Abstract
Effects of stacking fault energy (SFE) on the thermal stability and mechanical properties of nanostructured (NS) Cu-Al alloys during thermal annealing were investigated in this study. Compared with NS Cu-5at.%Al alloy with the higher SFE, NS Cu-8at.%Al alloy exhibits the lower critical temperatures for the initiation of recrystallization and the transition from recovery-dominated to recrystallization-dominated process, which significantly signals its low thermal stability. This may be attributed to the large microstructural heterogeneities resulting from severe plastic deformation. With increasing the annealing temperatures, both Cu-Al alloys present the similar trend of decreased strength and improved ductility. Meanwhile, the remarkable enhancement of uniform elongation is achieved when the volume fraction of Static recrystallization (SRX) grains exceeds -80%. Moreover, the better strength-ductility combination was achieved in the Cu-8at.%Al alloy with lower SFE.
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References
R.Z. Valiev and T.G. Langdon: Principles of equal-channel angular pressing as a processing tool for grain refinement. Prog. Mater. Sci. 51, 881 (2006).
M.A. Meyers, A. Mishra, and D.J. Benson: Mechanical properties of nanocrystalline materials. Prog. Mater. Sci. 51, 427 (2006).
C.C. Koch, D.G. Morris, K. Lu, and A. Inoue: Ductility of nanostructured materials. MRS Bull. 24, 54 (1999).
L. Lu, Y.F. Shen, X.H. Chen, L.H. Qian, and K. Lu: Ultrahigh strength and high electrical conductivity in copper. Science 304, 422 (2004).
Y.M. Wang, M.W. Chen, F. Zhou, and E. Ma: High tensile ductility in a nanostructured metal. Nature 419, 912 (2002).
X.X. Huang, N. Hansen, and N. Tsuji: Hardening by annealing and softening by deformation in nanostructured metals. Science 312, 249 (2006).
Y.H. Zhao, J.F. Bingert, Y.T. Zhu, X.Z. Liao, R.Z. Valiev, Z. Horita, T.G. Langdon, Y.Z. Zhou, and E.J. Lavernia: Tougher ultrarine grain Cu via high-angle grain boundaries and low dislocation density. Appl. Phys. Lett. 92, 081903 (2008).
N. Tsuji, Y. Ito, Y. Saito, and Y. Minamino: Strength and ductility of ultrarine grained aluminum and iron produced by ARB and annealing. Scr. Mater. 47, 893 (2002).
Y.S. Li, Y. Zhang, N.R. Tao, and K. Lu: Effect of thermal annealing on mechanical properties of a nanostructured copper prepared by means of dynamic plastic deformation. Scr. Mater. 59, 475 (2008).
R.Z. Valiev, A.V. Sergueeva, and A.K. Mukherjee: The effect of annealing on tensile deformation behavior of nanostructured SPD titanium. Scr. Mater. 49, 669 (2003).
B. Srinivasarao, K. Oh-ishi, T. Ohkubo, T. Mukai, and K. Hono: Synthesis of high-strength bimodally grained iron by mechanical alloying and spark plasma sintering. Scr. Mater. 58, 759 (2008).
M.A. Meyers and K.K. Chawla: Mechanical Behavior of Materials (Prentice Hall, NJ, 1999).
W.Z. Han, Z.F. Zhang, S.D. Wu, and S.X. Li: Combined effects of crystallographic orientation, stacking fault energy and grain size on deformation twinning in FCC crystals. Philos. Mag. 88, 3011 (2008).
F.J. Humphreys and M. Hatherly Recrystallization and Related Annealing Phenomena, 2nd ed. (Elsevier, Oxford, 2004).
S. Qu, X.H. An, H.J. Yang, C.X. Huang, G. Yang, Q.S. Zang, Z.G. Wang, S.D. Wu, and Z.F. Zhang: Microstructural evolution and mechanical properties of Cu-Al alloys subjected to equal channel angular pressing. Acta Mater. 57, 1586 (2009).
