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Spectroscopic properties of Sm3+-doped phosphate glasses

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Abstract

We report on the absorption, static, and transient luminescence spectra of Sm3+-doped glasses. The dependences between absorption and emission cross sections as well as between luminescence quantum efficiencies and Sm3+ doping concentration are examined. The large stimulated absorption cross section and emission cross section combined with the long fluorescent lifetime make phosphate glasses doped with Sm3+ promising material for visible fiber lasers. Moreover, ΔT(TxTg) of these glasses is about 290 °C, which guarantees their thermal stability against crystallization during the fiber drawing process.

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References

  1. H. Okamoto, K. Kasuga, I. Hara, and Y. Kubota: Visible-NIR tunable Pr3+-doped fiber laser pumped by a GaN laser diode. Opt. Express 17, 20227 (2009).

    Article  CAS  Google Scholar 

  2. Y. Fujimoto, O. Ishii, and M. Yamazaki: Multi-colour laser oscillation in Pr3+-doped fluoro-aluminate glass fibre pumped by 442.6 nm GaN-semiconductor laser. Electron. Lett. 45, 1301 (2009).

    Article  CAS  Google Scholar 

  3. Y. Fujimoto, O. Ishii, and M. Yamazaki: Yellow laser oscillation in Dy3+-doped waterproof fluoro-aluminate glass fibre pumped by 398.8 nm GaN laser diodes. Electron. Lett. 46, 1285 (2010).

    Article  Google Scholar 

  4. T. Yamashita and Y. Ohisi: Amplification and lasing characteristics of Tb3+-doped fluoride fiber in the 0.54 μm band. Jpn. J. Appl. Phys. 46, L991 (2007).

    Article  CAS  Google Scholar 

  5. M. Farries, P. Morkel, and J. Townsend: Spectroscopic and lasing characteristics of samarium doped glass fibre. Electron. Lett. 24, 709 (1988).

    Article  Google Scholar 

  6. M. Seshadri, K. Rao, J. Rao, and Y. Ratnakaram: Spectroscopic and laser properties of Sm3+ doped different phosphate glasses. J. Alloys Compd. 476, 263 (2009).

    Article  CAS  Google Scholar 

  7. H. Campbell and I. Suratwala: Nd-doped phosphate glasses for high-energy/high-peak-power lasers. J. Non-Cryst. Solids 263 and 318 (2000).

    Article  Google Scholar 

  8. H. Lin, E. Pun, X. Wang, and X. Liu: Optical absorption and photoluminescence in Sm3+- and Eu3+-doped rare-earth borate glasses. J. Alloys Compd. 390, 197 (2005).

    Article  CAS  Google Scholar 

  9. M. Elisa, I. Vasiliu, C. Grigorescu, B. Grigoras, H. Niciu, D. Niciu, A. Meghea, N. Lfitimie, M. Giurginca, H. Trodahl, and M. Dalley: Optical and structural investigation on rare-earth-doped aluminophosphate glasses. Opt. Mater. 28, 621 (2006).

    Article  CAS  Google Scholar 

  10. P. Pascuta, G. Borodi, N. Junate, I. Vida-Simmiti, D. Viorel, and E. Culea: The structural role of manganese ions in some zinc phosphate glasses and glass ceramics. J. Alloys Compd. 504, 479 (2010).

    Article  CAS  Google Scholar 

  11. M. Czaja, S. Bodyl, J. Gabrys-Pisaarska, and Z. Mazurak: Applications of Judd-Ofelt theory to praseodymium and samarium ions in phosphate glass. Opt. Mater. 31, 1898 (2009).

    Article  CAS  Google Scholar 

  12. F. Auzel: Upconversion and anti-stokes processes with f and d ions in solids. Chem. Rev. 104, 139 (2004).

    Article  CAS  Google Scholar 

  13. G. Righini and M. Ferrari: Photoluminescence of rare-earth-doped glasses. La Rivista del Nuovo Cimento. 28, 1 (2005).

    CAS  Google Scholar 

  14. M. Ferrari: in Handbook of Sole Gel Science and Technology, edited by S. Sakka (Kluwer Academic Publishers, 2, Boston, MA, 2005) pp. 359–388.

    Google Scholar 

  15. D. McCumber: Theory of phonon-terminated optical masers. Phys. Rev. 134, A299 (1964).

    Article  Google Scholar 

  16. S. Berneschi, M. Bettinelli, M. Brenci, G. Nunzi Conti, S. Pelli, S. Sebastiani, C. Siligardi, A. Speghini, and G.C. Righini: Aluminum co-doping of soda-lime silicate glasses: Effect on optical and spectroscopic properties. J. Non-Cryst. Solids 351, 1747 (2005).

    Article  CAS  Google Scholar 

  17. A. Saissy, N. Azami, J. Jones, and G. Maze: Properties of Sm3+ ions in fluorozirconate fiber. Appl. Opt. 36, 5931 (1997).

    Article  CAS  Google Scholar 

  18. J. de Mello, H. Wittmann, and R. Friend: An improved experimental determination of external photoluminescence quantum efficiency. Adv. Mater. 9, 230 (1997).

    Article  Google Scholar 

  19. W. Liu, Y. Chiu, C. Tung, S. Jang, and T. Chen: A study on the luminescence properties of CaAlBO4:RE3+(RE = Ce, Tb, and Eu) phosphors. J. Electrochem. Soc. 155, J252 (2008).

    Article  CAS  Google Scholar 

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 51072054, 51072060, 51102096, 51132004), the National Basic Research Program of China (973 Program) (2011CB808103), the Fundamental Research Funds for the Central Universities (Grant Nos. 2011ZZ0001, 2011ZB0001, and 2011ZP0002), the Natural Science Foundation of Guangdong Province (Grant Nos. 1045106410104887, S2011030001349), and the China Postdoctoral Science Special Foundation (Grant No. 201104350)

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Correspondence to Jianrong Qiu.

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Zhang, L., Peng, M., Dong, G. et al. Spectroscopic properties of Sm3+-doped phosphate glasses. Journal of Materials Research 27, 2111–2115 (2012). https://doi.org/10.1557/jmr.2012.119

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  • DOI: https://doi.org/10.1557/jmr.2012.119

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