Electrochem. Soc. 145, 3177 (1998).
M. Feng, J.B. Goodenough, K. Huang, and C. Milliken: Fuel cells with doped lanthanum gallate electrolyte. J. Power Sources 63, 47 (1996).
K. Huang, R. Tichy, and J.B. Goodenough: Superior perovskite oxide-ion conductor; strontium-and magnesium-doped LaGaO3: I, phase relationships and electrical properties. J. Am. Ceram. Soc. 81, 2565 (1998).
K. Huang, J.H. Wan, and J.B. Goodenough: Increasing power density of LSGM-based solid oxide fuel cells using new anode materials. J. Electrochem. Soc. 148, A788 (2001).
Z.H. Bi, B.L. Yi, W. Wang, Y.L. Dong, Y.C. Wu, Y.C. She, and M.J. Cheng: A high-performance anode-supported SOFC with LDC-LSGM bilayer electrolytes. Electrochem. Solid-State Lett. 7, A105 (2004).
D.Y. Lee, J.H. Han, E.G. Kim, R.H. Song, and D.R. Shin: Performance of strontium- and magnesium-doped lanthanum gallate electrolyte with lanthanum-doped ceria as a buffer layer for IT-SOFCs. J. Power Sources, 185, 207 (2008).
J.W. Yan, Z.G. Lu, Y. Jiang, Y.L. Dong, Y.C. Yu, and W.Z. Li: Fabrication and testing of a doped lanthanum gallate electrolyte thin-film solid oxide fuel cell. J. Electrochem. Soc. 149, A1132 (2002).
T. He, Q. He, L. Pei, and Y. Ji: Doped lanthanum gallate film solid oxide fuel cells fabricated on a Ni/YSZ anode support. J. Am. Ceram. Soc. 89, 2664 (2006).
W. Guo, J. Liu, and Y. Zhang: Electrical and stability performance of anode-supported solid oxide fuel cells with strontium- and magnesium-doped lanthanum gallate thin electrolyte. Electrochim. Acta 53, 4420 (2008).
F. Bozza, R. Polini, and E. Traversa: High performance anode-supported intermediate temperature solid oxide fuel cells (IT-SOFCs) with La0.8Sr0.2Ga0.8Mg0.2O3-δ electrolyte films prepared by electrophoretic deposition. Electrochem. Commun. 11, 1680 (2009).
J.W. Yan, H. Matsumoto, M. Enoki, and T. Ishihara: High-power SOFC using La0.9Sr0.1Ga0.8Mg0.2O3-δ composite film. Electrochem. Solid-State Lett. 8, A389 (2005).
T. Ishihara, J.W. Yan, M. Shinagawa, and H. Matsumoto: Ni-Fe bimetallic anode as an active anode for intermediate temperature SOFC using LaGaO3 based electrolyte film. Electrochim. Acta 52, 1645 (2006).
Y.W. Ju, H. Matsumoto, T. Ishihara, T. Inagaki, and H. Eto: Preparation of LaGaO3 based oxide thin film on porous Ni-Fe metal substrate and its SOFC application. J. Korean Chem. Soc. 45, 796 (2008).
Y.W. Ju, H. Eto, T. Inagaki, and T. Ishihara: High power SOFC using LSGM film on NiFe porous bi-metal substrate. ECS Trans. 25, 719 (2009).
Y.W. Ju, H. Eto, T. Inagaki, and T. Ishihara: Preparation of Ni-Fe bimetallic porous anode support for SOFCs using LaGaO3 based electrolyte film with high power density. J. Power Sources 195, 6294 (2010).
Y.W. Ju, T. Inagaki, S. Ida, and T. Ishihara: Sm(Sr)CoO3 cone cathode on LaGaO3 thin film electrolyte for with IT-SOFC high power density. J. Electrochem. Soc. 158, 1 (2011).
N.Q. Minh, T.R. Armstrong, J.R. Esopa, J.V. Guiheen, C.R. Home, and J.J. van Ackeren: Proceedings of the third international symposium on the solid oxide fuel cell. Electrochem. Soc. Proc. 93-94, 801 (1993).
R. Yamaguchi, K. Hashimoto, H. Sakata, H. Kajiware, K. Watanable, T. Setiguchi, K. Eguchi, and H. Arai: Proceedings of the third international symposium on the solid oxide fuel cell. Electrochem. Soc. Proc. 93-94, 704 (1993).
C.C. Chen, M.M. Nasrallah, and H.U. Anderson: Synthesis and characterization of YSZ thin film electrolytes. Solid State Ionics 71, 101 (1994).
S. de Souza, S.J. Visco, and L.C. De Jonghe: Thin film solid oxide fuel cell with high performance at low-temperature. Solid State Ionics 98, 57 (1997).
C. Lunot and Y. Denos: Evaluation of Different Processes to Fabricate Thin Film Solid Fuel Cells, in Proceeding of the 1998 International Gas Research Conference, San Diego, California, November 8-11, 1998; D.A. Dolenc, ed., Gas Research Institute: Chicago, IL, 1998; p. 834.
C.J. Li, C.X. Li, Y.Z. Xing, M. Gao, and G.J. Yang: Influence of YSZ electrolyte thickness on the characteristics of plasma-sprayed cermet supported tubular SOFC. Solid State Ionics 177, 2065 (2006).
W. Bai, K.L. Choy, R.A. Rudkin, and B.C.H. Steele: The process, structure and performance of pen cells for the intermediate temperature SOFCs. Solid State Ionics 113-114, 259 (1998).
L.S. Wang, E.S. Thiele, and S.A. Barnett: Sputter deposition of yttria-stabilized zirconia and silver cermet electrodes for SOFC applications. Solid State Ionics 52, 261 (1992).
H. Yamamura, E. Katoh, M. Ichikawa, K. Kakinuma, M. Tori, and H. Haneda: Multiple doping effect on the electrical conductivity in the (Ce1-x-yLaxMy)O2-δ (M = Ca, Sr) system. Electrochemistry 68, 455 (2000).
D.J. Kim: Lattice parameters, ionic conductivities, and solubility limits in fluorite-structure MO2 oxide (M = Hf4+, Zr4+, Ce4+, Th4+, U4+) solid solutions. J. Am. Ceram. Soc. 72, 1415 (1989).
L.L. Zhang: Doped LaCrO3 as Interconnect in SOFC. (Ohio State Literature Review, Columbus, OH, 2004).
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Ju, YW., Hong, JE., Hyodo, J. et al. New buffer layer material La(Pr)CrO3 for intermediate temperature solid oxide fuel cell using LaGaO3-based electrolyte film. Journal of Materials Research 27, 1906–1914 (2012). https://doi.org/10.1557/jmr.2012.187
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DOI: https://doi.org/10.1557/jmr.2012.187