Skip to main content
Log in

Elastic anomaly and internal friction of Ba0.5Sr0.5Co0.8Fe0.2O3-δ and La0.58Sr0.4Co0.2Fe0.8O3-δ

  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Elastic modulus and internal friction of Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) and La0.58Sr0.4Co0.2Fe0.8O3-δ (LSCF) were determined from resonance frequencies and damping behavior, respectively, using an impulse excitation method. An elastic anomaly for BSCF around 476 K, with a corresponding peak in the internal friction, is attributed to the experimentally confirmed spin transition of Co3+. LSCF is in a ferromagnetic state below ∼220 K and in a paramagnetic state above ∼250 K. The elastic modulus of LSCF exhibits an anomaly between 473 and 1113 K, which is attributed to a transition from rhombohedral to cubic symmetry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

FIG. 1.
FIG. 2.
FIG. 3.
FIG. 4.

Similar content being viewed by others

REFERENCES

  1. J. Sunarso, S. Baumann, J.M. Serra, W.A. Meulenberg, S. Liu, Y.S. Lin, and J.C. Diniz da Costa: Mixed ionic-electronic conducting (MIEC) ceramic-based membranes for oxygen separation. J. Membr. Sci. 320, 13 (2008).

    Article  CAS  Google Scholar 

  2. J.H. Cheng, A. Navrotsky, X.D. Zhou, and H.U. Anderson: Thermochemistry of La1-xSrxFeO3-d solid solutions (0.0 <= x <= 1.0, 0.0 <= d <= 0.5). Chem. Mater. 17, 2197 (2005).

    Article  CAS  Google Scholar 

  3. O. Buchler, J.M. Serra, W.A. Meulenberg, D. Sebold, and H.P. Buchkremer: Preparation and properties of thin La1-xSrxCo1-yFeyO3-d perovskitic membranes supported on tailored ceramic substrates. Solid State Ion 178, 91 (2007).

    Article  Google Scholar 

  4. B.X. Huang, J. Malzbender, R.W. Steinbrech, P. Grychtol, C.M. Schneider, and L. Singheiser: Anomalies in the thermomechanical behavior of Ba0.5Sr0.5Co0.8Fe0.2O3-d ceramic oxygen conductive membranes at intermediate temperatures. Appl. Phys. Lett. 95, 051901 (2009).

    Article  Google Scholar 

  5. B.X. Huang, J. Malzbender, R.W. Steinbrech, and L. Singheiser: Mechanical properties of La0.58Sr0.4Co0.2Fe0.8O3-d membranes. Solid State Ion 180, 241 (2009).

    Article  CAS  Google Scholar 

  6. R.K. Zheng, A.N. Tang, Y. Yang, W. Wang, G. Li, X.G. Li, and H.C. Ku Transport: magnetic, specific heat, internal friction, and shear modulus in the charge ordered La0.25Ca0.75MnO3 manganite. J. Appl. Phys. 94, 514 (2003).

    Article  CAS  Google Scholar 

  7. A.S. Bhalla, R.Y. Guo, and R. Roy: The perovskite structure—a review of its role in ceramic science and technology. Mater. Res. Innovations 4, 3 (2000).

    Article  CAS  Google Scholar 

  8. P.G. Radaelli and S.W. Cheong: Structural phenomena associated with the spin-state transition in LaCoO3. Phys. Rev. B 66, 094408 (2002).

    Article  Google Scholar 

  9. P. Ravindran, P.A. Korzhavyi, H. Fjellvag, and A. Kjekshus: Electronic structure, phase stability, and magnetic properties of La1-xSrxCoO3 from first-principles full-potential calculations. Phys. Rev. B 60, 16423 (1999).

    Article  CAS  Google Scholar 

  10. X.S. Wu, Y.B. Zuo, J.H. Li, C.S. Chen, and W. Liu: Low-frequency internal friction study of phase transitions in La1/3Sr2/3FeO3-d ceramics. J. Alloy. Comp. 462, 432 (2008).

    Article  CAS  Google Scholar 

  11. S. Yamaguchi, Y. Okimoto, H. Taniguchi, and Y. Tokura: Spin-state transition and high-spin polarons in LaCoO3. Phys. Rev. B 53, R2926 (1996).

    Article  CAS  Google Scholar 

  12. A.K. Swarnakar, S. Gimenez, S. Salehi, J. Vleugels, and O. Van der Biest: Recent advances in material characterization using the impulse excitation technique (IET). Key Eng. Mater. 333, 235 (2007).

    Article  CAS  Google Scholar 

  13. J. Du, Y. Sun, J. Jiang, F. Zeng, and H. Yin: Internal friction and Youngs modulus in the Bi(Pb)-Sr-Ca-Cu-O superconductor. Phys. Rev. B 41, 6679 (1990).

    Article  CAS  Google Scholar 

  14. S. Giraud and J. Canel: Young’s modulus of some SOFCs materials as a function of temperature. J. Eur. Ceram. Soc. 28, 77 (2008).

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors express their sincere gratitude to Dr. E. Kentzinger (IFF) for offering PPMS facility, Mr. J. Mönch for developing the impulse excitation set-up, and Ms. Y. Yao (IEK-2) for carrying out the measurements. The authors thank Dr. S. Bauman for the preparation of the perovskite materials.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jürgen Malzbender.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Huang, B., Malzbender, J. & Steinbrech, R.W. Elastic anomaly and internal friction of Ba0.5Sr0.5Co0.8Fe0.2O3-δ and La0.58Sr0.4Co0.2Fe0.8O3-δ. Journal of Materials Research 26, 1388–1391 (2011). https://doi.org/10.1557/jmr.2011.164

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/jmr.2011.164

Navigation