X.H. An, Q.Y. Lin, S. Qu, G. Yang, S.D. Wu, and Z.F. Zhang: Influence of stacking fault energy on the accommodation of severe shear strain in Cu-Al alloys during equal channel angular pressing. J. Mater. Res. 24, 3636 (2009).
X.H. An, W.Z. Han, C.X. Huang, P. Zhang, G. Yang, S.D. Wu, and Z.F. Zhang: High strength and utilizable ductility of bulk ultrafine-grained Cu-Al alloys. Appl. Phys. Lett. 92, 201915 (2008).
S.D. Wu, X.H. An, W.Z. Han, S. Qu, and Z.F. Zhang: Microstruc-ture evolution and mechanical properties of fee metallic materials subjected to equal channel angular pressing. Acta Mater. Sin. 46, 257 (2010).
Y.T. Zhu and T.G. Langdon: Observations and issues on mechanisms of grain refinement during ECAP process. Mater. Sci. Eng., A 291, 46 (2000).
F.J. Humphreys: Review grain and subgrain characterisation by electron backscatter diffraction. J. Mater. Sci. 36, 3833 (2001).
H.J. Yang, Y.B. Xu, Y. Seki, V.F. Nesterenko, and M.A. Meyers: Analysis and characterization by electron backscatter diffraction of microstructural evolution in the adiabatic shear bands in Fe-Cr-Ni alloys. J. Mater. Res. 24, 2617 (2009).
A. Rohatgi and K.S. Vecchio: The variation of dislocation density as a function of the stacking fault energy in shock-deformed FCC materials. Mater. Sci. Eng., A 328, 256 (2002).
H. Paul, J.H. Driver, and Z. Jasiehski: Shear banding and re-crystallization nucleation in a Cu-2%A1 alloy single crystal. Acta Mater. 50, 815 (2002).
F.J. Humphreys: A unified theory of recovery, recrystallization and grain growth, based on the stability and growth of cellular microstructures-I. The basic model. Acta Mater. 45, 4231 (1997).
M. Ferry and F.J. Humphreys: Discontinuous subgrain growth in deformed and annealed 110 (001) aluminium single crystals. Acta Mater. 44, 1293 (1996).
Y. Huang, F.J. Humphreys, and M. Ferry: The annealing behaviour of deformed cube-oriented aluminium single crystals. Acta Mater. 48, 2543 (2000).
S.D. Wu, Z.G. Wang, C.B. Jiang, G.Y. Li, I.V. Alexandrov, and R.Z. Valiev: The formation of PSB-like shear bands in cyclically deformed ultrarine grained copper processed by ECAP. Scr. Mater. 48, 1605 (2003).
J.Y. Huang, Y.T. Zhu, H. Jiang, and T.C. Lowe: Microstructures and dislocation configurations in nanostructured Cu processed by repetitive corrugation and straightening. Acta Mater. 49, 1497 (2001).
P.J. Hurley and F.J. Humphreys: Modelling the recrystallization of single-phase aluminium. Acta Mater. 51, 3779 (2003).
Y.S. Li, N.R. Tao, and K. Lu: Microstructural evolution and nanostructure formation in copper during dynamic plastic deformation at cryogenic temperatures. Acta Mater. 56, 230 (2008).
E. Ma, Y.M. Wang, Q.H. Lu, M.L. Sui, L. Lu, and K. Lu: Strain hardening and large tensile elongation in ultrahigh-strength nano-twinned copper. Appl. Phys. Lett. 85, 4932 (2004).
Y.H. Zhao, Y.T. Zhu, X.Z. Liao, Z. Horita, and T.G. Langdon: Tailoring stacking fault energy for high ductility and high strength in ultrarine grained Cu and its alloy. Appl. Phys. Lett. 89, 121906 (2006).
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An, X.H., Qu, S., Wu, S.D. et al. Effects of stacking fault energy on the thermal stability and mechanical properties of nanostructured Cu-Al alloys during thermal annealing. Journal of Materials Research 26, 407–415 (2011). https://doi.org/10.1557/jmr.2010.39
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DOI: https://doi.org/10.1557/jmr.2010.39